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Journal of Coatings Technology and Research

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11-11-2020

Fabrication of graphene-coated poly(glycidyl methacrylate) microspheres by electrostatic interaction and their application in epoxy anticorrosion coatings

Authors: Meng Li, Yiyi Li, Jiatian Zhang, Dandan Zhang, Jie Li, Kaibin He, Yiting Xu, Birong Zeng, Lizong Dai

Published in: Journal of Coatings Technology and Research | Issue 2/2021

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Abstract

The uneven dispersion of graphene in the resin matrix hinders its application in anticorrosion coatings. This study reports a new method where graphene oxide (GO) is coated on the surface of the poly(glycidyl methacrylate) (PGMA) microspheres to promote the dispersion of GO in epoxy resin (EP) to improve the anticorrosion performance of EP. GO-coated PGMA microspheres (PGMA@GO) were successfully fabricated by electrostatic interaction, which was confirmed by Fourier transform infrared spectroscopy, X-ray diffraction, Raman spectroscopy, transmission electron microscopy, and zeta potential analysis. The scanning electron microscopy results showed that the PGMA microspheres were uniformly coated with GO, when the weight ratio of PGMA@GO was 1:2 (PGMA: GO). Electrochemical impedance spectroscopy and salt immersion experiments were performed to evaluate the corrosion resistance of the EP composite coatings. Comparing with pure EP and GO/EP coatings, the mechanical properties and anticorrosion properties of coatings were improved after adding PGMA@GO. When the addition amount of PGMA@GO (of 50 g EP) was 1.0 wt% and about 0.67 wt% GO was only needed, the PGMA@GO/EP composite coating possessed a high impedance of 5.68 × 10⁸ Ω cm² and a low breakpoint frequency of 0.39 Hz for 21-day immersion in 3.5 wt% NaCl solution. The anticorrosion mechanism of PGMA@GO/EP composite coating was also discussed.

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Boukhvalov, DW, Katsnelson, MI, Lichtenstein, AI, “Hydrogen on Graphene: Electronic Structure, Total Energy, Structural Distortions and Magnetism from First-Principles Calculations.” Phys. Rev. B, 77 (3) 035427 (2008)

DeAndres, PL, Ramirez, R, Verges, JA, “Strong Covalent Bonding Between Two Graphene Layers.” Phys. Rev. B, 77 (4) 045403 (2008)

Reddy, CD, Rajendran, S, Liew, KM, “Equilibrium Configuration and Continuum Elastic Properties of Finite Sized Graphene.” Nanotechnology, 17 (3) 864–870 (2006)

Nemes-Incze, P, Osvath, Z, Kamaras, K, Biro, LP, “Anomalies in Thickness Measurements of Graphene and Few Layer Graphite Crystals by Tapping Mode Atomic Force Microscopy.” Carbon, 46 (11) 1435–1442 (2008)

Li, YY, Xu, YT, Wang, SC, Wang, HC, Li, M, Dai, LZ, “Preparation of Graphene/Polyaniline Nanocomposite by In Situ Intercalation Polymerization and Their Application in Anti-corrosion Coatings.” High Perform. Polym., 31 (9–10) 1226–1237 (2019)

Chen, D, Feng, HB, Li, JH, “Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications.” Chem. Rev., 112 (11) 6027–6053 (2012)

Atif, R, Inam, F, “Modeling and Simulation of Graphene Based Polymer Nanocomposites: Advances in the Last Decade.” Graphene, 5 96–142 (2016)

Nikpour, B, Ramezanzadeh, B, Bahlakeh, G, Mahdavian, M, “Synthesis of Graphene Oxide Nanosheets Functionalized by Green Corrosion Inhibitive Compounds to Fabricate a Protective System.” Corros. Sci., 127 240–259 (2017)

Kasaeian, M, Ghasemi, E, Ramezanzadeh, B, Mahdavian, M, Bahlakeh, G, “Construction of a Highly Effective Self-repair Corrosion-Resistant Epoxy Composite Through Impregnation of 1H-Benzimidazole Corrosion Inhibitor Modified Graphene Oxide Nanosheets (GO-BIM).” Corros. Sci., 145 119–134 (2018)

10.

