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01-06-2021 | Original Research

Fabrication of novel valorized ecofriendly olive seed residue/anthracite/chitosan composite for removal of Cr (VI): kinetics, isotherms and thermodynamics modeling

Authors: M. R. El-Aassar, F. M. Mohamed, Ibrahim Hotan Alsohaimi, R. E. Khalifa

Published in: Cellulose | Issue 11/2021

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Abstract

The present work verified the adsorption of hexavalent chromium (Cr (VI)) from synthetic aqueous solution using synthesized highly efficient low-cost adsorbent prepared from H₂O₂-modified olive seed residue solid waste/Anthracite/Chitosan (MOSR/An/CS) composite. Characteristics of the fabricated MOSR/An/CS composite were estimated by XRD, SEM, TGA, DSC, FT-IR, SBET and zeta potential tools. The entire chromium uptake study was conducted via batch adsorption mode under various operating conditions. Kinetics data were analyzed using five kinetic models, while empirical equilibrium data was fitted using three isotherms. The results clarified that Langmuir best described the adsorption of Cr (VI) ions with maximum monolayer coverage of 137.7 mg/g. Pseudo-first-order mode nicely fitted the kinetics adsorption. Further, Elovich, intraparticle diffusion, and Boyd models validate that more than one mechanism contributed to the adsorption of Cr (VI). The positive ΔH (110.11 kJ/mol), suggesting that the method of adsorption is endothermic and favorable at low temperatures, also indicated the chemisorption of Cr(VI). The positive value of ΔG varying from (14.53 to 8.1115 kJ/mol) at the temperature range measured confirms the possibility of the process as a non-spontaneous adsorption reaction. The Ea value was found to be 110.11 kJ mol⁻¹ which mean that the adsorption of Cr(VI) onto MOSR/An/CS composite is chemisorption. The developed MOSR/An/Cs composite exhibited decent reusability after five sequential adsorption cycles and showed higher adsorption affinity towards Cr (VI) ions. MOSR/An/CS composite could also be effectively used as an effective eco-friendly and recyclable sorbent for the elimination of Cr (VI) from wastewater.

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Abo-El-Enein SA, Eissa MA, Diafullah AA, Rizk MA, Mohamed FM (2011) Utilization of a low cost agro-residue for production of coagulant aids and their applications. J Hazard Mater 172:574–657CrossRef

AlawadyAlshahraniAouakaAlandis ARAATANM (2020) Polysulfone membranes with CNTs/Chitosan biopolymer nanocomposite as selective layer for remarkable heavy metal ions rejection capacity. Chem Eng J 388:124267CrossRef

Ali A, Saeed K, Maboob F (2016) Removal of chromium(VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent. Alex Eng J 55:2933–2942CrossRef

Amar MB, Walha K, Salvadó V (2020) Evaluation of olive stones for Cd(II), Cu(II), Pb(II) and Cr(VI) biosorption from aqueous solution: equilibrium and kinetics. Int J Environ Res. https://doi.org/10.1007/s41742-020-00246-5CrossRef

APHA (2005) Standard methods for examination of water and wastewater, 21st edn. American public health association, Washington

Bandara PC, Peña-Bahamonde J, Rodrigues DF (2020) Redox mechanisms of conversion of Cr(VI) to Cr(III) by graphene oxide polymer composite. Sci Reports. https://doi.org/10.1038/s41598-020-65534-8CrossRef

Bhatnagar A, Sillanpää M (2017) Removal of natural organic matter (NOM) and its constituents from water by adsorption–a review. Chemosphere 166:497–510PubMedCrossRef

Bhatnagar A, Kaczala F, Hogl W, Marques M, Christakis AP, Vagelis GP, Sillanpää M (2014) Valorization of solid waste products from olive oil industry as potential adsorbents for water pollution control—a review. Environ Sci Pollut Res 21:268–298CrossRef

