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Published in: Journal of Coatings Technology and Research 1/2020

08-08-2019

Enhanced corrosion resistance and weathering resistance of waterborne epoxy coatings with polyetheramine-functionalized graphene oxide

Authors: Jing Li, Wenwen Shan, Jincan Cui, Hanxun Qiu, Guangzhi Yang, Shiyou Zheng, Junhe Yang

Published in: Journal of Coatings Technology and Research | Issue 1/2020

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Abstract

Polyetheramine (D230), an epoxy curing agent, was grafted on graphene oxide (GO) surfaces, which can be stably dispersed in a waterborne curing agent for more than 8 months. Waterborne epoxy coatings reinforced by D230-functionalized GO (DGO) were prepared on carbon steel surfaces. According to the electrochemical impedance spectra, the impedance modulus at 0.1 Hz remained at 2.2 × 109 Ω after 150 days of immersion in 3.5% NaCl electrolytes for 0.2 wt% DGO-reinforced waterborne epoxy coatings, while that of the neat epoxy coatings dropped below 1 × 107 Ω after 10 days. Besides, the addition of DGO enhanced the weathering resistance of waterborne epoxy coatings. After 60 days of the UV aging test, the yellow color index of neat epoxy coatings was 1.6 times that of 0.5 wt% DGO/epoxy coatings. The residual pencil hardness of the 0.5 wt% DGO/epoxy coatings was three levels higher than that of neat epoxy coatings.

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Literature
1.
go back to reference Wang, SB, Ang, HM, Tade, MO, “Volatile Organic Compounds in Indoor Environment and Photocatalytic Oxidation: State of the Art.” Environ. Int., 33 (5) 694–705 (2007)CrossRef Wang, SB, Ang, HM, Tade, MO, “Volatile Organic Compounds in Indoor Environment and Photocatalytic Oxidation: State of the Art.” Environ. Int., 33 (5) 694–705 (2007)CrossRef
2.
go back to reference Harkal, UD, Muehlberg, AJ, Edwards, PA, Webster, DC, “Novel Water-Dispersible Glycidyl Carbamate (GC) Resins and Waterborne Amine-Cured Coatings.” J. Coat. Technol. Res., 8 (6) 735–747 (2011)CrossRef Harkal, UD, Muehlberg, AJ, Edwards, PA, Webster, DC, “Novel Water-Dispersible Glycidyl Carbamate (GC) Resins and Waterborne Amine-Cured Coatings.” J. Coat. Technol. Res., 8 (6) 735–747 (2011)CrossRef
3.
go back to reference Yu, J, Pan, H, Zhou, X, “Preparation of Waterborne Phosphated Acrylate-Epoxy Hybrid Dispersions and Their Application as Coil Coating Primer.” J. Coat. Technol. Res., 11 (3) 361–369 (2014)CrossRef Yu, J, Pan, H, Zhou, X, “Preparation of Waterborne Phosphated Acrylate-Epoxy Hybrid Dispersions and Their Application as Coil Coating Primer.” J. Coat. Technol. Res., 11 (3) 361–369 (2014)CrossRef
4.
go back to reference Wang, Z, Han, E, Liu, F, Qian, Z, Zhu, L, “Waterborne Epoxy Nanocoatings Modified by Nanoemulsions and Nanoparticles.” J. Mater. Sci. Technol., 30 (10) 1036–1042 (2014)CrossRef Wang, Z, Han, E, Liu, F, Qian, Z, Zhu, L, “Waterborne Epoxy Nanocoatings Modified by Nanoemulsions and Nanoparticles.” J. Mater. Sci. Technol., 30 (10) 1036–1042 (2014)CrossRef
5.