Krishnamoorthy, K, Jeyasubramanian, K, Premanathan, M, Subbiah, G, Shin, HS, Kim, SJ, “Graphene Oxide Nanopaint.” Carbon, 72 328–337 (2014)

11.

Yu, YH, Lin, YY, Lin, CH, Chan, CC, Huang, YC, “High-Performance Polystyrene/Graphene-Based Nanocomposites with Excellent Anti-corrosion Properties.” Polym. Chem., 5 (2) 535–550 (2014)

12.

Ramezanzadeh, B, Niroumandrad, S, Ahmadi, A, Mahdavian, M, Moghadam, MHM, “Enhancement of Barrier and Corrosion Protection Performance of an Epoxy Coating Through Wet Transfer of Amino Functionalized Graphene Oxide.” Corros. Sci., 103 283–304 (2016)

13.

Yu, ZX, Di, HH, Ma, Y, et al., “Fabrication of Graphene Oxide-Alumina Hybrids to Reinforce the Anti-corrosion Performance of Composite Epoxy Coatings.” Appl. Surf. Sci., 351 986–996 (2015)

14.

Muzammil Ezzah, M, Khan, A, Stuparu, MC, “Post-polymerization Modification Reactions of Poly(glycidyl methacrylate)s.” RSC Adv., 7 (88) 55874–55884 (2017)

15.

Li, QL, Gu, WX, Gao, H, Yang, YW, “Self-assembly and Applications of Poly(glycidyl methacrylate)s and Their Derivatives.” Chem. Commun., 50 (87) 13201–13215 (2014)

16.

Sun, XT, Yang, LR, Xing, HF, et al., “High Capacity Adsorption of Cr(VI) from Aqueous Solution Using Polyethylenimine-Functionalized Poly(glycidyl methacrylate) Microspheres.” Colloid Surf. A, 457 160–168 (2014)

17.

Zhang, HW, Zhao, R, Chen, ZY, Shangguan, DH, Liu, GQ, “QCM-FIA with PGMA Coating for Dynamic Interaction Study of Heparin and Antithrombin III.” Biosens. Bioelectron., 21 (1) 121–127 (2005)

18.

Koysuren, O, Karaman, M, Ozyurt, D, “Effect of Noncovalent Chemical Modification on the Electrical Conductivity and Tensile Properties of Poly(methyl methacrylate)/Carbon Nanotube Composites.” J. Appl. Polym. Sci., 127 (6) 4557–4563 (2013)

19.

Canamero, PF, de la Fuente, JL, Madruga, EL, Fernandez-Garcia, M, “Atom Transfer Radical Polymerization of Glycidyl Methacrylate: A Functional Monomer.” Macromol. Chem. Phys., 205 (16) 2221–2228 (2004)

20.

Mrlik, M, Ilcikova, M, Plachy, T, Moucka, R, Pavlinek, V, Mosnacek, J, “Tunable Electrorheological Performance of Silicone Oil Suspensions Based on Controllably Reduced Graphene Oxide by Surface Initiated Atom Transfer Radical Polymerization of Poly(glycidyl methacrylate).” J. Ind. Eng. Chem., 57 104–112 (2018)

21.

Chuo, T-W, Yeh, J-M, Liu, Y-L, “A Reactive Blend of Electroactive Polymers Exhibiting Synergistic Effects on Self-healing and Anticorrosion Properties.” RSC Adv., 6 (60) 55593–55598 (2016)

22.

EI-Sawy, SM, Abu-Ayana, YM, Abdel-Mohdy, FA, “Preparation of Some Nitrogen Containing Polymers/Copolymers for Corrosion Protection.” J. Appl. Sci. Res., 4 (5) 534–544 (2008)

23.

Zhang, WC, Sun, Y, Zhang, L, “In Situ Synthesis of Monodisperse Silver Nanoparticles on Sulfhydryl-Functionalized Poly(glycidyl methacrylate) Microspheres for Catalytic Reduction of 4-Nitrophenol.” Ind. Eng. Chem. Res., 54 (25) 6480–6488 (2015)

24.

Chen, GF, Lu, JR, Lam, C, Yu, Y, “A Novel Green Synthesis Approach for Polymer Nanocomposites Decorated with Silver Nanoparticles and Their Antibacterial Activity.” Analyst, 139 (22) 5793–5799 (2014)

25.

