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Cellulose
Published in: Cellulose 12/2017

16-10-2017 | Original Paper

Esterification of bagasse cellulose with metal salts as efficient catalyst in mechanical activation-assisted solid phase reaction system

Authors: Tao Gan, Yanjuan Zhang, Yang Su, Huayu Hu, Aimin Huang, Zuqiang Huang, Dong Chen, Mei Yang, Juan Wu

Published in: Cellulose | Issue 12/2017

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Abstract

The present study focused on investigating the catalytic mechanism of metal salts (sodium hypophosphite, sodium bisulfate and ammonium ferric sulfate) for esterification of bagasse cellulose carried out by mechanical activation-assisted solid phase reaction in a stirring ball mill. FTIR analysis of the products confirmed that these metal salts could catalyze the esterification of cellulose. XRD, SEM, FTIR, and 31P-NMR analyses of different samples indicated a synergistic effect between metal salt and ball milling, and the presence of metal salts enhanced the destruction on crystal structure of cellulose by mechanical force. The catalytic mechanism of three metal salts was difference: sodium bisulfate and ammonium ferric sulfate belonged to the catalytic mechanism of protonic acid and Lewis acid, respectively, while the catalytic mechanism of sodium hypophosphite was considered as that it could react with maleic acid to form active intermediates under ball milling.
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Appendix
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Metadata
Title
Esterification of bagasse cellulose with metal salts as efficient catalyst in mechanical activation-assisted solid phase reaction system
Authors
Tao Gan
Yanjuan Zhang
Yang Su
Huayu Hu
Aimin Huang
Zuqiang Huang
Dong Chen
Mei Yang
Juan Wu
Publication date
16-10-2017
Publisher
Springer Netherlands
Published in
Cellulose / Issue 12/2017
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1524-2

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