go back to reference Ai, L, Liu, Y, Zhang, XY, Ouyang, XH, Ge, ZY, “A Facile and Template-Free Method for Preparation of Polythiophene Microspheres and Their Dispersion for Waterborne Corrosion Protection Coatings.” Synth. Met., 191 41–46 (2014)CrossRef Ai, L, Liu, Y, Zhang, XY, Ouyang, XH, Ge, ZY, “A Facile and Template-Free Method for Preparation of Polythiophene Microspheres and Their Dispersion for Waterborne Corrosion Protection Coatings.” Synth. Met., 191 41–46 (2014)CrossRef
6.
go back to reference Rahman, OU, Kashif, M, Ahmad, S, “Nanoferrite Dispersed Waterborne Epoxy-Acrylate: Anticorrosive Nanocomposite Coatings.” Prog. Org. Coat., 80 77–86 (2015)CrossRef Rahman, OU, Kashif, M, Ahmad, S, “Nanoferrite Dispersed Waterborne Epoxy-Acrylate: Anticorrosive Nanocomposite Coatings.” Prog. Org. Coat., 80 77–86 (2015)CrossRef
7.
go back to reference Chang, K-C, Lu, H-I, Peng, C-W, Lai, M-C, Hsu, S-C, Hsu, M-H, Tsai, Y-K, Chang, C-H, Hung, W-I, Wei, Y, Yeh, J-M, “Nanocasting Technique to Prepare Lotus-Leaf-Like Superhydrophobic Electroactive Polyimide as Advanced Anticorrosive Coatings.” ACS Appl. Mater. Interfaces, 5 (4) 1460–1467 (2013)CrossRef Chang, K-C, Lu, H-I, Peng, C-W, Lai, M-C, Hsu, S-C, Hsu, M-H, Tsai, Y-K, Chang, C-H, Hung, W-I, Wei, Y, Yeh, J-M, “Nanocasting Technique to Prepare Lotus-Leaf-Like Superhydrophobic Electroactive Polyimide as Advanced Anticorrosive Coatings.” ACS Appl. Mater. Interfaces, 5 (4) 1460–1467 (2013)CrossRef
8.
go back to reference Zhang, F, Zhang, C, Song, L, Zeng, R, Li, S, Cui, H, “Fabrication of the Superhydrophobic Surface on Magnesium Alloy and Its Corrosion Resistance.” J. Mater. Sci. Technol., 31 (11) 1139–1143 (2015)CrossRef Zhang, F, Zhang, C, Song, L, Zeng, R, Li, S, Cui, H, “Fabrication of the Superhydrophobic Surface on Magnesium Alloy and Its Corrosion Resistance.” J. Mater. Sci. Technol., 31 (11) 1139–1143 (2015)CrossRef
9.
go back to reference Ramezanzadeh, B, Haeri, Z, Ramezanzadeh, M, “A Facile Route of Making Silica Nanoparticles-Covered Graphene Oxide Nanohybrids (SiO2-GO); Fabrication of SiO2-GO/Epoxy Composite Coating with Superior Barrier and Corrosion Protection Performance.” Chem. Eng. J., 303 511–528 (2016)CrossRef Ramezanzadeh, B, Haeri, Z, Ramezanzadeh, M, “A Facile Route of Making Silica Nanoparticles-Covered Graphene Oxide Nanohybrids (SiO2-GO); Fabrication of SiO2-GO/Epoxy Composite Coating with Superior Barrier and Corrosion Protection Performance.” Chem. Eng. J., 303 511–528 (2016)CrossRef
10.
go back to reference Conradi, M, Kocijan, A, Kek-Merl, D, Zorko, M, Verpoest, I, “Mechanical and Anticorrosion Properties of Nanosilica-Filled Epoxy-Resin Composite Coatings.” Appl. Surf. Sci., 292 432–437 (2014)CrossRef Conradi, M, Kocijan, A, Kek-Merl, D, Zorko, M, Verpoest, I, “Mechanical and Anticorrosion Properties of Nanosilica-Filled Epoxy-Resin Composite Coatings.” Appl. Surf. Sci., 292 432–437 (2014)CrossRef
11.
