Top

Published in:

06-01-2021 | Energy materials

Fabrication of direct Z-scheme black phosphorus nanosheets/Ag₂CO₃ heterojunction photocatalyst with enhanced stability and visible light photocatalytic activity

Authors: Pengfei Wang, Haoxu Zhao, Shutao Li, Ruisen Jing, Yao Liu, Ning Jiang, Fenggang Bian, Yunyan Liu, Huiqiang Liu, Qian Zhang

Published in: Journal of Materials Science | Issue 13/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

In this paper, PDDA-functionalized black phosphorus nanosheets (BP) was used to construct BP/Ag₂CO₃ heterojunction photocatalyst by a simple co-precipitation process. The morphology, photoelectrochemical, and photocatalytic performance of BP/Ag₂CO₃ heterojunction photocatalyst were systematically characterized and analyzed. BP was proved to enhance the transport efficiency and restrain the recombination efficiency of the carriers in the BP/Ag₂CO₃ heterojunction. At the same time, BP greatly suppressed the Ag₂CO₃ photo-corrosion and improved the stability for methyl orange (MO) degradation. After four cycles, compared with the 19.2% degradation rate of MO in pure Ag₂CO₃, the photocatalytic activity remained as high as 87.1% in 15-BP/Ag₂CO₃ heterojunction. The Mott–Schottky and active species capture experiments enabled us to obtain the BP/Ag₂CO₃ heterojunction band gap configuration, and propose the reaction mechanism of the direct Z-scheme. The in-situ X-ray photoelectron spectroscopy (XPS) analysis and work function calculation verified the charge transfer in BP/Ag₂CO₃ direct Z-scheme heterojunction. This Z-scheme mechanism interpreted the enhanced photocatalytic stability of BP/Ag₂CO₃ for inhibiting the Ag⁺ photoreduction in the conduction band of Ag₂CO₃, and meanwhile elucidated the extremely improved photocatalytic activity by restraining the recombination of electron-hole pairs. This work is expected to be useful in providing a facile route for designing novel heterojunction photocatalytic material and carrying out high-efficiency wastewater treatment.

previous article Mn2+-doped Cs2NaInCl6 double perovskites and their photoluminescence properties

next article Enhanced photoelectrochemical water oxidation of WO3/R-CoO and WO3/B-CoO photoanodes with a type II heterojunction

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Chen C, Ma W, Zhao J (2010) Semiconductor-mediated photodegradation of pollutants under visible-light irradiation. Chem Soc Rev 39:4206–4219CrossRef

Cui W, An W, Liu L, Hu J, Liang Y (2014) Novel Cu₂O quantum dots coupled flower-like BiOBr for enhanced photocatalytic degradation of organic contaminant. J Hazard Mater 280:417–427CrossRef

Liang Q, Liu X, Zeng G, Liu Z, Tang L, Shao B, Zeng Z, Zhang W, Liu Y, Cheng M, Tang W, Gong S (2019) Surfactant-assisted synthesis of photocatalysts: Mechanism, synthesis, recent advances and environmental application. Chem Eng J 372:429–451CrossRef

Wu T, Liu X, Liu Y, Cheng M, Liu Z, Zeng G, Shao B, Liang Q, Zhang W, He Q, Zhang W (2020) Application of QD-MOF composites for photocatalysis: energy production and environmental remediation. Coordin Chem Rev 403:213097CrossRef

Yang Y, Guo Y, Liu F, Yuan X, Guo Y, Zhang S, Guo W, Huo M (2013) Preparation and enhanced visible-light photocatalytic activity of silver deposited graphitic carbon nitride plasmonic photocatalyst. Appl Cata B-Environ 142–143:828–837CrossRef

Liu Z, Jiang Y, Liu X, Zeng G, Shao B, Liu Y, Liu Y, Zhang W, Zhang W, Yan M, He X (2019) Silver chromate modified sulfur doped graphitic carbon nitride microrod composites with enhanced visible-light photoactivity towards organic pollutants degradation. Compos Part B-Eng 173:106918CrossRef

