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Published in: International Journal of Plastics Technology 1/2018

11-05-2018 | Research Article

Enhanced properties of poly(vinyl alcohol) composite films filled with microfibrillated cellulose isolated from continuous steam explosion

Authors: Achmad Solikhin, Kazushige Murayama

Published in: International Journal of Plastics Technology | Issue 1/2018

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Abstract

The objective of this research was to analyze the enhanced properties of poly(vinyl alcohol) composite films reinforced with microfibrillated cellulose obtained from continuous steam-explosion. Irregular and unsmooth external surfaces were observed in PVA/MFC composite films along with the high incorporation of MFC concentration. Voids and aggregates localized in PVA/MFC composite films induced the fractures of the films. Opacity of the obtained films increased with the high inclusion of MFC. However, all the tested composite films had higher transmittance of above 50% at visible wavelength of above 400 nm. Oxygen increased and N decreased with the incorporation of high MFC concentration. Chemical functional groups were changed due to intermolecular linkages between PVA and MFC. PVA/MFC composite films had good thermal stability with higher temperature of melting point and maximum degradation than neat PVA film. PVA matrix reinforced with MFC 5% had the highest tensile strength because of percolation network in the films during intercalation and exfoliation process. PVA/MFC composite films have the potential as food packaging plastics because of these above enhanced properties.

