Top

Published in:

05-09-2017 | Metals

Evolution of ω phase during heating of metastable β titanium alloy Ti–15Mo

Authors: Pavel Zháňal, Petr Harcuba, Michal Hájek, Bohumil Smola, Josef Stráský, Jana Šmilauerová, Jozef Veselý, Miloš Janeček

Published in: Journal of Materials Science | Issue 1/2018

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Evolution of \(\omega \) phase during heating of metastable \(\beta \) titanium alloy Ti–15Mo was investigated in situ during heating by electrical resistance measurements and accompanied by transmission electron microscopy. Different heating rates were employed aiming to determine kinetics of occurring phase transformations. Sharp change of temperature dependence of electrical resistance caused by complete dissolution of \(\omega \) phase was observed at 560 \(^{\circ }\hbox {C}\) independently of heating rate. Majority of \(\omega _{\mathrm{iso}}\) particles revert back to \(\beta \) phase at 560 \(^{\circ }\hbox {C}\); therefore, they are not direct precursors of \(\alpha \) precipitation during continuous heating.

previous article Pitting corrosion behavior in novel Mn–N alloyed lean duplex stainless steel containing Cu

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Lütjering G, Williams JC (2007) Titanium. Engineering materials, processes. Springer, Berlin, pp 1–39. doi:10.1007/978-3-540-73036-1

Maeshima T, Nishida M (2004) Shape memory and mechanical properties of biomedical Ti–Sc–Mo alloys. Mater Trans 45(4):1101–1105. doi:10.2320/matertrans.45.1101 CrossRef

Duraccio D, Mussano F, Faga MG (2015) Biomaterials for dental implants: current and future trends. J Mater Sci 50(14):4779–4812. doi:10.1007/s10853-015-9056-3 CrossRef

Duerig TW, Williams JC (1984) In: Boyer RR, Rosenberg HW (eds) Beta-Titanium Alloys in the 1980’s. The Metallurgical Society of AIME, pp 19–69

Wang CH, Yang CD, Liu M, Li X, Hu PF, Russell AM, Cao GH (2016) Martensitic microstructures and mechanical properties of as-quenched metastable \(\beta \)-type Ti–Mo alloys. J Mater Sci 51(14):6886–6896. doi:10.1007/s10853-016-9976-6 CrossRef

Duerig TW, Albrecht J, Richter D, Fischer P (1982) Formation and reversion of stress induced martensite in Ti–10V–2Fe–3Al. Acta Metall 30(12):2161–2172. doi:10.1016/0001-6160(82)90137-7 CrossRef

Tang X, Ahmed T, Rack HJ (2000) Phase transformations in Ti–Nb–Ta and Ti–Nb–Ta–Zr alloys. J Mater Sci 35(7):1805–1811. doi:10.1023/A:1004792922155 CrossRef

Frost PD, Parris WM, Hirsch LL, Doig JR, Schwartz CM (1954) Isothermal transformation of titanium–chromium alloys. Trans Am Soc Met 46:231

Zheng Y, Williams RE, Sosa JM, Alam T, Wang Y, Banerjee R, Fraser HL (2016) The indirect influence of the \(\omega \) phase on the degree of refinement of distributions of the \(\alpha \) phase in metastable \(\beta \)-titanium alloys. Acta Mater 103:165–173. doi:10.1016/j.actamat.2015.09.053 CrossRef

10.

Zheng Y, Williams RE, Sosa JM, Wang Y, Banerjee R, Fraser HL (2016) The role of the \(\omega \) phase on the non-classical precipitation of the \(\alpha \) phase in metastable \(\beta \)-titanium alloys. Scripta Mater 111:81–84. doi:10.1016/j.scriptamat.2015.08.019 CrossRef

11.

Sikka SK, Vohra YK, Chidambaram R (1982) Omega phase in materials. Prog Mater Sci 27(3):245. doi:10.1016/0079-6425(82)90002-0 CrossRef

12.

Hickman BS (1969) The formation of omega phase in titanium and zirconium alloys: a review. J Mater Sci 4(6):554CrossRef

13.

Banerjee S, Mukhopadhyay P (2007) Phase transformations: examples from titanium and zirconium alloys. No. 12 in Pergamon materials seriesv. Elsevier, Pergamon

14.

Šmilauerová J, Harcuba P, Stráský J, Stráská J, Janeček M, Pospíšil J, Kužel R, Brunátová T, Holý V, Ilavský J (2014) Ordered array of \(\omega \) particles in \(\beta \)-Ti matrix studied by small-angle X-ray scattering. Acta Mater 81:71–82. doi:10.1016/j.actamat.2014.06.042 CrossRef

15.

Bagaryatskiy A, Yu I, Nosova G (1962) Phys Met Metallogr 13(3):92

16.

De Fontaine D, Paton NE, Williams JC (1971) The omega phase transformation in titanium alloys as an example of displacement controlled reactions. Acta Metall 19(11):1153. doi:10.1016/0001-6160(71)90047-2 CrossRef

17.