Bhattacharya AK, NaiyaT K, Mandal SN, Das SK (2008) Adsorption, kinetics and equilibrium studies on removal of Cr(VI) from aqueous solutions using different low-cost adsorbents. Chem Eng J 137:529–541

Bhattacharya A, Gupta A, Kaur A, Malik D (2019) Alleviation of hexavalent chromium by using microorganisms: insight into the strategies and complications. Water Sci Technol 79(3):411–424PubMedCrossRef

Biglari H, Saeidi M, Alipour V, Rahdar S, Sohrabi Y, Khaksefidi R, Narooie MR, Zarei A, Ahamadabadi M (2016) Review on hydrochemical and health effects of it in Sistan and Baluchistan groundwaters Iran. Int J Pharm Technol 8(3):17900–17920

Bishnoi NR, Bajaj M, Sharma N, Gupta A (2004) Adsorption of Cr(VI) on activated rice husk carbon and activated alumina. Biores Technol 91:305–307CrossRef

Boral P, Varma AK, Maity S (2015) X-ray diffraction studies of some structurally modified Indian coals and their correlation with petrographic parameters. CurrSci 108(3):384–394

Chen X, Lee DW (2019) A Spectroscopic Study of Solid-Phase ChFerrariitosan/Cyclodextrin-Based Electrospin. Fibers. https://doi.org/10.3390/fib7050048CrossRef

Devi BM, Sathyamoorthy SL, Umamaheshwari D, Vijayalakshmi K, Thandapani Gomathi T, Sudha PN (2014) Synthesis and characterization of chitosan/sodium alginate/carboxymethyl cellulose beads. Pharm Lett 6(6):389–395

Eckmann A, Felten A, Mishchenko A, Britnell L, Krupke R, Novoselov KS, Casiragh C (2012) Probing the effects in graphene by Raman spectroscopy. Nano Lett 12(8):3925–3930PubMedCrossRef

Eivazzadeh-Keihana R, Radinekiyana F, Asgharnasla S, Malekia A, HosseinBahreinizad H (2020) Natural and eco-friendly magneticnanobio-composite based on activated chitosan for heavy metals adsorption and the in-vitrohyperthermia of cancer therapy. J Mater Res Technol 9(6):12244–12259CrossRef

El-Aassar MR, Mohamed FM (2021) Characterization valorized anthracite and its application in manganese (VII) adsorption from aqueous solution; batch and column studies. Microporous Mesoporous Mater. https://doi.org/10.1016/j.micromeso.2020.110641CrossRef

El-Aassar MR, Hashem FSA, Elzain A, Mohamed FM (2021) Reduction of non-point source pollution by poly (styrene-co-acrylonitrile) composites nanofibers inoculated with sorbent materials. Int J Environ Sci Technol. https://doi.org/10.1007/s13762-020-03051-xCrossRef

Elzain AA, El-Aassar MR, Masoud MS, Mohamed MF (2018) Synthesis, optimization, and characterization of poly (Styrene-co-Acrylonitrile) copolymer prepared via precipitation polymerization. Adv Polymer Technol 37(6):2021–2029CrossRef

Esposito A, Pagnanelli F, Lodi A, Solisio C, Vegliò F (2001) Biosorption of heavy metals by Sphaeronatans: an equilibrium study at different pH and biomass concentrations. Hydrometa 60(2):129–141CrossRef

European Commission (2017) Agriculture and rural development. Available online: http://ec.europa.eu/agriculture/olive-oil_en

Foroutana R, Peighambardousta SG, Mohammadi R, Omidvar M, Sorial GA, Ramavandi B (2020) Influence of chitosan and magnetic iron nanoparticles on chromium adsorption behavior of natural clay: adaptive neuro-fuzzy inference modeling. Int J Biol Macromol 151:355–365CrossRef

Goel PK (2006) Water pollution: causes, effects and control, new age international, New Delhi

Goharshadi EK, Moghaddam MB (2015a) Adsorption of hexavalent chromium ions from aqueous solution by grapheme nanosheets: kinetic and thermodynamic studies. Int Environ Sci Technol 12:2153–2160CrossRef

