Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Published in:
Porphyrins Read chapter Read first chapter

2013 | OriginalPaper | Chapter

2. Exohedral Metallofullerenes

Author : Oleksandr Loboda

Published in: Quantum-chemical studies on Porphyrins, Fullerenes and Carbon Nanostructures

Publisher: Springer Berlin Heidelberg

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Fullerene-based materials have attracted considerable interest since the discovery of C60. A promising area of research concerns metal–fullerene interactions and their application to advanced nano materials, with potential use in optical and switching devices, as photoconductors, and for hydrogen storage. Moreover, transition metal complexes of fullerenes show catalytic activity in homogeneous hydrogenation of acetylenic alcohols [1] and hydroformylation of alkenes [2]. In heterogeneous catalysis, exohedral metallofullerenes are found to promote hydrogenation of olefins and acetylenes [3, 4] as well as reduction of carbon monoxide to methane [5, 6].

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
previous chapter Porphyrins
next chapter Nonlinear Optical Properties of Fullerene Derivatives
Literature
1.
Sulman, E., Matveeva, V., Semagina, N., Yanov, I., Bashilov, V., Sokolov, V.: J. Mol. Catal. 146, 257 (1999)CrossRef
2.
3.
Nagashima, H., Nakaoka, A., Tajima, S., Saito, Y., Itoh, K.: Chem. Lett. 7, 1361 (1992)CrossRef
4.
Nagashima, H., Kato, Y., Yamaguchi, H., Kimura, E., Kawanishi, T., Kato, M.: Saito, Y., Haga, M., Itoh, K. Chem. Lett. 7, 1207 (1994)CrossRef
5.
Wohlers, M., Herzog, B., Belz, T., Bauer, A., Braun, T., Ruhle, T., Schlogl, R.: Synth. Met. 77, 55 (1996)CrossRef
6.
Braun, T., Wohlers, M., Belz, T., Nowitzke, G., Wormann, G., Uchida, Y.: Pfander, N., Schlogl, R. Catal. Lett. 43, 167 (1997)CrossRef
7.
Fagan, P., Calabrese, J., Malone, B.: Science 252, 1160 (1991)
8.
9.
Bashilov, V., Petrovskii, P., Sokolov, V., Lindeman, S., Guzey, I., Struchkov, Y.: Organometallics 12, 991 (1993)CrossRef
10.
Dresselhaus, M., Dresselhaus, G., Eklund, P.: Science of Fullerenes and Carbon Nanotubes. Academic press Inc., San Diego (1996)
11.
12.
Fagan, P.J., Calabrese, J.C., Malone, B.: J. Am. Chem. Soc. 113, 9408 (1991)CrossRef
13.
14.
15.
Lichtenberger, D., Wright, L., Gruhn, N., Rempe, M.: J. Organomet. Chem. 478, 213 (1994)CrossRef
16.
17.
Alemany, M., Dieguez, O., Rey, C., Gallego, L.: J. Chem. Phys. 114, 9371 (2001)CrossRef
18.
19.
20.
Dunning, T., Hay, P.: Methods of Electronic Structure Theory. In: Schaeffer, H. (ed.) Modern theoretical chemistry. Plenum Press, New York (1977)
21.
22.
23.
Andrae, D., Haeussermann, U., Dolg, M., Stoll, H.: Theor. Chim. Acta 77, 123 (1990)CrossRef
24.
25.
26.
Koch, W., Holthausen, M.: A Chemist’s Guide to Density Functional Theory. Wiley-VCH, Weinheim (2000)
27.
28.
Moore, C.: Atomic Energy Levels. NBS, Washington (1958)
29.
Glendening, E., Reed, A., Carpenter, J., Weinhold, F.: NBO Version 3.1. (2001)
30.
31.
32.
33.
Hedberg, K., Hedberg, L., Bethune, D., Brown, C., Dorn, H., Johnson, R., de Vries, M.: Science 254, 410 (1991)CrossRef
34.
Nunzi, F., Sgamellotti, A., Re, N., Floriani, C.: Organometallics 19, 1628 (2000)CrossRef
35.
Kameno, Y., Ikeda, A., Nakao, Y., Sato, H., Sakaki, S.: J. Phys. Chem. 109, 8055 (2005)CrossRef
36.
Campanera, J., Munoz, J., Vazquez, J., Bo, C., Poblet, J.: Inorg. Chem. 43, 6815 (2004)CrossRef
37.
38.
Hawkins, J., Meyer, A., Lewis, T., Loren, S., Hollander, F.: Science 252, 312 (1991)CrossRef
39.
40.
41.
42.
43.
Gates, B.: Catalytic Chemistry. Wiley, New York (1992)
44.