Zháňal P, Harcuba P, Šmilauerová J, Stráský J, Janeček M, Smola B, Hájek M (2015) Phase transformations in Ti–15Mo investigated by in situ electrical resistance. Acta Phys Pol A 128(4):779. doi:10.12693/APhysPolA.128.779 CrossRef

18.

Nejezchlebová J, Janovská M, Seiner H, Sedlák P, Landa M, Šmilauerová J, Stráský J, Harcuba P, Janeček M (2016) The effect of athermal and isothermal \(\omega \) phase particles on elasticity of \(\beta \)-Ti single crystals. Acta Mater 110:185–191. doi:10.1016/j.actamat.2016.03.033 CrossRef

19.

Froes F, Staff AI (2015) Titanium: physical metallurgy processing and applications. ASM International, New York

20.

Šmilauerová J, Harcuba P, Pospíšil J, Matěj Z, Holý V (2013) Growth of \(\omega \) inclusions in Ti alloys: an X-ray diffraction study. Acta Mater 61(17):6635–6645. doi:10.1016/j.actamat.2013.07.059 CrossRef

21.

Ohmori Y, Ogo T, Nakai K, Kobayashi S (2001) Effects of \(\omega \)-phase precipitation on \(\beta \rightarrow \alpha \), \(\alpha \)” transformations in a metastable \(\beta \) titanium alloy. Mater Sci Eng A 312(1):182. doi:10.1016/S0921-5093(00)01891-8 CrossRef

22.

Williams JC, Blackburn MJ (1969) The influence of Misfit on the morphology and stability of the omega phase in titanium–transition metal alloys. Trans Met Soc AIME 245:2352–2355

23.

Nag S, Banerjee R, Srinivasan R, Hwang JY, Harper M, Fraser HL (2009) \(\omega \)-Assisted nucleation and growth of \(\alpha \) precipitates in the Ti–5Al–5Mo–5V–3Cr–0.5Fe \(\beta \) titanium alloy. Acta Mater 57(7):2136. doi:10.1016/j.actamat.2009.01.007 CrossRef

24.

Li T, Kent D, Sha G, Stephenson LT, Ceguerra AV, Ringer SP, Dargusch MS, Cairney JM (2016) New insights into the phase transformations to isothermal \(\omega \) and \(\omega \)-assisted \(\alpha \) in near \(\beta \)-Ti alloys. Acta Mater 106:353–366. doi:10.1016/j.actamat.2015.12.046 CrossRef

25.

Prima F, Vermaut P, Texier G, Ansel D, Gloriant T (2006) Evidence of \(\alpha \)-nanophase heterogeneous nucleation from \(\omega \) particles in a \(\beta \)-metastable Ti-based alloy by high-resolution electron microscopy. Scripta Mater 54(4):645. doi:10.1016/j.scriptamat.2005.10.024 CrossRef

26.

Ho JC, Collings EW (1972) Anomalous electrical resistivity in titanium–molybdenum alloys. Phys Rev B 6(10):3727CrossRef

27.

Luhman TS, Taggart R, Polonis DH (1968) A resistance anomaly in beta stabilized Ti–Cr alloys. Scr Metall 2(3):169. doi:10.1016/0036-9748(68)90219-6 CrossRef

28.

Hake RR, Leslie DH, Berlincourt TG (1961) Electrical resistivity, Hall effect and superconductivity of some b.c.c. titanium–molybdenum alloys. J Phys Chem Solids 20(3):177. doi:10.1016/0022-3697(61)90002-6 CrossRef

29.

Komatsu SY, Ikeda M, Sugimoto T, Kamei K, Maesaki O, Kojima MA (1996) Aging behaviour of Ti15Mo5Zr and Ti15Mo5Zr3Al alloy up to 573 K. Mater Sci Eng A 213(1—-2):61–65. doi:10.1016/0921-5093(96)10228-8 CrossRef

30.

Sun F, Prima F, Gloriant T (2010) High-strength nanostructured Ti–12Mo alloy from ductile metastable beta state precursor. Mater Sci Eng A 527(16–17):4262–4269. doi:10.1016/j.msea.2010.03.044 CrossRef

31.

Hill MA, Polonis DH (1987) Influence of beta phase decomposition on the temperature coefficient of resistivity of titanium alloys. J Mater Sci 22(6):2181–2184. doi:10.1007/BF01132957 CrossRef

32.

Yoshida S, Tsuya Y (1956) The temperature dependence of the electrical resistivity of the \(\beta \)-phase titanium–molybdenum alloys. J Phys Soc Jpn 11(11):1206. doi:10.1143/JPSJ.11.1206 CrossRef

33.

Prima F, Debuigne J, Boliveau M, Ansel D (2000) Control of omega phase volume fraction precipitated in a beta titanium alloy: development of an experimental method. J Mater Sci Lett 19(24):2219CrossRef

34.

Hájek M, Veselý J, Cieslar M (2007) Precision of electrical resistivity measurements. Mater Sci Eng A 462(1–2):339–342. doi:10.1016/j.msea.2006.01.175 CrossRef

35.

