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2023 | OriginalPaper | Chapter

3. Emerging 2D Materials for Supercapacitors: MXenes

Authors : Shagufi Naz Ansari, Mohit Saraf, Shaikh M. Mobin

Published in: Handbook of Nanocomposite Supercapacitor Materials IV

Publisher: Springer International Publishing

Abstract

MXenes are two-dimensional (2D) transition metal carbides, nitrides, or carbonitrides that display layered structure, rich surface chemistry, superior hydrophilicity, and intrinsic electronic conductivity. Since the very first report on MXenes (Ti₃C₂T_x) in 2011, the focus on MXenes has increased exponentially due to their favorable properties for a diverse range of applications including energy storage, thanks to their high conductivity, redox activity, and electrochemically active surface. In this chapter, we have targeted the current advances, achievements, and challenges in MXenes research on supercapacitors in a concise manner. In the beginning, an overview of various synthetic approaches for 2D MXenes are presented, and then, their structural aspects and properties are summarized. Moreover, MXenes and their composites-based supercapacitors are discussed highlighting their potential in such energy storage devices. Finally, few challenges and perspectives are provided to encourage the further improvement of MXenes in supercapacitors.

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Y. Shao, M.F. El-Kady, J. Sun, Y. Li, Q. Zhang, M. Zhu, H. Wang, B. Dunn, R.B. Kaner, Design and mechanisms of asymmetric supercapacitors. Chem. Rev. 118, 9233–9280 (2018). https://doi.org/10.1021/acs.chemrev.8b00252 CrossRef

S. Chu, A. Majumdar, Opportunities and challenges for a sustainable energy future. Nature 488, 294–303 (2012). https://doi.org/10.1038/nature11475 CrossRef

D. Kundu, E. Talaie, V. Duffort, L.F. Nazar, The emerging chemistry of sodium ion batteries for electrochemical energy storage. Angew. Chem. Int. Ed. 54, 3431–3448 (2015). https://doi.org/10.1002/anie.201410376 CrossRef

Y. Wang, Y. Song, Y. Xia, Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem. Soc. Rev. 45, 5925–5950 (2016). https://doi.org/10.1039/C5CS00580A CrossRef

H. Shao, Y.C. Wu, Z. Lin, P.-L. Taberna, P. Simon, Nanoporous carbon for electrochemical capacitive energy storage. Chem. Soc. Rev. 49, 3005–3039 (2020). https://doi.org/10.1039/D0CS00059K CrossRef

Z. Lin, E. Goikolea, A. Balducci, K. Naoi, P.L. Taberna, M. Salanne, G. Yushin, P. Simon, Materials for supercapacitors: when Li-ion battery power is not enough. Mater. Today. 21, 419–436 (2018). https://doi.org/10.1016/j.mattod.2018.01.035 CrossRef

J. Yan, Q. Wang, T. Wei, Z. Fan, Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities. Adv. Energy. Mater. 4, 1300816 (2014). https://doi.org/10.1002/aenm.201300816 CrossRef

R. Rajak, M. Saraf, S.M. Mobin, Mixed-ligand architected unique topological heterometallic sodium/cobalt-based metal-organic framework for high-performance supercapacitors. Inorg. Chem. 59, 1642–1652 (2020). https://doi.org/10.1021/acs.inorgchem.9b02762 CrossRef

S.N. Ansari, M. Saraf, A.K. Gupta, S.M. Mobin, Functionalized Cu-MOF@CNT hybrid: synthesis, crystal structure and applicability in supercapacitors. Asian J. Chem. 14, 3566–3571 (2019). https://doi.org/10.1002/asia.201900629 CrossRef

10.

R. Rajak, M. Saraf, A. Mohammad, S.M. Mobin, Design and construction of a ferrocene based inclined polycatenated Co-MOF for supercapacitor and dye adsorption applications. J. Mater. Chem. A. 5, 17998–18011 (2017). https://doi.org/10.1039/C7TA03773B

11.