Goharshadi EK, Moghaddam MB (2015b) Adsorption of hexavalent chromium ions from aqueous solution by grapheme nanosheets: kinetic and thermodynamic studies. Int Environ Sci Technol 12:2153–2160CrossRef

Guizani C, Haddad K, Jeguirim M, Colin B, Limousy L (2016) Combustion characteristics and kinetics of torrefied olive pomace. Energy 107:453–463CrossRef

Guthrie GD, Dish DL, Reynolds RC (1995) Modeling the X-ray diffraction pattern of opal-CT. Am Mineral 80:869–872CrossRef

Habiba U, Siddique TA, Joo TC, Salleh A, Ang BC, Afifi AM (2016) Synthesis of Chitosan/Polyvinyl alcohol/ZeoliteComposite for Removal of Methyl orange, Congo red and Chromium (VI) by Flocculation/Adsorption. Carbohyd Polym 157:1568–1576CrossRef

Hahid M, Shamshad S, Rafiq M, Khalid S, Bibi I, Niazi KN, Dumat C, Rashid MI (2017) Chromium speciation, bioavailability, uptake, toxicity and detoxification in soil-plant system: a review. Chemosphere 178:513–533CrossRef

Hernandez-Ortiz M, Hernandez-Padron G, Bernal R, Cruz-Vazquez C, Castano VM (2015) Nanocrystalline mimetic opals: synthesis and comparative characterization vs natural stones. M Int J Bas Appl Sci 4(2):238–243

Inai S, Harao A, Nishikawa H (2007) Correlation between the luminescence properties and the surface structures of submicron silica particles. J Non-Cryst Solids 353:510–513. https://doi.org/10.1016/j.jnoncrysol.2006.10.051CrossRef

Itodo AU, Abdulrahman FW, Hassan LG, Maigandi SA, Itodo HU (2010) Intraparticle diffusion and intraparticulate diffusivities of herbicide on drived activated carbon. Research 2:74–86

Jamshidifard S, Koushkbaghi S, Hosseini S, Rezaei S, Karamipour A, Irani M (2019) Incorporation of UiO- 66-NH₂ MOF into the PAN/chitosan nanofibers for adsorption and membrane filtration of Pb (II), Cd (II) and Cr(VI) ions from aqueous solutions. J Hazard Mater 368:10–20PubMedCrossRef

Jeguirim M, Elmay Y, Limousy L, Lajili M, Said R (2014) Devolatilization behaviour and pyrolysis kinetics of potential Tunisian biomass fuels. Environ Prog Sustain Energy 33:1452–1458

Kaklidis N, Kyriakou V, Garagounis I, Arenillas A, Meńendez JA, Marnellos GE, Konsolakis M (2014) Effect of carbon type on the performance of a direct or hybrid carbon solid oxide fuel cell. RSC Adv 4:18792CrossRef

Karamipour A, Khadiv-Parsi P, Zahedi P, Moosavian SMA (2019) Using Fe₃O₄-coated nanofibers based on cellulose acetate/ chitosan for adsorption of Cr(VI), Ni(II) and phenol from aqueous solutions. Int J Biol Macromol. https://doi.org/10.1016/j.ijbiomac.2019.11.058CrossRefPubMed

Khalifa RE, Omer AM, Tamer TM, Mohyeldin MS (2019a) Removal of methylene blue dye from synthetic aqueous solutions using novel phosphonated cellulose acetate membranes: adsorption kinetic, equilibrium, and thermodynamic studies". Desal Water Treatment 144:272–285CrossRef

Khalifa RE, Omer AM, Tamer TM, Ali AA, Ammar YA (2019b) Efficient ecofriendly crude oil adsorptive chitosan derivatives: kinetics, equilibrium and thermodynamic studies". Desalin Water Treatment. https://doi.org/10.5004/dwt.2019.24166CrossRef