go back to reference Wang, N, Fu, W, Zhang, J, Li, X, Fang, Q, “Corrosion Performance of Waterborne Epoxy Coatings Containing Polyethylenimine Treated Mesoporous-TiO2 Nanoparticles on Mild Steel.” Prog. Org. Coat., 89 114–122 (2015)CrossRef Wang, N, Fu, W, Zhang, J, Li, X, Fang, Q, “Corrosion Performance of Waterborne Epoxy Coatings Containing Polyethylenimine Treated Mesoporous-TiO2 Nanoparticles on Mild Steel.” Prog. Org. Coat., 89 114–122 (2015)CrossRef
12.
go back to reference Cui, M, Ren, S, Chen, J, Liu, S, Zhang, G, Zhao, H, Wang, L, Xue, Q, “Anticorrosive Performance of Waterborne Epoxy Coatings Containing Water-Dispersible Hexagonal Boron Nitride (h-BN) Nanosheets.” Appl. Surf. Sci., 397 77–86 (2017)CrossRef Cui, M, Ren, S, Chen, J, Liu, S, Zhang, G, Zhao, H, Wang, L, Xue, Q, “Anticorrosive Performance of Waterborne Epoxy Coatings Containing Water-Dispersible Hexagonal Boron Nitride (h-BN) Nanosheets.” Appl. Surf. Sci., 397 77–86 (2017)CrossRef
13.
go back to reference Li, J, Gan, L, Liu, Y, Mateti, S, Lei, W, Chen, Y, Yang, J, “Boron Nitride Nanosheets Reinforced Waterborne Polyurethane Coatings for Improving Corrosion Resistance and Antifriction Properties.” Eur. Polym. J., 104 57–63 (2018)CrossRef Li, J, Gan, L, Liu, Y, Mateti, S, Lei, W, Chen, Y, Yang, J, “Boron Nitride Nanosheets Reinforced Waterborne Polyurethane Coatings for Improving Corrosion Resistance and Antifriction Properties.” Eur. Polym. J., 104 57–63 (2018)CrossRef
14.
go back to reference Liu, S, Gu, L, Zhao, H, Chen, J, Yu, H, “Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings.” J. Mater. Sci. Technol., 32 (5) 425–431 (2016)CrossRef Liu, S, Gu, L, Zhao, H, Chen, J, Yu, H, “Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings.” J. Mater. Sci. Technol., 32 (5) 425–431 (2016)CrossRef
15.
go back to reference Gu, L, Liu, S, Zhao, H, Yu, H, “Facile Preparation of Water-Dispersible Graphene Sheets Stabilized by Carboxylated Oligoanilines and Their Anticorrosion Coatings.” ACS Appl. Mater. Interfaces, 7 (32) 17641–17648 (2015)CrossRef Gu, L, Liu, S, Zhao, H, Yu, H, “Facile Preparation of Water-Dispersible Graphene Sheets Stabilized by Carboxylated Oligoanilines and Their Anticorrosion Coatings.” ACS Appl. Mater. Interfaces, 7 (32) 17641–17648 (2015)CrossRef
16.
go back to reference Li, Y, Yang, Z, Qiu, H, Dai, Y, Zheng, Q, Li, J, Yang, J, “Self-Aligned Graphene as Anticorrosive Barrier in Waterborne Polyurethane Composite Coatings.” J. Mater. Chem. A, 2 (34) 14139–14145 (2014)CrossRef Li, Y, Yang, Z, Qiu, H, Dai, Y, Zheng, Q, Li, J, Yang, J, “Self-Aligned Graphene as Anticorrosive Barrier in Waterborne Polyurethane Composite Coatings.” J. Mater. Chem. A, 2 (34) 14139–14145 (2014)CrossRef
17.