R. Rajak, M. Saraf, P. Kumar, K. Natarajan, S.M. Mobin, Construction of a Cu-based metal-organic framework by employing a mixed-ligand strategy and its facile conversion into nanofibrous CuO for electrochemical energy storage applications. Inorg. Chem. 60, 16986–16995 (2021). https://doi.org/10.1021/acs.inorgchem.1c02062 CrossRef

12.

M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, M.W. Barsoum, Two-dimensional nanocrystals produced by exfoliation of Ti ₃AlC ₂. Adv. Mater. 23, 4248–4253 (2022). https://doi.org/10.1002/adma.201102306 CrossRef

13.

W. Yuan, L. Cheng, H. Wu, Y. Zhang, S. Lv, X. Guo, One-step synthesis of 2D-layered carbon wrapped transition metal nitrides from transition metal carbides (MXenes) for supercapacitors with ultrahigh cycling stability. Chem. Commun. 54, 2755–2758 (2017). https://doi.org/10.1039/C7CC09017J CrossRef

14.

A. VahidMohammadi, J. Rosen, Y. Gogotsi, The world of two-dimensional carbides and nitrides (MXenes). Science 372, 6547 (2021). https://doi.org/10.1126/science.abf158 CrossRef

15.

J. Fu, J. Yun, S. Wu, L. Li, L. Yu, K.H. Kim, Architecturally robust graphene-encapsulated MXene Ti2CTx@polyaniline composite for high-performance pouch-type asymmetric supercapacitor. ACS Appl. Mater. Interfaces 10, 34212–34221 (2018). https://doi.org/10.1021/acsami.8b10195 CrossRef

16.

Q. Yang, Y. Wang, X. Li, Recent progress of MXene-based nanomaterials in flexible energy storage and electronic devices. Energy Environ. Mater. 1, 183–195 (2018). https://doi.org/10.1002/eem2.12023 CrossRef

17.

Q. Jiang, N. Kurra, M. Alhabeb, Y. Gogotsi, H.N. Alshareef, 2D all pseudocapacitive MXene-RuO ₂ asymmetric supercapacitors. Adv. Energy Mater. 8, 16098 (2018). https://doi.org/10.1002/aenm.201703043 CrossRef

18.

L. Verger, C. Xu, V. Natu, H.-M. Cheng, W. Ren, M.W. Barsoum, Overview of the synthesis of MXenes and other ultrathin 2D transition metal carbides and nitrides. Curr. Opin. Solid State Mater. Sci. 23, 49–163 (2019). https://doi.org/10.1016/j.cossms.2019.02.001 CrossRef

19.

J. Xu, T. Peng, X. Qin, Q. Zhang, T. Liu, W. Dai, B. Chen, H.u, S. Shi, Recent advances in 2D MXenes: preparation, intercalation and applications in flexible devices. J. Mater. Chem. A. 9, 4147–14171 (2021). https://doi.org/10.1039/D1TA03070A

20.

M. Alhabeb, K. Maleski, B. Anasori, P. Lelyukhet, L. Clark, S. Sin, Y. Gogotsi, Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti ₃C ₂T _x MXene). Chem. Mater. 29, 7633–7644 (2017). https://doi.org/10.1021/acs.chemmater.7b02847 CrossRef

21.

C.E. Shuck, K. Ventura-Martinez, A. Goad, S. Uzun, M. Shekhirev, Y. Gogotsi, Goad, safe synthesis of MAX and MXene: guidelines to reduce risk during synthesis. ACS Chem. Health Saf. 28, 326–338 (2021). https://doi.org/10.1021/acs.chas.1c00051 CrossRef

22.

J Xu, J Shim, J.-H Park, S. Lee, MXene electrode for the integration of WSe ₂ and MoS ₂ field effect transistors. Adv. Funct. Mater. 26, 5328–5334 (2016). https://doi.org/10.1002/adfm.201600771

23.

M. Hu, Z. Li, H. Zhang, T. Hu, C. Zhang, Z. Wu, X. Wang, Self-assembled Ti ₃C ₂T _x MXene film with high gravimetric capacitance. Chem. Commun. 51, 13531–13533 (2015). https://doi.org/10.1039/C5CC04722F CrossRef

24.