Xiao S, Cheng M, Zhong H, Liu Z, Liu Y, Yang X, Liang Q (2020) Iron-mediated activation of persulfate and peroxymonosulfate in both homogeneous and heterogeneous ways: a review. Chem Eng J 384:123265CrossRef

Dong P, Yang B, Liu C, Xu F, Xi X, Hou G, Shao R (2017) Highly enhanced photocatalytic activity of WO₃ thin films loaded with Pt–Ag bimetallic alloy nanoparticles. RSC Adv 7:947–956CrossRef

Gao M, You L, Guo L, Li T (2019) Fabrication of a novel polyhedron-like WO₃/Ag₂CO₃ p-n junction photocatalyst with highly enhanced photocatalytic activity. J Photoch Photobio A 374:206–217CrossRef

10.

Ren X, Qi X, Shen Y, Xiao S, Xu G, Zhang Z, Huang Z, Zhong J (2016) 2D co-catalytic MoS2nanosheets embedded with 1D TiO₂ nanoparticles for enhancing photocatalytic activity. J Phys D App Phy 49:315304CrossRef

11.

Cui C, Wang Y, Liang D, Cui W, Hu H, Lu B, Xu S, Li X, Wang C, Yang Y (2014) Photo-assisted synthesis of Ag₃PO₄/reduced graphene oxide/Ag heterostructure photocatalyst with enhanced photocatalytic activity and stability under visible light. Appl Cata B-Environ 158–159:150–160CrossRef

12.

Cheng H, Kamegawa T, Mori K, Yamashita H (2014) Surfactant-free nonaqueous synthesis of plasmonic molybdenum oxide nanosheets with enhanced catalytic activity for hydrogen generation from ammonia borane under visible light. Angew Chem Int Ed 53:2910–2914CrossRef

13.

Zhang P, Wu P, Bao S, Wang Z, Tian B, Zhang J (2016) Synthesis of sandwich-structured AgBr@Ag@TiO₂ composite photocatalyst and study of its photocatalytic performance for the oxidation of benzyl alcohols to benzaldehydes. Chem Eng J 306:1151–1161CrossRef

14.

Liu Y, Kong J, Yuan J, Zhao W, Zhu X, Sun C, Xie J (2018) Enhanced photocatalytic activity over flower-like sphere Ag/Ag₂CO₃/BiVO₄ plasmonic heterojunction photocatalyst for tetracycline degradation. Chem Eng J 331:242–254CrossRef

15.

Voiry D, Yang J, Chhowalla M (2016) Recent strategies for improving the catalytic activity of 2D TMD nanosheets toward the hydrogen evolution reaction. Adv Mater 28:6197–6206CrossRef

16.

Low J, Jiang C, Cheng B, Wageh S, Al-Ghamdi AA, Yu J (2017) A Review of direct Z-scheme photocatalysts. Small Methods 1:1700080CrossRef

17.

Shao B, Liu Z, Zeng G, Wang H, Liang Q, He Q, Cheng M, Zhou C, Jiang L, Song B (2020) Two-dimensional transition metal carbide and nitride (MXene) derived quantum dots (QDs): synthesis, properties, applications and prospects. J Mater Chem A 8:7508–7535CrossRef

18.

Pan Y, Liu X, Zhang W, Liu Z, Zeng G, Shao B, Liang Q, He Q, Yuan X, Huang D, Chen M (2020) Advances in photocatalysis based on fullerene C₆₀ and its derivatives: properties, mechanism, synthesis, and applications. Appl Cata B-Environ 265:118579CrossRef

19.

Qiu P, Xu C, Zhou N, Chen H, Jiang F (2018) Metal-free black phosphorus nanosheets-decorated graphitic carbon nitride nanosheets with C P bonds for excellent photocatalytic nitrogen fixation. Appl Cata B-Environ 221:27–35CrossRef

20.

Lei W, Mi Y, Feng R, Liu P, Hu S, Yu J, Liu X, Rodriguez JA, J.o. Wang, L. Zheng, K. Tang, S. Zhu, G. Liu, M. Liu, (2018) Hybrid 0D–2D black phosphorus quantum dots–graphitic carbon nitride nanosheets for efficient hydrogen evolution. Nano Energy 50:552–561CrossRef

21.