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Literature
1.
go back to reference Silvério HA, Neto WPF, Pasquini D (2013) Effect of incorporating cellulose nanocrystals from corncob on the tensile, thermal and barrier properties of poly(vinyl alcohol) nanocomposites. J Nanomater 2013:1–9CrossRef Silvério HA, Neto WPF, Pasquini D (2013) Effect of incorporating cellulose nanocrystals from corncob on the tensile, thermal and barrier properties of poly(vinyl alcohol) nanocomposites. J Nanomater 2013:1–9CrossRef
2.
go back to reference Zheng Q, Cai Z, Gong S (2014) Green synthesis of polyvinyl alcohol (PVA)–cellulose nanofibril (CNF) hybrid aerogels and their use as superabsorbents. J Mater Chem A 2:3110–3118CrossRef Zheng Q, Cai Z, Gong S (2014) Green synthesis of polyvinyl alcohol (PVA)–cellulose nanofibril (CNF) hybrid aerogels and their use as superabsorbents. J Mater Chem A 2:3110–3118CrossRef
3.
go back to reference Gaaz TS, Sulong AB, Akhtar MN, Kadhum AAH, Mohamad AB, Al-Amiery AA (2015) Properties and applications of polyvinyl alcohol, halloysite nanotubes and their nanocomposites. Molecules 20:22833–22847CrossRefPubMed Gaaz TS, Sulong AB, Akhtar MN, Kadhum AAH, Mohamad AB, Al-Amiery AA (2015) Properties and applications of polyvinyl alcohol, halloysite nanotubes and their nanocomposites. Molecules 20:22833–22847CrossRefPubMed
4.
go back to reference Liu F, Ni Q-Q, Murakami Y (2015) Preparation of magnetic polyvinyl alcohol composite nanofibers with homogenously dispersed nanoparticles and high water resistance. Text Res J 83:510–518CrossRef Liu F, Ni Q-Q, Murakami Y (2015) Preparation of magnetic polyvinyl alcohol composite nanofibers with homogenously dispersed nanoparticles and high water resistance. Text Res J 83:510–518CrossRef
5.
go back to reference Ibrahim MM, El-Zawawy WK, Nassar MA (2010) Synthesis and characterization of polyvinyl alcohol/nanospherical cellulose particle films. Carbohydr Polym 79:694–699CrossRef Ibrahim MM, El-Zawawy WK, Nassar MA (2010) Synthesis and characterization of polyvinyl alcohol/nanospherical cellulose particle films. Carbohydr Polym 79:694–699CrossRef
6.
go back to reference Tan BK, Ching YC, Poh SC, Abdullah LC, Gan SN (2015) A review of natural fiber reinforced poly(vinyl alcohol) based composites: application and opportunity. Polymers 7:2205–2222CrossRef Tan BK, Ching YC, Poh SC, Abdullah LC, Gan SN (2015) A review of natural fiber reinforced poly(vinyl alcohol) based composites: application and opportunity. Polymers 7:2205–2222CrossRef
7.
go back to reference Niu Y, Zhang X, He X, Zhao J, Zhang W, Lu C (2015) Effective dispersion and crosslinking in PVA/cellulose fiber biocomposites via solid-state mechanochemistry. Int J Biol Macromol 72:855–861CrossRefPubMed Niu Y, Zhang X, He X, Zhao J, Zhang W, Lu C (2015) Effective dispersion and crosslinking in PVA/cellulose fiber biocomposites via solid-state mechanochemistry. Int J Biol Macromol 72:855–861CrossRefPubMed
8.
go back to reference Peresin MS, Habibi Y, Zoppe JO, Pawlak JJ, Rojas OJ (2010) Nanofiber composites of polyvinyl alcohol and cellulose nanocrystals: manufacture and characterization. Biomacromolecules 11:674–681CrossRefPubMed Peresin MS, Habibi Y, Zoppe JO, Pawlak JJ, Rojas OJ (2010) Nanofiber composites of polyvinyl alcohol and cellulose nanocrystals: manufacture and characterization. Biomacromolecules 11:674–681CrossRefPubMed
9.
go back to reference Peresin MS, Vesterinen A-H, Habibi Y, Johansson L-S, Pawlak JJ, Nevzorov AA, Rojas OJ (2014) Crosslinked PVA nanofibers reinforced with cellulose nanocrystals water interactions and thermomechanical properties. J Appl Polym Sci 2014:1–12 Peresin MS, Vesterinen A-H, Habibi Y, Johansson L-S, Pawlak JJ, Nevzorov AA, Rojas OJ (2014) Crosslinked PVA nanofibers reinforced with cellulose nanocrystals water interactions and thermomechanical properties. J Appl Polym Sci 2014:1–12
10.
go back to reference Sutka A, Antsov M, Jarvekulg M, Visnapuu M, Heinmaa I, Maeorg U, Vlassov S, Sutka A (2016) Mechanical properties of individual fiber segments of electrospun lignocellulose-reinforced poly(vinyl alcohol). J Appl Polym Sci 2016:1–8 Sutka A, Antsov M, Jarvekulg M, Visnapuu M, Heinmaa I, Maeorg U, Vlassov S, Sutka A (2016) Mechanical properties of individual fiber segments of electrospun lignocellulose-reinforced poly(vinyl alcohol). J Appl Polym Sci 2016:1–8