O. Mashtalir, M. Naguib, V.N. Mochalin, Y.D. Agnese, M. Heon, M.W. Barsoum, Y. Gogotsi, Intercalation and delamination of layered carbides and carbonitrides. Nat. Commun. 4, 1–7 (2013). https://doi.org/10.1038/ncomms2664 CrossRef

25.

O. Mashtalir, M.R. Lukatskaya, M.-Q. Zhao, M.W. Barsoum, Y. Gogotsi, Amine-assisted delamination of Nb ₂C MXene for Li-ion energy storage devices. Adv. Mater. 27, 3501–3506 (2015). https://doi.org/10.1002/adma.201500604 CrossRef

26.

M. Naguib, R.R. Unocic, B.L. Armstrong, J. Nanda, Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes.” Dalton Trans. 44, 9353–9358 (2015). https://doi.org/10.1039/C5DT01247C CrossRef

27.

B. Anasori, M.R. Lukatskaya, Y. Gogotsi, 2D metal carbides and nitrides (MXenes) for energy storage. Nat. Rev. Mater. 2, 16098 (2017). https://doi.org/10.1038/natrevmats.2016.98 CrossRef

28.

M.R. Lukatskaya, S.M. Bak, X. Yu, X.Q. Yang, M.W. Barsoum, Y. Gogotsi, 2D probing the mechanism of high capacitance in 2d titanium carbide using in situ X-ray absorption spectroscopy. Adv. Energy Mater. 5, 1500589 (2015). https://doi.org/10.1002/aenm.201500589 CrossRef

29.

G. Zou, J. Guo, X. Liu, Q. Yang, Hydrogenated core-shell MAX@K2Ti8O17 pseudocapacitance with ultrafast sodium storage and long-term cycling. Adv. Energy Mater. 7, 1–9 (2017). https://doi.org/10.1002/aenm.201700700 CrossRef

30.

J. Xuan, Z. Wang, Y. Chen, D. Liang, L. Cheng, X. Yang, Z. Liu, R. Ma, T. Sasaki, F. Geng, Organic-base-driven intercalation and delamination for the production of functionalized titanium carbide nanosheets with superior photothermal therapeutic performance. Angew. Chem. Int. Ed. 55, 14569–14574 (2016). https://doi.org/10.1002/ange.201606643 CrossRef

31.

G. Zou, Q. Zhang, C. Fernandez, G. Huang, J. Huang, Q. Peng, Heterogeneous Ti ₃SiC ₂@C-Containing Na ₂Ti ₇O ₁₅ architecture for high-performance sodium storage at elevated temperatures. ACS Nano 11, 12219 (2017). https://doi.org/10.1021/acsnano.7b05559

32.

T. Li, L. Yao, Q. Liu, J. Gu, R. Luo, J. Li, X. Yan, W. Wang, P. Liu, B. Chen, W. Zhang, W. Abbas, R. Naz, D. Zhang, Fluorine-free synthesis of high-purity Ti ₃C ₂T _x (T=OH, O) via alkali treatment. Angew. Chem. Int. Ed. 57, 6115–6119 (2018). https://doi.org/10.1002/anie.201800887 CrossRef

33.

P. Urbankowski, B. Anasori, T. Makaryan, D. Er, S. Kota, P.L. Walsh, M. Zhao, V.B. Sheno, M.W. Barsoum, Y. Gogotsi, Synthesis of two-dimensional titanium nitride Ti ₄N ₃ (MXene). Nanoscale 8, 11385 (2016). https://doi.org/10.1039/C6NR02253G CrossRef

34.

M. Li, J. Lu, K. Luo, Y. Li, K. Chang, K. Chen, K. Zhou, K. Rosen, L. Hultman, P. Eklund, P.O.A. Persson, S. Du, Z. Chai, Z. Huang, Q. Huang, Element replacement approach by reaction with Lewis acidic molten salts to synthesize nanolaminated MAX phases and MXenes. J. Am. Chem. Soc. 141, 4730–4737 (2019). https://doi.org/10.1021/jacs.9b00574 CrossRef

35.