Ren X, Zhou J, Qi X, Liu Y, Huang Z, Li Z, Ge Y, Dhanabalan SC, Ponraj JS, Wang S, Zhong J, Zhang H (2017) Few-layer black phosphorus nanosheets as electrocatalysts for highly efficient oxygen evolution reaction. Adv Energy Mater 7:1700396CrossRef

22.

Boppella R, Yang W, Tan J, Kwon HC, Park J, Moon J (2019) Black phosphorus supported Ni₂P co-catalyst on graphitic carbon nitride enabling simultaneous boosting charge separation and surface reaction. Appl Cata B-Environ 242:422–430CrossRef

23.

Zhu X, Zhang T, Jiang D, Duan H, Sun Z, Zhang M, Jin H, Guan R, Liu Y, Chen M, Ji H, Du P, Yan W, Wei S, Lu Y, Yang S (2018) Stabilizing black phosphorus nanosheets via edge-selective bonding of sacrificial C₆₀ molecules. Nat Commun 9:4177CrossRef

24.

Han X, Han J, Liu C, Sun J (2018) Promise and challenge of phosphorus in science, technology, and application. Adv Funct Mater 28:1803471CrossRef

25.

Gui R, Jin H, Wang Z, Li J (2018) 19 Black phosphorus quantum dots: synthesis, properties, functionalized modification and applications. Chem Soc Rev 47:6795–6823CrossRef

26.

Lu SB, Miao LL, Guo ZN, Qi X, Zhao CJ, Zhang H, Wen SC, Tang DY, Fan DY (2015) Broadband nonlinear optical response in multi-layer black phosphorus: an emerging infrared and mid-infrared optical material. Opt Express 23:11183–11194CrossRef

27.

Zhu M, Osakada Y, Kim S, Fujitsuka M, Majima T (2017) Black phosphorus: a promising two dimensional visible and near-infrared-activated photocatalyst for hydrogen evolution. Appl Cata B-Environ 217:285–292CrossRef

28.

Zhu M, Zhai C, Fujitsuka M, Majima T (2018) Noble metal-free near-infrared-driven photocatalyst for hydrogen production based on 2D hybrid of black Phosphorus/WS₂. Appl Cata B-Environ 221:645–651CrossRef

29.

Zhou C, Shi R, Shang L, Wu L-Z, Tung C-H, Zhang T (2018) Template-free large-scale synthesis of g-C₃N₄ microtubes for enhanced visible light-driven photocatalytic H₂ production. Nano Res 11:3462–3468CrossRef

30.

Reddy DA, Kim EH, Gopannagari M, Kim Y, Kumar DP, Kim TK (2019) Few layered black phosphorus/MoS₂ nanohybrid: a promising co-catalyst for solar driven hydrogen evolution. Appl Cata B-Environ 241:491–498CrossRef

31.

Shao B, Wang J, Liu Z, Zeng G, Tang L, Liang Q, He Q, Wu T, Liu Y, Yuan X (2020) Ti₃C₂T_x MXene decorated black phosphorus nanosheets with improved visible-light photocatalytic activity: experimental and theoretical studies. J Mater Chem A 8:5171–5185CrossRef

32.

Ran J, Zhu B, Qiao SZ (2017) Phosphorene co-catalyst advancing highly efficient visible-light photocatalytic hydrogen production. Angew Chem Int Ed 56:10373–10377CrossRef

33.

Wang L, Hu Y, Qi F, Ding L, Wang J, Zhang X, Liu Q, Liu L, Sun H, Qu P (2020) Anchoring black phosphorus nanoparticles onto ZnS porous nanosheets: efficient photocatalyst design and charge carrier dynamics . ACS Appl Mater Inter 12:8157–8167CrossRef

34.