12.
go back to reference Ibrahim MM, El-Zawawy WK, Nassar MA (2010) Synthesis and characterization of polyvinyl alcohol/nanospherical cellulose particle films. Carbohydr Polym 79:694–699CrossRef Ibrahim MM, El-Zawawy WK, Nassar MA (2010) Synthesis and characterization of polyvinyl alcohol/nanospherical cellulose particle films. Carbohydr Polym 79:694–699CrossRef
13.
go back to reference Mansour AF, Mansour SF, Abdo MA (2015) Improvement structural and optical properties of ZnO/PVA nanocomposites. IOSR J Appl Phys 7:60–69 Mansour AF, Mansour SF, Abdo MA (2015) Improvement structural and optical properties of ZnO/PVA nanocomposites. IOSR J Appl Phys 7:60–69
14.
go back to reference Shehata N, Gaballah S, Samir E, Hamed A, Saad M (2016) Fluorescent nanocomposite of embedded ceria nanoparticles in crosslinked PVA electrospun nanofibers. Nanomaterials 6:102–112CrossRefPubMedCentral Shehata N, Gaballah S, Samir E, Hamed A, Saad M (2016) Fluorescent nanocomposite of embedded ceria nanoparticles in crosslinked PVA electrospun nanofibers. Nanomaterials 6:102–112CrossRefPubMedCentral
15.
go back to reference Spence KL, Venditti RA, Habibi Y, Orlando JR, Joel JP (2010) The effect of chemical composition on microfibrillar cellulose films from wood pulps: mechanical processing and physical properties. Bioresour Technol 101:5961–5968CrossRefPubMed Spence KL, Venditti RA, Habibi Y, Orlando JR, Joel JP (2010) The effect of chemical composition on microfibrillar cellulose films from wood pulps: mechanical processing and physical properties. Bioresour Technol 101:5961–5968CrossRefPubMed
16.
go back to reference Henriksson M, Henriksson G, Berglund LA, Lindstrom T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Euro. Polym J 43:3434–3441 Henriksson M, Henriksson G, Berglund LA, Lindstrom T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Euro. Polym J 43:3434–3441
17.
go back to reference Joonobi M, Harun J, Shakeri A, Misra M, Oksman K (2009) Chemical composition, crystallinity, and thermal degradation of bleached and bleached kenaf bast (Hibiscus canabius) pulp and nanofibers. BioResources 2:626–639 Joonobi M, Harun J, Shakeri A, Misra M, Oksman K (2009) Chemical composition, crystallinity, and thermal degradation of bleached and bleached kenaf bast (Hibiscus canabius) pulp and nanofibers. BioResources 2:626–639
18.
go back to reference Lavoine N, Desloges I, Dufresne A, Bras J (2012) Microfibrillated cellulose—its barrier properties and applications in cellulosic materials: A review. Carbohydr Polym 90:735–764CrossRefPubMed Lavoine N, Desloges I, Dufresne A, Bras J (2012) Microfibrillated cellulose—its barrier properties and applications in cellulosic materials: A review. Carbohydr Polym 90:735–764CrossRefPubMed
19.
go back to reference Lu J, Wang T, Drzal LT (2008) Preparation and properties of microfibrillated cellulose polyvinyl alcohol composite materials. Compos Part A Appl Sci Manuf 39(5):738–746CrossRef Lu J, Wang T, Drzal LT (2008) Preparation and properties of microfibrillated cellulose polyvinyl alcohol composite materials. Compos Part A Appl Sci Manuf 39(5):738–746CrossRef
20.
go back to reference Tanpichai S, Sampson MW, Eichhorn SJ (2013) Microfibrillated cellulose reinforced poly(vinyl alcohol) composites. Adv Mater Res 747:359–362CrossRef Tanpichai S, Sampson MW, Eichhorn SJ (2013) Microfibrillated cellulose reinforced poly(vinyl alcohol) composites. Adv Mater Res 747:359–362CrossRef
21.
go back to reference Solikhin A, Hadi YS, Massijaya MY, Nikmatin S (2017) Novel isolation of empty fruit bunch lignocellulose nanofibers using different vibration milling times-assisted multimechanical stages. Waste Biomass Valor 8(7):2451–2462CrossRef Solikhin A, Hadi YS, Massijaya MY, Nikmatin S (2017) Novel isolation of empty fruit bunch lignocellulose nanofibers using different vibration milling times-assisted multimechanical stages. Waste Biomass Valor 8(7):2451–2462CrossRef
23.