Gloriant T, Texier G, Sun F, Thibon I, Prima F, Soubeyroux J (2008) Characterization of nanophase precipitation in a metastable \(\beta \) titanium-based alloy by electrical resistivity, dilatometry and neutron diffraction. Scripta Mater 58(4):271. doi:10.1016/j.scriptamat.2007.10.007 CrossRef

36.

Settefrati A, Aeby-Gautier E, Dehmas M, Geandier G, Appolaire B, Audion S, Delfosse J (2011) Precipitation in a near beta titanium alloy on ageing: influence of heating rate and chemical composition of the beta-metastable phase. Solid State Phenom 172–174:760–765. doi:10.4028/www.scientific.net/SSP.172-174.760 CrossRef

37.

Boeckels H (2012) Phase transformations in titanium–molybdenum–oxygen. Ph.D. thesis, Clemson University

38.

Barriobero-Vila P, Requena G, Warchomicka F, Stark A, Schell N, Buslaps T (2015) Phase transformation kinetics during continuous heating of a \(\beta \)-quenched Ti–10V–2Fe–3Al alloy. J Mater Sci 50(3):1412–1426. doi:10.1007/s10853-014-8701-6 CrossRef

39.

Donachie M (1988) Titanium: a technical guide. AMS International, New York

40.

Gemelli E, Camargo NHA (2007) Oxidation kinetics of commercially pure titanium. Matéria (Rio de Janeiro) 12(3):525–531. doi:10.1590/S1517-70762007000300014 CrossRef

41.

Prima F, Vermaut P, Thibon I, Ansel D, Debuigne J, Gloriant T (2002) Nanostructured metastable \(\beta \)-titanium based alloy. J Metastab Nanocrystal Mater 13:307. doi:10.4028/www.scientific.net/JMNM.13.307 CrossRef

42.

Takemoto Y, Hida M, Sakakibara A (1993) Mechanism of \(\omega \rightarrow \alpha \) transformation in \(\beta \)-Ti alloy. J Jpn Inst Met 57(3):261–267CrossRef

43.

Devaraj A, Nag S, Srinivasan R, Williams R, Banerjee S, Banerjee R, Fraser H (2012) Experimental evidence of concurrent compositional and structural instabilities leading to \(\omega \) precipitation in titanium–molybdenum alloys. Acta Mater 60(2):596. doi:10.1016/j.actamat.2011.10.008 CrossRef

44.

Schryvers D, Tanner L (1990) High resolution electron microscopy observations of athermal omega phase in Ti–Mo alloys. Mater Sci Forum 56–58:329. doi:10.4028/www.scientific.net/MSF.56-58.329 CrossRef

45.

Zháňal P, Harcuba P, Janeček M, Smilauerová J, Veselý J, Smola B, Zimina M (2016) In: Venkatesh V, Pilchak AL, Allison JE, Ankem S, Boyer R, Christodoulou J, Fraser HL, Imam MA, Kosaka Y, Rack HJ, Chatterjee A, Woodfield A (eds) Proceedings of the 13th world conference on titanium, TMS (The Minerals, Metals & Materials Society), pp 431–436

46.

Furuhara T, Makino T, Idei Y, Ishigaki H, Takada A, Maki T (1998) Morphology and crystallography of \(\alpha \) precipitates in \(\beta \) Ti–Mo binary alloys. Mater Trans JIM 39(1):31–39. doi:10.2320/matertrans1989.39.31 CrossRef

47.

Zheng Y, Williams REA, Wang D, Shi R, Nag S, Kami P, Sosa JM, Banerjee R, Wang Y, Fraser HL (2016) Role of \(\omega \) phase in the formation of extremely refined intragranular \(\alpha \) precipitates in metastable \(\beta \)-titanium alloys. Acta Mater 103:850–858. doi:10.1016/j.actamat.2015.11.020 CrossRef

Title: Evolution of ω phase during heating of metastable β titanium alloy Ti–15Mo
Authors: Pavel Zháňal
Petr Harcuba
Michal Hájek
Bohumil Smola
Josef Stráský
Jana Šmilauerová
Jozef Veselý
Miloš Janeček
Publication date: 05-09-2017
Publisher: Springer US
Published in: Journal of Materials Science / Issue 1/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-017-1519-2

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 1/2018

Synthesis of poly(m-phenylenediamine)-coated hexagonal Co9S8 for high-performance supercapacitors

Nitrogen-doped porous carbon derived from imidazole-functionalized polyhedral oligomeric silsesquioxane

Modeling and simulation of the effective strength of hybrid polymer composites reinforced by carbon and steel fibers

Efficient visible-light-driven photocatalytic hydrogen production from water by using Eosin Y-sensitized novel g-C3N4/Pt/GO composites

Preparation of TiO2/graphene composite with appropriate N-doping ratio for humic acid removal

A review of soft errors and the low α-solder bumping process in 3-D packaging technology

Premium Partners