Li S, Wang P, Wang R, Liu Y, Jing R, Li Z, Meng Z, Liu Y, Zhang Q (2019) One-step co-precipitation method to construct black phosphorus nanosheets/ZnO nanohybrid for enhanced visible light photocatalytic activity. Appl Surf Sci 497:143628CrossRef

35.

Feng Q, Liu H, Zhu M, Shang J, Liu D, Cui X, Shen D, Kou L, Mao D, Zheng J, Li C, Zhang J, Xu H, Zhao J (2018) Electrostatic functionalization and passivation of water-exfoliated few-layer black phosphorus by poly dimethyldiallyl ammonium chloride and its ultrafast laser application. ACS Appl Mater Inter 10:9679–9687CrossRef

36.

Zhang Z, Wang W, Gao E, Sun S, Zhang L (2012) Photocatalysis coupled with thermal effect induced by SPR on Ag-loaded Bi₂WO₆ with enhanced photocatalytic activity. J Phy Chem C 116:25898–25903CrossRef

37.

Misra M, Kapur P, Singla ML (2014) Surface plasmon quenched of near band edge emission and enhanced visible photocatalytic activity of Au@ZnO core-shell nanostructure. Appl Cata B-Environ 150–151:605–611CrossRef

38.

Linic S, Christopher P, Ingram DB (2011) Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy. Nat Mater 10:911–921CrossRef

39.

Fei J, Li J (2015) Controlled preparation of porous TiO₂-Ag nanostructures through supramolecular assembly for plasmon-enhanced photocatalysis. Adv Mater 27:314–319CrossRef

40.

Dai G, Yu J, Liu G (2012) A new approach for photocorrosion inhibition of Ag₂CO₃ photocatalyst with highly visible-light-responsive reactivity. J Phy Chem C 116:15519–15524CrossRef

41.

Wen XJ, Niu CG, Guo H, Zhang L, Liang C, Zeng GM (2018) Photocatalytic degradation of levofloxacin by ternary Ag₂CO₃/CeO₂/AgBr photocatalyst under visible-light irradiation: Degradation pathways, mineralization ability, and an accelerated interfacial charge transfer process study. J Catal 358:211–223CrossRef

42.

Tian N, Huang H, He Y, Guo Y, Zhang Y (2015) Organic–inorganic hybrid photocatalyst g-C₃N₄/Ag₂CO₃ with highly efficient visible-light-active photocatalytic activity. Coll Surf A 467:188–194CrossRef

43.

Li J, Guan R, Zhang J, Zhao Z, Zhai H, Sun D, Qi Y (2019) Preparation and Photocatalytic Performance of Dumbbell Ag₂CO₃–ZnO Heterojunctions. ACS Omega 5:570–577CrossRef

44.

Yu C, Li G, Kumar S, Yang K, Jin R (2014) Phase transformation synthesis of novel Ag₂O/Ag₂CO₃ heterostructures with high visible light efficiency in photocatalytic degradation of pollutants. Adv Mater 26:892–898CrossRef

45.

Song S, Meng A, Jiang S, Cheng B, Jiang C (2017) Construction of Z-scheme Ag₂CO₃/N-doped graphene photocatalysts with enhanced visible-light photocatalytic activity by tuning the nitrogen species. Appl Surf Sci 396:1368–1374CrossRef

46.

Fu S, Yuan W, Yan Y, Liu H, Shi X, Zhao F, Zhou J (2019) Highly efficient visible-light photoactivity of Z-scheme MoS₂/Ag₂CO₃ photocatalysts for organic pollutants degradation and bacterial inactivation. J Environ Manage 252:109654CrossRef

47.

Yan J, Wu H, Chen H, Zhang Y, Zhang F, Liu SF (2008) Fabrication of TiO₂/C₃N₄ heterostructure for enhanced photocatalytic Z-scheme overall water splitting. Appl Cata B-Environ 191:130–137CrossRef

48.

Liang Q, Liu X, Wang J, Liu Y, Liu Z, Tang L, Shao B, Zhang W, Gong S, Cheng M, He Q, Feng C (2021) In-situ self-assembly construction of hollow tubular g-C₃N₄ isotype heterojunction for enhanced visible-light photocatalysis: Experiments and theories. J Hazard Mater 401:123335CrossRef

49.