Y. Wei, P. Zhang, R.A. Soomro, Q. Zhu, B. Xu, Advances in the synthesis of 2D MXenes. Adv. Mater. 33, 2103148 (2021). https://doi.org/10.1002/adma.202103148 CrossRef

36.

F. Liu, A. Zhou, J. Chen, J. Jia, W. Zhou, L. Wang, Q. Hu, Preparation of Ti ₃C ₂ and Ti ₂C MXenes by fluoride salts etching and methane adsorptive properties. Appl. Surf. Sci. 416, 781 (2017). https://doi.org/10.1016/j.apsusc.2017.04.239 CrossRef

37.

M. Ghidiu, M.R. Lukatskaya, M.-Q. Zhao, Y. Gogotsi, M.W. Borsum, Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature 516, 78–81 (2014). https://doi.org/10.1038/nature13970 CrossRef

38.

M.R. Lukatskaya, J. Halim, B. Dyatkin, M. Naguib, Y.S. Buranova, M.W. Borsum, Y. Gogotsi, Room-temperature carbide-derived carbon synthesis by electrochemical etching of MAX phases. Angew. Chem. Int. Ed. 126, 4977–4980 (2014). https://doi.org/10.1002/ange.201402513 CrossRef

39.

W. Sun, S. Shah, Z. Chen, H. Gao, T. Habib, M. Radovic, M.J. Green, Electrochemical etching of Ti ₂AlC to Ti ₂CT _x (MXene) in low-concentration hydrochloric acid solution. J. Mater. Chem. A. 5, 21663–21668 (2017). https://doi.org/10.1039/C7TA05574A CrossRef

40.

X. Sang, Y. Xi, M.-W. Lin, M. Alhabeb, K.L. Van Aken, Y. Gogotsi, P.R.C. Kent, K. Xiao, R.R. Unocic, Vacancies in Ti ₂CT ₂ atomic defects in monolayer titanium carbide (Ti ₃C ₂T _x) MXene. ACS Nano 10, 9193–9200 (2016). https://doi.org/10.1021/acsnano.6b05240 CrossRef

41.

T. Hu, J. Yang, X. Wang, Carbon vacancies in Ti ₂CT ₂ MXenes: defects or a new opportunity? Phys. Chem. Chem. Phys. 19, 31773–31780 (2017). https://doi.org/10.1039/C7CP06593K CrossRef

42.

Q. Tao, M. Dahlqvist, J. Lu, S. Kota, R. Meshkian, J. Halim, J. Palisaitis, L. Hultman, M.W. Barsoum, P.O.Å. Persson, J. Rose, Two-dimensional Mo _1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering. Nat. Commun. 8, 1–7 (2017). https://doi.org/10.1038/ncomms14949

43.

J.L. Hart, K. Hantanasirisakul, A.C. Lang, B. Anasori, D. Pinto, Y. Pivak, J.T.V. Omme, S.J. May, Y. Gogotsi, M.L. Taheri, Control of MXenes’ electronic properties through termination and intercalation. Nat. Commun. 10, 522 (2019). https://doi.org/10.1038/s41467-018-08169-8 CrossRef

44.

S. Tanwar, A. Arya, A. Gaur, A.L. Sharma, Transition metal dichalcogenide (TMDs) electrodes for supercapacitors: a comprehensive review. J. Phys.: Condens. Matter 33, 303002 (2021). https://doi.org/10.1088/1361-648X/abfb3c

45.

X. Li, Z. Huang, C.E. Shuck, G. Liang, Y. Gogotsi, C. Zhi, MXene chemistry, electrochemistry and energy storage applications. Nat. Rev. Chem. 6, 389–404 (2022). https://doi.org/10.1038/s41570-022-00384-8 CrossRef

46.

M. Boota, Y. Gogotsi, Mxene-conducting polymer asymmetric pseudocapacitors. Adv. Energy Mater. 9, 1502–1505 (2018). https://doi.org/10.1002/aenm.201802917 CrossRef

47.