Jin, HJ, Choi, HJ, Yoon, SH, Myung, SJ, Shim, SE, “Carbon Nanotube-Adsorbed Polystyrene and Poly(methyl methacrylate) Microspheres.” Chem. Mater., 17 (16) 4034–4037 (2005)

26.

Cho, MS, Cho, YH, Choi, HJ, Jhon, MS, “Synthesis and Electrorheological Characteristics of Polyaniline-Coated Poly(methyl methacrylate) Microsphere: Size Effect.” Langmuir, 19 (14) 5875–5881 (2003)

27.

Krizova, J, Spanova, A, Rittich, B, Horak, D, “Magnetic Hydrophilic Methacrylate-Based Polymer Microspheres for Genomic DNA Isolation.” J. Chromatogr. A, 1064 (2) 247–253 (2005)

28.

Yu, Y, Wu, X-L, Li, Y, et al., “Preparation of Mixed-Mode Chromatography Supports Based on Gigaporous Polymer Microspheres.” Chin. J. Anal. Chem., 44 (12) 1874–1879 (2016)

29.

Oh, H, Kim, Y, Kim, J, “Co-curable Poly(glycidyl methacrylate)-Grafted Graphene/Epoxy Composite for Thermal Conductivity Enhancement.” Polymer, 183 121834 (2019)

30.

Kakaei, K, Hasanpour, K, “Synthesis of Graphene Oxide Nanosheets by Electrochemical Exfoliation of Graphite in Cetyltrimethylammonium Bromide and Its Application for Oxygen Reduction.” J. Mater. Chem. A., 2 (37) 15428–15436 (2014)

31.

Meng, W, Gall, E, Ke, FY, et al., “Structure and Interaction of Graphene Oxide-Cetyltrimethylammonium Bromide Complexation.” J. Phys. Chem. C, 119 (36) 21135–21140 (2015)

32.

Oh, J, Lee, JH, Koo, JC, et al., “Graphene Oxide Porous Paper from Amine-Functionalized Poly(glycidyl methacrylate)/Graphene Oxide Core-Shell Microspheres.” J. Mater. Chem., 20 (41) 9200–9204 (2010)

33.

Oh, JS, Luong, ND, Hwang, TS, Hong, JP, Lee, YK, Nam, JD, “In Situ Fabrication of Platinum/Graphene Composite Shell on Polymer Microspheres Through Reactive Self-assembly and In Situ Reduction.” J. Mater. Sci., 48 (3) 1127–1133 (2013)

34.

Fang, R, Ge, XP, Du, M, et al., “Preparation of Silver/Graphene/Polymer Hybrid Microspheres and the Study of Photocatalytic Degradation.” Colloid Polym. Sci., 292 (4) 985–990 (2014)

35.

Sari, MG, Ramezanzadeh, B, “Epoxy Composite Coating Corrosion Protection Properties Reinforcement Through the Addition of Hydroxyl-Terminated Hyperbranched Polyamide Non-covalently Assembled Graphene Oxide Platforms.” Constr. Build. Mater., 234 117421 (2020)

36.

Long, GC, Tang, CY, Wong, KW, et al., “Resolving the Dilemma of Gaining Conductivity but Losing Environmental Friendliness in Producing Polystyrene/Graphene Composites via Optimizing the Matrix-Filler Structure.” Green Chem., 15 (3) 821–828 (2013)

37.

Akbarzadeh, S, Ramezanzadeh, M, Ramezanzadeh, B, Bahlakeh, G, “A Green Assisted Route for the Fabrication of a High-Efficiency Self-healing Anti-corrosion Coating Through Graphene Oxide Nanoplatform Reduction by Tamarindus indiaca Extract.” J. Hazard. Mater., 390 122147 (2020)

38.

Liu, Y, Zhang, YH, Duan, LL, et al., “Polystyrene/Graphene Oxide Nanocomposites Synthesized via Pickering Polymerization.” Prog. Org. Coat., 99 23–31 (2016)

39.

Zhang, WL, Liu, YD, Choi, HJ, “Graphene Oxide Coated Core-Shell Structured Polystyrene Microspheres and Their Electrorheological Characteristics Under Applied Electric Field.” J. Mater. Chem., 21 (19) 6916–6921 (2011)

40.