Nilges T, Kersting M, Pfeifer T (2008) A fast low-pressure transport route to large black phosphorus single crystals. J Solid State Chem 181:707–1711CrossRef

50.

Zhao M, Niu X, Guan L, Qian H, Wang W, Sha J, Wang Y (2016) Understanding the growth of black phosphorus crystals. CrystEngComm 18:7737–7744CrossRef

51.

Chen L, Zhou G, Liu Z, Ma X, Chen J, Zhang Z, Ma X, Li F, Cheng HM, Ren W (2016) Scalable clean exfoliation of high-quality few-layer black phosphorus for a flexible lithium ion battery. Adv Mater 28:510–517CrossRef

52.

Zhuge Z, Tang YH, Tao JW, Zhao Y (2019) Unctionalized black phosphorus nanocomposite for biosensing. ChemElectroChem 6:1129–1133CrossRef

53.

Zhu Q, Wang WS, Lin L, Gao GQ, Guo HL, Du H, Xu AW (2013) Facile synthesis of the novel Ag₃VO₄/AgBr/Ag plasmonic photocatalyst with enhanced photocatalytic activity and stability . T J Phy Chem C 117:5894–5900CrossRef

54.

Guo Y, Li J, Gao Z, Zhu X, Liu Y, Wei Z, Zhao W, Sun C (2016) A simple and effective method for fabricating novel p–n heterojunction photocatalyst g-C₃N₄/Bi4Ti₃O₁₂ and its photocatalytic performances. Appl Cata B-Environ 192:57–71CrossRef

55.

Kruk M, Jaroniec M (2001) Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chem Mater 13:3169–3183CrossRef

56.

Yu C, Wei L, Zhou W, Chen J, Fan Q, Liu H (2014) Enhancement of the visible light activity and stability of Ag2CO3 by formation of AgI/Ag₂CO₃ heterojunction. Appl Surf Sci 319:312–318CrossRef

57.

Xu C, Liu Y, Huang B, Li H, Qin X, Zhang X, Dai Y (2011) Preparation, characterization, and photocatalytic properties of silver carbonate. Appl Surf Sci 257:8732–8736CrossRef

58.

Li Z, Meng X, Zhang Z (2018) Few-layer MoS₂ nanosheets-deposited on Bi₂MoO₆ microspheres: a Z-scheme visible-light photocatalyst with enhanced activity. Catal Today 315:67–78CrossRef

59.

Wen XJ, Niu CG, Zhang L, Liang C, Zeng GM (2017) An in depth mechanism insight of the degradation of multiple refractory pollutants via a novel SrTiO₃/BiOI heterojunction photocatalysts. J Catal 356:283–299CrossRef

60.

Nayak S, Parida KM (2018) Dynamics of charge-transfer behavior in a plasmon-induced quasi-Type-II p-n/n-n dual heterojunction in Ag@Ag₃PO₄/g-C₃N₄/NiFe LDH nanocomposites for photocatalytic Cr(VI) reduction and phenol oxidation. ACS Omega 3:7324–7343CrossRef

61.

Cao Y, Fang Y, Lei X, Tan B, Hu X, Liu B, Chen Q (2020) Fabrication of novel CuFe₂O₄/MXene hierarchical heterostructures for enhanced photocatalytic degradation of sulfonamides under visible light. J Hazard Mater 387:122021CrossRef

62.

Akir S, Barras A, Coffinier Y, Bououdina M, Boukherroub R, Omrani AD (2016) Eco-friendly synthesis of ZnO nanoparticles with different morphologies and their visible light photocatalytic performance for the degradation of Rhodamine B. Ceram Inte 42:10259–10265CrossRef

63.

Song S, Cheng B, Wu N, Meng A, Cao S, Yu J (2016) Structure effect of graphene on the photocatalytic performance of plasmonic Ag/Ag₂CO₃-rGO for photocatalytic elimination of pollutants. Appl Cata B-Environ 181:71–78CrossRef

64.