M.D. Levi, M.R. Lukatskaya, S. Sigalov, M. Beidaghi, N. Shpigel, L. Daikhin, D. Aurbach, M.W. Barsoum, Y. Gogotsi, Solving the capacitive paradox of 2D MXene using electrochemical quartz-crystal admittance and in situ electronic conductance measurements. Adv. Energy Mater. 5, 1400815 (2014). https://doi.org/10.1002/aenm.201400815 CrossRef

48.

M.R. Lukatskaya, O. Mashtalir, C.E. Ren, Y. Dallagnese, P. Rozier, P.L. Taberna, M. Naguib, P. Simon, M.W. Barsoum, Y. Gogotsi, Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science 341, 1502–1505 (2013). https://doi.org/10.1126/science.1241488 CrossRef

49.

N. Shpigel, M.R. Lukatskaya, S. Sigalov, C.E. Ren, P. Nayak, M.D. Levi, L. Daikhin, D. AurbachO, Y. Gogotsi, In situ monitoring of gravimetric and viscoelastic changes in 2d intercalation electrodes. ACS. Energy Lett. 2, 1407–1415 (2017). https://doi.org/10.1021/acsenergylett.7b00133 CrossRef

50.

X.H. Xia, L. Shi, H.B. Liu, L. Yang, Y.D. He, A facile production of microporous carbon spheres and their electrochemical performance in EDLC. J. Phys. Chem. Solids 73, 385–390 (2012). https://doi.org/10.1016/j.jpcs.2011.10.028 CrossRef

51.

Y. Tao, X. Xie, W. Lv, D.-M. Tang, D.K.Z. Huang, H. Nishihara, T. Ishii, B. Li, D. Golberg, F. Kang, T. Kyotani, Q.-H. Yang, Towards ultrahigh volumetric capacitance: graphene derived highly dense but porous carbons for supercapacitors. Sci. Rep. 3, 2975 (2013). https://doi.org/10.1038/srep02975 CrossRef

52.

S. Kumar, D. Kang, H. Hong, M.A. Rehman, Y.-J. Lee, N. Leeab, Y. Seo, Effect of Ti ₃C ₂T _x MXenes etched at elevated temperatures using concentrated acid on binder-free supercapacitors. RSC Adv. 10, 41837–41845 (2020). https://doi.org/10.1039/D0RA05376G CrossRef

53.

C. Wang, H. Shou, S. Chen, S. Wei, Y. Lin, P. Zhang, Z. Liu, K. Zhu, X. Guo, X. Wu, P.M. Ajayan, L. Song, HCl-based hydrothermal etching strategy toward fluoride-free MXenes. Adv. Mater. 33, 2101015 (2021). https://doi.org/10.1002/adma.202101015

54.

M. Naguib, V.N. Mochalin, M.W. Barsoum, Y. Gogotsi, Two-dimensional materials: 25th anniversary article: MXenes: a new family of two-dimensional materials. Adv. Mater. 26, 982–1005 (2014). https://doi.org/10.1002/adma.201470041 CrossRef

55.

X. Wang, S. Lin, H. Tong Y. Huang, P. Tong, B. Zhao, J. Dai, C. Liang, H. Wang, X. Zhu, Y. Sunad, S. Dou, Two-dimensional V ₄C ₃ MXene as high performance electrode materials for supercapacitors. Electrochim. Acta. 307, 414–421 (2019). https://doi.org/10.1016/j.electacta.2019.03.205

56.

S. Zhao, C. Chen, X. Zhao, X. Chu, F. Du, G. Chen, Y. Gogotsi, Y. Gao, Y.D. Agnese, Flexible Nb ₄C ₃T _x film with large interlayer spacing for high-performance supercapacitors. Adv. Funct. Mater. 30, 2000815 (2020). https://doi.org/10.1002/adfm.202000815 CrossRef

57.