go back to reference Li, J, Cui, J, Yang, J, Li, Y, Qiu, H, Yang, J, “Reinforcement of Graphene and Its Derivatives on the Anticorrosive Properties of Waterborne Polyurethane Coatings.” Compos. Sci. Technol., 129 30–37 (2016)CrossRef Li, J, Cui, J, Yang, J, Li, Y, Qiu, H, Yang, J, “Reinforcement of Graphene and Its Derivatives on the Anticorrosive Properties of Waterborne Polyurethane Coatings.” Compos. Sci. Technol., 129 30–37 (2016)CrossRef
18.
go back to reference Li, H, Wen, J, Yu, R, Meng, J, Wang, C, Wang, C, Sun, S, “Facile Synthesis of a Nanocomposite Based on Graphene and ZnAl Layered Double Hydroxides as a Portable Shelf of a Luminescent Sensor for DNA Detection.” RSC Adv., 5 (13) 9341–9347 (2015)CrossRef Li, H, Wen, J, Yu, R, Meng, J, Wang, C, Wang, C, Sun, S, “Facile Synthesis of a Nanocomposite Based on Graphene and ZnAl Layered Double Hydroxides as a Portable Shelf of a Luminescent Sensor for DNA Detection.” RSC Adv., 5 (13) 9341–9347 (2015)CrossRef
19.
go back to reference Cui, M, Ren, S, Zhao, H, Xue, Q, Wang, L, “Polydopamine Coated Graphene Oxide for Anticorrosive Reinforcement of Water-Borne Epoxy Coating.” Chem. Eng. J., 335 255–266 (2018)CrossRef Cui, M, Ren, S, Zhao, H, Xue, Q, Wang, L, “Polydopamine Coated Graphene Oxide for Anticorrosive Reinforcement of Water-Borne Epoxy Coating.” Chem. Eng. J., 335 255–266 (2018)CrossRef
20.
go back to reference Chen, C, He, Y, Xiao, G, Zhong, F, Li, H, Wu, Y, Chen, J, “Synergistic Effect of Graphene Oxide@phosphate-Intercalated Hydrotalcite for Improved Anti-Corrosion and Self-Healable Protection of Waterborne Epoxy Coating in Salt Environments.” J. Mater. Chem. C, 7 (8) 2318–2326 (2019)CrossRef Chen, C, He, Y, Xiao, G, Zhong, F, Li, H, Wu, Y, Chen, J, “Synergistic Effect of Graphene Oxide@phosphate-Intercalated Hydrotalcite for Improved Anti-Corrosion and Self-Healable Protection of Waterborne Epoxy Coating in Salt Environments.” J. Mater. Chem. C, 7 (8) 2318–2326 (2019)CrossRef
21.
go back to reference Jiang, F, Zhao, W, Wu, Y, Wu, Y, Liu, G, Dong, J, Zhou, K, “A Polyethyleneimine-Grafted Graphene Oxide Hybrid Nanomaterial: Synthesis and Anti-Corrosion Applications.” Appl. Surf. Sci., 479 963–973 (2019)CrossRef Jiang, F, Zhao, W, Wu, Y, Wu, Y, Liu, G, Dong, J, Zhou, K, “A Polyethyleneimine-Grafted Graphene Oxide Hybrid Nanomaterial: Synthesis and Anti-Corrosion Applications.” Appl. Surf. Sci., 479 963–973 (2019)CrossRef
22.
go back to reference Alhumade, H, Yu, A, Elkamel, A, Simon, L, Abdala, A, “Enhanced Protective Properties and UV Stability of Epoxy/Graphene Nanocomposite Coating on Stainless Steel.” Express Polym. Lett., 10 (12) 1034–1046 (2016)CrossRef Alhumade, H, Yu, A, Elkamel, A, Simon, L, Abdala, A, “Enhanced Protective Properties and UV Stability of Epoxy/Graphene Nanocomposite Coating on Stainless Steel.” Express Polym. Lett., 10 (12) 1034–1046 (2016)CrossRef
23.