Dong C, Wu KL, Wei XW, Li XZ, Liu L, Ding TH, Wang J, Ye Y (2014) Synthesis of graphene oxide–Ag₂CO₃ composites with improved photoactivity and anti-photocorrosion. CrystEngComm 16:730–736CrossRef

65.

Xu X, Meng L, Dai Y, Zhang M, Sun C, Yang S, He H, Wang S, Li H (2020) Bi spheres SPR-coupled Cu₂O/Bi₂MoO₆ with hollow spheres forming Z-scheme Cu₂O/Bi/Bi₂MoO₆ heterostructure for simultaneous photocatalytic decontamination of sulfadiazine and Ni(II). J Hazard Mater 381:120953CrossRef

66.

Wen XJ, Zhang C, Niu CG, Zhang L, Huang DW, Wang XY, Zhang XG, Zeng GM (2016) Facile synthesis of a visible light α-Fe₂O₃/BiOBr composite with high photocatalytic performance. RSC Advances 6:4035–4042CrossRef

67.

Ye L, Liu J, Gong C, Tian L, Peng T, Zan L (2012) Two different roles of metallic Ag on Ag/AgX/BiOX (X = Cl, Br) visible light photocatalysts: surface plasmon resonance and Z-scheme bridge. ACS Catal 2:1677–1683CrossRef

68.

An W, Sun K, Hu J, Cui W, Liu L (2020) The Z-scheme Ag₂CO₃@g-C₃N₄ core-shell structure for increased photoinduced charge separation and stable photocatalytic degradation. Appl Surf Sci 504:144345CrossRef

69.

Wu C (2014) 60 Synthesis of Ag₂CO₃/ZnO nanocomposite with visible light-driven photocatalytic activity. Mater Lett 136:262–264CrossRef

70.

Tonda S, Jo W-K (2018) Plasmonic Ag nanoparticles decorated NiAl-layered double hydroxide/graphitic carbon nitride nanocomposites for efficient visible-light-driven photocatalytic removal of aqueous organic pollutants. Catal Today 315:213–222CrossRef

71.

Qu J, Wang X, Zhang Y, Yuan G (2018) Multifunctional Ag nanoparticles in heterostructured Ag₂MoO₄/Ag/AgBr cubes with boosted photocatalytic performances. Sol Energy 170:124–131CrossRef

72.

Meng A, Zhu B, Zhong B, Zhang L, Cheng B (2017) Direct Z-scheme TiO₂/CdS hierarchical photocatalyst for enhanced photocatalytic H₂-production activity. Appl Surf Sci 422:518–527CrossRef

73.

Wang S, Zhu B, Liu M, Zhang L, Yu J, Zhou M (2019) Direct Z-scheme ZnO/CdS hierarchical photocatalyst for enhanced photocatalytic H₂-production activity. Appl Cata B-Environ 243:19–26CrossRef

Title: Fabrication of direct Z-scheme black phosphorus nanosheets/Ag2CO3 heterojunction photocatalyst with enhanced stability and visible light photocatalytic activity
Authors: Pengfei Wang
Haoxu Zhao
Shutao Li
Ruisen Jing
Yao Liu
Ning Jiang
Fenggang Bian
Yunyan Liu
Huiqiang Liu
Qian Zhang
Publication date: 06-01-2021
Publisher: Springer US
Published in: Journal of Materials Science / Issue 13/2021
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-05752-7

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 13/2021

Interfacial phenomena between molten iron and molten slag–Effect of nitrogen on the Marangoni convection

Porous spinel-type (Al0.2CoCrFeMnNi)0.58O4-δ high-entropy oxide as a novel high-performance anode material for lithium-ion batteries

Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation

Fabrication of reduced graphene oxide/manganese oxide ink for 3D-printing technology on the application of high-performance supercapacitors

In situ observation of the impact of hydrogen bubbles in Al–Cu melt on directional dendritic solidification

Novel nanoscale Yb-MOF used as highly efficient electrode for simultaneous detection of heavy metal ions

Premium Partners