S. Feng, Z. Liu, Q. Yu, Z. Zhuang, Q. Chen, S. Fu, L. Zhou, L. Ma, Monodisperse carbon sphere-constructed pomegranate-like structures for high-volumetric-capacitance supercapacitors. ACS Appl. Mater. Interfaces 11, 4011–4016 (2019). https://doi.org/10.1021/acsami.8b19901 CrossRef

58.

Y. Tang, J.F. Zhu, C.H. Yang, F. Wang, Enhanced capacitive performance based on diverse layered structure of two-dimensional Ti ₃C ₂ MXene with long etching time. J. Electrochem. Soc. 163, A1975–A1982 (2016). https://doi.org/10.1149/2.0921609jes CrossRef

59.

X.W. Yu, H.-H. Cheng, M. Zhang, Y. Zhao, L. Qu, G. Shi, Graphene-based smart materials. Nat. Rev. Mater. 2, 17046 (2017). https://doi.org/10.1038/natrevmats.2017.46 CrossRef

60.

H.-H. Li, S.H. Yu, Recent advances on controlled synthesis and engineering of hollow alloyed nanotubes for electrocatalysis. Adv. Mater. 31, 1803503 (2019). https://doi.org/10.1002/adma.201803503 CrossRef

61.

M. Saraf, K. Natarajan, S.M. Mobin, Emerging robust heterostructure of MoS ₂–rGO for high-performance supercapacitors. ACS Appl. Mater. Interfaces. 10, 16588–16595 (2018). https://doi.org/10.1021/acsami.8b04540 CrossRef

62.

M. Saraf, K. Natarajan, S.M. Mobin, Robust nanocomposite of nitrogen-doped reduced graphene oxide and MnO ₂ nanorods for high-performance supercapacitors and nonenzymatic peroxide sensors. ACS Sustain. Chem. Eng. 6, 10489–10504 (2018). https://doi.org/10.1021/acssuschemeng.8b01845 CrossRef

63.

M. Saraf, K. Natarajan, S.M. Mobin, Microwave assisted fabrication of a nanostructured reduced graphene oxide (rGO)/Fe ₂O ₃ composite as a promising next generation energy storage material. RSC Adv. 7, 309–317 (2017). https://doi.org/10.1039/C6RA24766K CrossRef

64.

R.B. Rakhi, B. Ahmed, D. Anjum, H.N. Alshareef, Direct chemical synthesis of MnO ₂ nanowhiskers on transition-metal carbide surfaces for supercapacitor applications. ACS Appl. Mater. Interfaces. 8, 18806–18814 (2016). https://doi.org/10.1021/acsami.6b04481 CrossRef

65.

J.P. Zheng, T.R. Jow, A new charge storage mechanism for electrochemical capacitors. J. Electrochem. Soc. 142, L6–L8 (1995). https://doi.org/10.1557/PROC-393-439

66.

S. Shi, Z. Sun, Y.H. Hu, Synthesis, stabilization and applications of 2-dimensional 1T metallic MoS ₂. J. Mater. Chem. A. 6, 23932–23977 (2018). https://doi.org/10.1039/C8TA08152B CrossRef

67.

M.Q. Zhao, M. Torelli, C.E. Ren, M. Ghidiu, Z. Ling, B. Anasori, M.W. Barsoum, Y. Gogotsi, 2D titanium carbide and transition metal oxides hybrid electrodes for Li-ion storage. Nano Energy 30, 603–613 (2016). https://doi.org/10.1016/j.nanoen.2016.10.062 CrossRef

68.

X. Wang, H. Li, H. Li, S. Lin, W. Ding, X. Zhu, Z. Sheng, H. Wang, X. Zhu, Y. Sun, 2D/2D 1T-MoS ₂/Ti ₃C ₂ MXene heterostructure with excellent supercapacitor performance. Adv. Funct. Mater. 30, 0190302 (2020). https://doi.org/10.1002/adfm.201910302 CrossRef

69.