go back to reference Mandal A, Chakrabarty D (2015) Characterization of nanocellulose reinforced semi-interpenetratingpolymer network of poly(vinyl alcohol) and polyacrylamide composite films. Carbohydr Polym 134:240–250CrossRefPubMed Mandal A, Chakrabarty D (2015) Characterization of nanocellulose reinforced semi-interpenetratingpolymer network of poly(vinyl alcohol) and polyacrylamide composite films. Carbohydr Polym 134:240–250CrossRefPubMed
24.
go back to reference Miri NE, Achaby ME, Fihri A, Larzek M, Zahouily M, Abdelouahdi K, Barakat A, Solhy A (2016) Synergistic effect of ceelulose nanocrystals/graphene oxide nanosheets as functional hybrid nanofiller for enhancing properties of PVA nanocomposites. Carbohydr Polmes 137:239–248CrossRef Miri NE, Achaby ME, Fihri A, Larzek M, Zahouily M, Abdelouahdi K, Barakat A, Solhy A (2016) Synergistic effect of ceelulose nanocrystals/graphene oxide nanosheets as functional hybrid nanofiller for enhancing properties of PVA nanocomposites. Carbohydr Polmes 137:239–248CrossRef
25.
go back to reference Li W, Wu Q, Zhao X, Huang Z, Cao J, Li J, Liu S (2014) Enhanced thermal and mechanical properties of PVA compositesformed with filamentous nanocellulose fibrils. Carbohydr Polym 113:403–410CrossRefPubMed Li W, Wu Q, Zhao X, Huang Z, Cao J, Li J, Liu S (2014) Enhanced thermal and mechanical properties of PVA compositesformed with filamentous nanocellulose fibrils. Carbohydr Polym 113:403–410CrossRefPubMed
26.
go back to reference Rescignano N, Fortunati E, Montesano S, Emiliani C, Kenny JM, Martino S, Armentano I (2014) PVA bio-nanocomposites: a new take-off using cellulose nanocrystals and PLGA nanoparticles. Carbohydr Polym 99:47–58CrossRefPubMed Rescignano N, Fortunati E, Montesano S, Emiliani C, Kenny JM, Martino S, Armentano I (2014) PVA bio-nanocomposites: a new take-off using cellulose nanocrystals and PLGA nanoparticles. Carbohydr Polym 99:47–58CrossRefPubMed
27.
go back to reference Gonzales JS, Luduena LN, Ponce A, Alvarez VA (2014) Poly(vynil alcohol)/cellulose nanowhiskers nanocomposite hydrogels for potential wood dressing. Mater Sci Eng C 34:54–61CrossRef Gonzales JS, Luduena LN, Ponce A, Alvarez VA (2014) Poly(vynil alcohol)/cellulose nanowhiskers nanocomposite hydrogels for potential wood dressing. Mater Sci Eng C 34:54–61CrossRef
28.
go back to reference Priya B, Gupta VK, Pathania D, Singha AS (2014) Synthesis, characterization and antibacterial activity of biodegradable starch/PVA composite films reinforced with cellulosic fibre. Carbohydr Polym 109:171–179CrossRefPubMed Priya B, Gupta VK, Pathania D, Singha AS (2014) Synthesis, characterization and antibacterial activity of biodegradable starch/PVA composite films reinforced with cellulosic fibre. Carbohydr Polym 109:171–179CrossRefPubMed
29.
go back to reference Fortunati E, Puglia D, Luzi F, Santulli C, Kenny JM, Torre L (2013) Binary PVA bio-nanocomposites containing cellulose nanocrystals extracted from different natural resources: part I. Carnohydr Polym 97:825–836CrossRef Fortunati E, Puglia D, Luzi F, Santulli C, Kenny JM, Torre L (2013) Binary PVA bio-nanocomposites containing cellulose nanocrystals extracted from different natural resources: part I. Carnohydr Polym 97:825–836CrossRef
30.
go back to reference Kakroodi AR, Cheng S, Sain M, Asiri A (2014) Mehanical, thermal, and morphological properties of nanocomposites based on polyvinyl alcohol and cellulose nanofiber from Aloe vera Rind. J Nanomater 2014:1–7CrossRef Kakroodi AR, Cheng S, Sain M, Asiri A (2014) Mehanical, thermal, and morphological properties of nanocomposites based on polyvinyl alcohol and cellulose nanofiber from Aloe vera Rind. J Nanomater 2014:1–7CrossRef
Metadata
Title
Enhanced properties of poly(vinyl alcohol) composite films filled with microfibrillated cellulose isolated from continuous steam explosion
Authors
Achmad Solikhin
Kazushige Murayama
Publication date
11-05-2018
Publisher
Springer India
Published in
International Journal of Plastics Technology / Issue 1/2018
Print ISSN: 0972-656X
Electronic ISSN: 0975-072X
DOI
https://doi.org/10.1007/s12588-018-9208-9

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