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Supramolecular Hybrid Organic/Inorganic Nanomaterials Based on Metalloporphyrins and Phthalocyanines Read chapter Read first chapter

2016 | OriginalPaper | Chapter

Electrosynthesis of Oligo- and Polyporphyrins Based on Oxidative Coupling of Macrocycles

Authors : Delphine Schaming, Laurent Ruhlmann

Published in: Electrochemistry of N4 Macrocyclic Metal Complexes

Publisher: Springer International Publishing

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Abstract

This chapter is devoted to oligo- and polyporphyrin systems obtained from reactions directly involving macrocycles, especially from their oxidized states. Indeed, it is possible to oxidize porphyrin macrocycles, leading successively to π-radical cations and then dications, these species being very reactive. Oxidized porphyrins can either react with nucleophilic groups or couple each other to give oligomers or polymers of porphyrins. This reactivity offers a novel electrochemical pathway to synthesize supramolecular assemblies containing porphyrin macrocycles.

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previous chapter Spirobifluorenyl-Porphyrins and their Derived Polymers for Homogeneous or Heterogeneous Catalysis
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Metadata
Title
Electrosynthesis of Oligo- and Polyporphyrins Based on Oxidative Coupling of Macrocycles
Authors
Delphine Schaming
Laurent Ruhlmann
Copyright Year
2016
Book
Electrochemistry of N4 Macrocyclic Metal Complexes

Print ISBN: 978-3-319-31330-6

Electronic ISBN: 978-3-319-31332-0

Copyright Year: 2016

DOI
https://doi.org/10.1007/978-3-319-31332-0_10