go back to reference Awaja, F, Pigram, PJ, “Surface Molecular Characterisation of Different Epoxy Resin Composites Subjected to UV Accelerated Degradation Using XPS and ToF-SIMS.” Polym. Degrad. Stab., 94 (4) 651–658 (2009)CrossRef Awaja, F, Pigram, PJ, “Surface Molecular Characterisation of Different Epoxy Resin Composites Subjected to UV Accelerated Degradation Using XPS and ToF-SIMS.” Polym. Degrad. Stab., 94 (4) 651–658 (2009)CrossRef
24.
go back to reference Ghasemi-Kahrizsangi, A, Neshati, J, Shariatpanahi, H, Akbarinezhad, E, “Improving the UV Degradation Resistance of Epoxy Coatings Using Modified Carbon Black Nanoparticles.” Prog. Org. Coat., 85 199–207 (2015)CrossRef Ghasemi-Kahrizsangi, A, Neshati, J, Shariatpanahi, H, Akbarinezhad, E, “Improving the UV Degradation Resistance of Epoxy Coatings Using Modified Carbon Black Nanoparticles.” Prog. Org. Coat., 85 199–207 (2015)CrossRef
25.
go back to reference Woo, RSC, Chen, Y, Zhu, H, Li, J, Kim, J-K, Leung, CKY, “Environmental Degradation of Epoxy-Organoclay Nanocomposites Due to UV Exposure. Part 1: Photo-Degradation.” Compos. Sci. Technol., 67 (15–16) 3448–3456 (2007)CrossRef Woo, RSC, Chen, Y, Zhu, H, Li, J, Kim, J-K, Leung, CKY, “Environmental Degradation of Epoxy-Organoclay Nanocomposites Due to UV Exposure. Part 1: Photo-Degradation.” Compos. Sci. Technol., 67 (15–16) 3448–3456 (2007)CrossRef
26.
go back to reference Asmatulu, R, Mahmud, GA, Hille, C, Misak, HE, “Effects of UV Degradation on Surface Hydrophobicity, Crack, and Thickness of MWCNT-Based Nanocomposite Coatings.” Prog. Org. Coat., 72 (3) 553–561 (2011)CrossRef Asmatulu, R, Mahmud, GA, Hille, C, Misak, HE, “Effects of UV Degradation on Surface Hydrophobicity, Crack, and Thickness of MWCNT-Based Nanocomposite Coatings.” Prog. Org. Coat., 72 (3) 553–561 (2011)CrossRef
27.
go back to reference Li, J, Yang, Z, Qiu, H, Dai, Y, Zheng, Q, Zheng, G-P, Yang, J, “Microwave-Assisted Simultaneous Reduction and Titanate Treatment of Graphene Oxide.” J. Mater. Chem. A, 1 (37) 11451–11456 (2013)CrossRef Li, J, Yang, Z, Qiu, H, Dai, Y, Zheng, Q, Zheng, G-P, Yang, J, “Microwave-Assisted Simultaneous Reduction and Titanate Treatment of Graphene Oxide.” J. Mater. Chem. A, 1 (37) 11451–11456 (2013)CrossRef
28.
go back to reference Li, J, Lin, H, Yang, Z, Li, J, “A Method for the Catalytic Reduction of Graphene Oxide at Temperatures Below 150°C.” Carbon, 49 (9) 3024–3030 (2011)CrossRef Li, J, Lin, H, Yang, Z, Li, J, “A Method for the Catalytic Reduction of Graphene Oxide at Temperatures Below 150°C.” Carbon, 49 (9) 3024–3030 (2011)CrossRef
29.
