Skip to main content
Top
Published in: Journal of Materials Science: Materials in Electronics 8/2019

27-03-2019

Enhanced structural, optical, electrochemical and magnetic behavior on manganese doped tin oxide nanoparticles via chemical precipitation method

Authors: S. Sivakumar, E. Manikandan

Published in: Journal of Materials Science: Materials in Electronics | Issue 8/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A series of Sn1−xMnxO2 (X = 0.00, 0.015, 0.025, 0.035 and 0.045 mol%) nanoparticles have been synthesized by effective chemical precipitation method. In this work to explore the structural, morphological, optical, electrochemical and magnetic properties of the pure and Manganese doped SnO2 nanoparticles are characterized on the TG/DTA, XRD, SEM/EDX, HR-TEM, FTIR, UV–DRS, PL, CV, and VSM analysis. XRD indicates that the tetragonal crystal structure, with the crystallite size of range from 37 to 11 nm. The structure, size, shape, and morphology analysis by SEM and HR-TEM was spherical shape is observed. FTIR studies on functional group analysis of pure and Manganese doped SnO2 nanoparticles. The peak appeared at 619 cm−1 due to O–Sn–O stretching vibration of clearly indicates the formation of SnO2 phase. UV–DRS absorption measures were the optical band gap energies decreasing with increasing Mn (0.00%, 0.015%, 0.025%, 0.035% and 0.045%) concentration from 3.89 to 3.75 eV. UV–DRS analyzed the mechanisms of electron–hole recombination and charge carriers separation. Further, the electrochemical properties were subsequently characterized by cyclic voltammetry. From the CV performance of the supercapacitor application was analyzed, the higher capacitance value of pure and Manganese (0.045%) doped SnO2 electrode 156.7 Fg−1 and 285.2 Fg−1 observed in the scan rate of 5 mV s−1 for the product calcinated at 700 °C. The M–H loop of pure SnO2 nanoparticles showed diamagnetism, Manganese doped SnO2 nanoparticles show weak ferromagnetic and paramagnetic behavior at room temperature as measured by VSM. A tin oxide with lower manganese concentration show larger magnetization and with increasing manganese concentration the retentivity and coercivity are found to decrease. The magnetic parameters such as saturation magnetization (MS), coercivity (HC) and retentivity (MR) are obtained from VSM data.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
40.
go back to reference M.H. Huang, Y. Wu, H. Feick, N. Tran, E. Weber, P. Yang, Adv. Mater. 13, 113–116 (2001)CrossRef M.H. Huang, Y. Wu, H. Feick, N. Tran, E. Weber, P. Yang, Adv. Mater. 13, 113–116 (2001)CrossRef
Metadata
Title
Enhanced structural, optical, electrochemical and magnetic behavior on manganese doped tin oxide nanoparticles via chemical precipitation method
Authors
S. Sivakumar
E. Manikandan
Publication date
27-03-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 8/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01076-8

Other articles of this Issue 8/2019

Journal of Materials Science: Materials in Electronics 8/2019 Go to the issue