Blomberg, M., Siegbahn, P., Nagashima, U., Wennerberg, J.: J. Am. Chem. Soc. 113, 424 (1991)CrossRef
45.
46.
47.
48.
49.
50.
51.
Dewar, M.: Bull. Soc. Chim. Fr. p. 71(1951)
52.
53.
54.
Dresselhaus, M.S., Dresselhaus, G., Eklund, P.C.: Science of Fullerenes and Carbon Nanotubes. Academic Press, San Diego (1996)
55.
Nagashima, H., Nakaoka, A., Saito, Y., Kato, M., Kawanishi, T., Itoh, K.: The first organometallic polymer of buckminsterfullerene. J. Chem. Soc. Chem. Commun. 69, 377–379 (1992)CrossRef
56.
Nagashima, H., Kato, Y., Yamaguchi, H., Kimura, E., Kawanishi, T., Kato, M.: Haga, M., Itoh, K.: Synthesis and reactions of organoplatinum compounds of \(C_{60}, C_{60}Pt_n\). Chem. Lett. 7, 1207–1210 (1994) CrossRef
57.
Ivanova, V.N.: Fullerene compounds with transition metals \({\rm M}_{n}{\rm C}_{60}\): preparation, structure, and properties. J. Struct. Chem. 41, 135–148 (2000)CrossRef
58.
Wohlers, M., Herzog, B., Belz, T., Bauer, A., Braun, Th, Ruhle, Th, Schlogl, R.: Ruthenium-\({\rm C}_{60}\) compounds: Properties and catalytic potential. Synth. Met. 77, 55–58 (1996)CrossRef
59.
Talyzin, A.V., Jansson, U.: A comparative Raman study of some transition metal fullerides. Thin Solid Films 429, 96–101 (2003)CrossRef
60.
Alemany, M.M.G., Dieguez, O., Rey, C., Gallego, L.J.: A densityfunctional study of the structures and electronic properties of \(C_{59}\)Ni and \(C_{60}\)Ni clusters. J. Chem. Phys. 114, 9371–9374 (2001)CrossRef
61.
Andriotis, A.N., Menon, M.: Geometry and bonding in small (\(C_{60})_nNi_m\) clusters. Phys. Rev. B 60, 4521–4524 (1999)CrossRef
62.
Nagashima, H., Yamaguchi, H., Kato, Y., Saito, Y., Haga, M., Itoh, K.: Facile cleavage of carbon-palladium bonds in \(C_{60}Pd_n\) with phosphines and phosphites. An alternative route to (\(\eta ^{2}-C_{60})PdL_{2}\) and discovery of fluxionarity suggesting the rotation of \(C_{60}\) on the \(PdL_2\) species in solution. Chem. Lett. 12, 2153–2156 (1993)CrossRef
63.
Nagashima, H., Nakaoka, A., Tajima, S., Saito, Y., Itoh, K.: Catalytic hydrogenation of olefins and acetylenes over \({\rm C}_{60}{\text{ Pd}}_n\). Chem. Lett. 377, 1361–1364 (1992)CrossRef
64.
Andrae, D., Haeussermann, U., Dolg, M., Stoll, H., Preuss, H.: Energyadjusted ab initio pseudopotentials for the second and third row transition elements. Theor. Chim. Acta 77, 123–141 (1990)CrossRef
65.
Sparta, M., Jensen, V.R., Borve, K.J.: Structure and stability of substitutional metallofullerenes of the first-row transition metals. Fuller. Nanotub. Carb. Nanostruct. 14(2–3), 269–278 (2006)CrossRef
66.
Hedberg, K., Hedberg, L., Bethunde, D.S., Brown, C.A., Dorn, H.C., Johnson, R.D., Devries, M.: Bond lengths in free molecules of buckminsterfullerene, \(C_{60}\), from gas-phase electron-diffraction. Science 254, 410–412 (1991)CrossRef
67.
Chatt, J., Duncanson, L.A.: Olefin co-ordination compounds 3. Infrared spectra and structure-attempted preparation of acetylene complexes. J. Chem. Soc. 28, 2939–2947 (1953)CrossRef
68.
Dewar, M.J.S.: A review of the \(\pi \)-complex theory. Bull. Soc. Chim. Fr. 18, C71–79 (1951)
69.
Lin, S.S., Strauss, B., Kant, A.: Dissociation energy of \({\text{ Pd}}_2\). J. Chem. Phys. 51, 2282–2283 (1969)CrossRef
Metadata
Title
Exohedral Metallofullerenes
Author
Oleksandr Loboda
Copyright Year
2013
Publisher
Springer Berlin Heidelberg
Book
Quantum-chemical studies on Porphyrins, Fullerenes and Carbon Nanostructures

Print ISBN: 978-3-642-31844-3

Electronic ISBN: 978-3-642-31845-0

Copyright Year: 2013

DOI
https://doi.org/10.1007/978-3-642-31845-0_2

Premium Partners

    Image Credits