Experimental Study on Near-Limiting Burning Behavior of Thermoplastic Materials with Various Thicknesses Under Candle-Like Burning Configuration

We studied the near-limiting behavior of various thicknesses of thermoplastic materials under a candle-like burning configuration; followed by an ISO 4589-2 protocol. The motivation for this work is to understand the sensitivity of the sample thickness on the limiting oxygen concentration in the range from 0.5 mm to 10 mm. In the first place, the effect of heating time on successive ignition was discussed. Through a simple analysis, it was suggested that a 30 s heating time, regulated in ISO 4589-2, might be insufficient to achieve a successful ignition when the specimen becomes thicker. Second, the effect of the thickness of the test specimen (PMMA, ABS) on the limiting oxygen concentration was examined. Flames formed over thicker PMMA (>4.0 mm thickness in this study) at near-limiting condition displayed a flickering motion, which then suddenly extinguished when the critical condition was achieved due to temporal acceleration of the surrounding flow. While the flame behavior with a thinner sample (<4.0 mm thickness in this study) at the limiting condition was found to be stationary, a gentle extinction was experienced as approached to the limit. This fact suggests that the key to leading extinction is different between thicker and thinner sample. Third, the temperature distribution over the 4.0 mm PMMA at the near-limiting condition was measured and a strategy to model/predict the limiting behavior is then proposed.