Xu, J, Wang, L, Zhu, YF, “Decontamination of Bisphenol A from Aqueous Solution by Graphene Adsorption.” Langmuir, 28 (22) 8418–8425 (2012)

41.

Zhao, JP, Ren, WC, Cheng, HM, “Graphene Sponge for Efficient and Repeatable Adsorption and Desorption of Water Contaminations.” J. Mater. Chem., 22 (38) 20197–20202 (2012)

42.

Konkena, B, Vasudevan, S, “Understanding Aqueous Dispersibility of Graphene Oxide and Reduced Graphene Oxide Through pKa Measurements.” J. Phys. Chem. Lett., 3 (7) 867–872 (2012)

43.

Li, D, Muller, MB, Gilje, S, Kaner, RB, Wallace, GG, “Processable Aqueous Dispersions of Graphene Nanosheets.” Nat. Nanotechnol., 3 (2) 101–105 (2008)

44.

Chen, C, Qiu, SH, Cui, MJ, et al., “Achieving High Performance Corrosion and Wear Resistant Epoxy Coatings via Incorporation of Noncovalent Functionalized Graphene.” Carbon, 114 356–366 (2017)

45.

Chen, Y, Wang, XH, Li, J, Lu, JL, Wang, FS, “Long-Term Anticorrosion Behaviour of Polyaniline on Mild Steel.” Corros. Sci., 49 (7) 3052–3063 (2007)

46.

Qiu, SH, Liu, G, Li, W, Zhao, HC, Wang, LP, “Noncovalent Exfoliation of Graphene and Its Multifunctional Composite Coating with Enhanced Anticorrosion and Tribological Performance.” J. Alloy. Compd., 747 60–70 (2018)

47.

Sakhri, A, Perrin, FX, Aragon, E, Lamouric, S, Benaboura, A, “Chlorinated Rubber Paints for Corrosion Prevention of Mild Steel: A Comparison Between Zinc Phosphate and Polyaniline Pigments.” Corros. Sci., 52 (3) 901–909 (2010)

48.

Ramezanzadeh, B, Ghasemi, E, Mahdavian, M, Changizi, E, Moghadam, MHM, “Covalently-Grafted Graphene Oxide Nanosheets to Improve Barrier and Corrosion Protection Properties of Polyurethane Coatings.” Carbon, 93 555–573 (2015)

49.

Liu, S, Gu, L, Zhao, HC, Chen, JM, Yu, HB, “Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings.” J. Mater. Sci. Technol., 32 (5) 425–431 (2016)

50.

Parhizkar, N, Shahrabi, T, Ramezanzadeh, B, “A New Approach for Enhancement of the Corrosion Protection Properties and Interfacial Adhesion Bonds Between the Epoxy Coating and Steel Substrate Through Surface Treatment by Covalently Modified Amino Functionalized Graphene Oxide Film.” Corros. Sci., 123 55–75 (2017)

51.

Zheng, HP, Shao, YW, Wang, YQ, Meng, GZ, Liu, B, “Reinforcing the Corrosion Protection Property of Epoxy Coating by Using Graphene Oxide–Poly(urea–formaldehyde) Composites.” Corros. Sci., 123 267–277 (2017)

52.

Liu, X, Xiong, J, Lv, Y, Zuo, Y, “Study on Corrosion Electrochemical Behavior of Several Different Coating Systems by EIS.” Prog. Org. Coat., 64 (4) 497–503 (2009)

53.

Ramezanzadeh, B, Bahlakeh, G, Ramezanzadeh, M, “Polyaniline-Cerium Oxide (PAni-CeO₂) Coated Graphene Oxide for Enhancement of Epoxy Coating Corrosion Protection Performance on Mild Steel.” Corros. Sci., 137 111–126 (2018)

Title: Fabrication of graphene-coated poly(glycidyl methacrylate) microspheres by electrostatic interaction and their application in epoxy anticorrosion coatings
Authors: Meng Li
Yiyi Li
Jiatian Zhang
Dandan Zhang
Jie Li
Kaibin He
Yiting Xu
Birong Zeng
Lizong Dai
Publication date: 11-11-2020
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 2/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-020-00409-1

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