go back to reference Guan, L-Z, Wan, Y-J, Gong, L-X, Yan, D, Tang, L-C, Wu, L-B, Jiang, J-X, Lai, G-Q, “Toward Effective and Tunable Interphases in Graphene Oxide/Epoxy Composites by Grafting Different Chain Lengths of Polyetheramine Onto Graphene Oxide.” J. Mater. Chem. A, 2 (36) 15058–15069 (2014)CrossRef Guan, L-Z, Wan, Y-J, Gong, L-X, Yan, D, Tang, L-C, Wu, L-B, Jiang, J-X, Lai, G-Q, “Toward Effective and Tunable Interphases in Graphene Oxide/Epoxy Composites by Grafting Different Chain Lengths of Polyetheramine Onto Graphene Oxide.” J. Mater. Chem. A, 2 (36) 15058–15069 (2014)CrossRef
30.
go back to reference Tang, G, Jiang, Z-G, Li, X, Zhang, H-B, Hong, S, Yu, Z-Z, “Electrically Conductive Rubbery Epoxy/Diamine-Functionalized Graphene Nanocomposites with Improved Mechanical Properties.” Compos. Part B-Eng., 67 564–570 (2014)CrossRef Tang, G, Jiang, Z-G, Li, X, Zhang, H-B, Hong, S, Yu, Z-Z, “Electrically Conductive Rubbery Epoxy/Diamine-Functionalized Graphene Nanocomposites with Improved Mechanical Properties.” Compos. Part B-Eng., 67 564–570 (2014)CrossRef
31.
go back to reference Giray, D, Balkan, T, Dietzel, B, Sarac, A-S, “Electrochemical Impedance Study on Nanofibers of Poly(m-anthranilic acid)/Polyacrylonitrile Blends.” Eur. Polym. J., 49 2645–2653 (2013)CrossRef Giray, D, Balkan, T, Dietzel, B, Sarac, A-S, “Electrochemical Impedance Study on Nanofibers of Poly(m-anthranilic acid)/Polyacrylonitrile Blends.” Eur. Polym. J., 49 2645–2653 (2013)CrossRef
32.
go back to reference Chunsheng, L, Yiu-Wing, M, “Influence of Aspect Ratio on Barrier Properties of Polymer-Clay Nanocomposites.” Phys. Rev. Lett., 95 (8) 088303 (2005)CrossRef Chunsheng, L, Yiu-Wing, M, “Influence of Aspect Ratio on Barrier Properties of Polymer-Clay Nanocomposites.” Phys. Rev. Lett., 95 (8) 088303 (2005)CrossRef
33.
go back to reference Li, J, Ma, PC, Chow, WS, Chi, KT, Kim, JK, “Correlations Between Percolation Threshold, Dispersion State, and Aspect Ratio of Carbon Nanotubes.” Adv. Funct. Mater., 17 (16) 3207–3215 (2010)CrossRef Li, J, Ma, PC, Chow, WS, Chi, KT, Kim, JK, “Correlations Between Percolation Threshold, Dispersion State, and Aspect Ratio of Carbon Nanotubes.” Adv. Funct. Mater., 17 (16) 3207–3215 (2010)CrossRef
34.
go back to reference Rabek, JF, Polymer Photodegradation: Mechanisms and Experimental Methods. Springer, London (2012) Rabek, JF, Polymer Photodegradation: Mechanisms and Experimental Methods. Springer, London (2012)
35.
go back to reference Paredes, JI, Villar-Rodil, S, Martínez-Alonso, A, Tascón, JMD, “Graphene Oxide Dispersions in Organic Solvents.” Langmuir, 24 (19) 10560–10564 (2008)CrossRef Paredes, JI, Villar-Rodil, S, Martínez-Alonso, A, Tascón, JMD, “Graphene Oxide Dispersions in Organic Solvents.” Langmuir, 24 (19) 10560–10564 (2008)CrossRef
Metadata
Title
Enhanced corrosion resistance and weathering resistance of waterborne epoxy coatings with polyetheramine-functionalized graphene oxide
Authors
Jing Li
Wenwen Shan
Jincan Cui
Hanxun Qiu
Guangzhi Yang
Shiyou Zheng
Junhe Yang
Publication date
08-08-2019
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 1/2020
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-019-00252-z

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