J. Zhou, J.L. Yu, L.D. Shi, Z. Wang, H. Liu, B. Yang, C. Li, C. Zhu, J. Xu, A conductive and highly deformable all-pseudocapacitive composite paper as supercapacitor electrode with improved areal and volumetric capacitance. Small 14, 1803786 (2018). https://doi.org/10.1002/smll.201803786 CrossRef

70.

K.K. Kar (ed.), Handbook of Nanocomposite Supercapacitor Materials II (Springer Cham, New York, 2020). https://doi.org/10.1007/978-3-030-43009-2

71.

K.K. Kar (ed.), Handbook of Nanocomposite Supercapacitor Materials II (Springer Cham, New York, 2020). https://doi.org/10.1007/978-3-030-52359-6

72.

K.K. Kar (ed.), Handbook of Nanocomposite Supercapacitor Materials III (Springer Cham, New York, 2021). https://doi.org/10.1007/978-3-030-68364-1

73.

S.K. Xu, G.D. Wei, J.Z. Li, J. Li, W. Han, Y. Gogotsi, Flexible MXene–graphene electrodes with high volumetric capacitance for integrated co-cathode energy conversion/storage devices. J. Mater. Chem. A. 5, 17442–17451 (2017). https://doi.org/10.1039/C7TA05721K CrossRef

74.

Z.M. Fan, Y.S. Wang, Z.M. Xie, D. Wang, Y. Yuan, H. Kang, B. Su, Z. Cheng, Y. Liu, Modified MXene/holey graphene films for advanced supercapacitor electrodes with superior energy storage. Adv. Sci. 5, 1800750 (2018). https://doi.org/10.1002/advs.201800750 CrossRef

75.

Q. Fu, X. Wang, N. Zhang, J. Wen, L. Li, H. Gao, X. Zhang, Self-assembled Ti ₃C ₂T _x/SCNT composite electrode with improved electrochemical performance for supercapacitor. J. Colloid Interface Sci. 511, 128–134 (2018). https://doi.org/10.1016/j.jcis.2017.09.104 CrossRef

76.

H. Li, R. Chen, M. Ali, H. Lee, M.J. Ko, In situ grown MWCNTs/MXenes nanocomposites on carbon cloth for high-performance flexible supercapacitors. Adv. Funct. Mater. 30, 2002739 (2020). https://doi.org/10.1002/adfm.202002739 CrossRef

77.

X. Yang, Q. Wang, K. Zhu, K. Ye, G. Wang, D. Cao, J. Yan, 3D porous oxidation-resistant MXene/graphene architectures induced by in situ zinc template toward high-performance supercapacitors. Adv. Funct. Mater. 31, 2101087 (2021). https://doi.org/10.1002/adfm.202101087 CrossRef

78.

Y. Gogotsi, Q. Huang, MXenes: two-dimensional building blocks for future materials and devices. ACS Nano 15, 5775–5780 (2021)

79.

Z. Wang, S. Qin, S. Seyedin, J. Zhang, J. Wang, A. Levitt, N. Li, C. Haines, R. Ovalle-Robles, W. Lei, Y. Gogotsi, R.H. Baughman, J.M. Razal, High-performance biscrolled mxene/carbon nanotube yarn supercapacitors. Small 14, 1802225 (2018). https://doi.org/10.1002/smll.201802225 CrossRef

80.

S. Uzun, S. Seyedin, A.L. Stoltzfus, A.S. Levitt, M. Alhabeb, M. Anayee, C.J. Strobel, J.M. Razal, G. Dion, Y. Gogotsi, Knittable and washable multifunctional mxene-coated cellulose yarns. Adv. Funct. Mater. 29, 1905015 (2019). https://doi.org/10.1002/adfm.201905015 CrossRef

Title: Emerging 2D Materials for Supercapacitors: MXenes
Authors: Shagufi Naz Ansari
Mohit Saraf
Shaikh M. Mobin
Publisher: Springer International Publishing
Book: Handbook of Nanocomposite Supercapacitor Materials IV
Print ISBN: 978-3-031-23700-3

Electronic ISBN: 978-3-031-23701-0

Copyright Year: 2023
DOI: https://doi.org/10.1007/978-3-031-23701-0_3