Koushkbaghi S, Zakialamdari A, Pishnamazi M, Ramandi HF, Aliabadi M, Irani M (2018) Aminated-Fe₃O₄ nanoparticles filled chitosan/PVA/PES dual layers nanofibrous membrane for the removal of Cr(VI) and Pb (II) ions from aqueous solutions in adsorption and membrane processes. Chem Eng J 337:169–182CrossRef

Koushkbaghi S, Zakialamdari A, Pishnamazi M, Ramandi HF, Aliabadi M, Irani M (2018) Aminated-Fe3O4 nanoparticles filled chitosan/PVA/PES dual layers nanofibrous membrane for the removal of Cr (VI) and Pb (II) ions from aqueous solutions in adsorption and membrane processes. Chem Eng J 337:169–182CrossRef

Lawrie G, Keen I, Drew B, Chandler-Temple A, Rintoul L, Fredericks P, Grøndahl L (2007) Interactions between Alginate and Chitosan Biopolymers Characterized Using FTIR and XPS. Biomacromol 8(8):2533–2541. https://doi.org/10.1021/bm070014yCrossRef

Manoj B, Mohan AN, Ramya AV, Manoj B (2016) Probing the nature of defects of graphene like nano-carbon from amorphous materials by Raman spectroscopy. Asian J Chem 28(7):1501–1504CrossRef

Maponya TC, Ramohlola KE, Kera NH, Modibane KD, Maity A, Katata-Seru LM, Hato MJ (2020) Influence of magnetic nanoparticles on modified polypyrrole/m-phenylediamine for adsorption of Cr (VI) from aqueous solution. Polymers 12(3):679PubMedCentralCrossRef

Marchessault RH, Ravenelle F, Zhu XX (2006) Polysaccharides for drug delivery and pharmaceutical applications. American Chemical SocietyCrossRef

Mei J, Zhang H, Mo S, Zhang Y, Li Z, Ou H (2020) Prominent adsorption of Cr (VI) with graphene oxide aerogel twined with creeper-like polymer based on chitosan oligosaccharide. Carb Polym 247:116733CrossRef

Mohamed FM, Alfalous KA (2020) The effectiveness of activated silica derived from rice husk in coagulation process compared with inorganic coagulants for wastewater treatment. Egyp J Aquat Res 46(2):131–136CrossRef

Mohamed FM, Li Z, Zayed MA (2020) Carbon nanotube impregnated anthracite (An/CNT) as a superior sorbent for azo dye removal. RSC Adv 2020(10):25586. https://doi.org/10.1039/d0ra03869eCrossRef

Mondal NK, Chakraborty S (2020) Adsorption of Cr (VI) from aqueous solution on graphene oxide (GO) prepared from graphite: equilibrium, kinetic and thermodynamic studies. Appl Water Sci 10(2):1–10CrossRef

Narandalai B, Wang GS, Balathanigaimanic MS, Hee M (2016) Highly porous activated carbons prepared from carbon richMongolian anthracite by direct NaOH activation. Appl Surf Sci 379:331–337CrossRef

Nelson LGD, Souza TF, Salles HM, Brandão HGM, Edwardsc LFC, de Oliveira, (2015) Synthesis, Vibrational Spectroscopic and Thermal Properties of Oxocarbon Cross-Linked Chitosan. J Braz Chem Soc 26:1247–1256. https://doi.org/10.5935/01035053.20150090CrossRef

Nokano Y, Tanaka M, Nakamura Y, Konno M (2000) Removal and recovery system of hexavalent chromium from wastewater by tannin gel particles, J. Chem. Eng. Japan 33:747–752

Omer AM, Elgarhy GS, El-Subruiti GM, Khalifa RE, Eltaweil AS (2020) Fabrication of novel iminodiacetic acid-functionalized carboxymethyl cellulose microbeads for efficient removal of cationic crystal violet dye from aqueous solutions. Int J Biol Macromol 148:1072–1083PubMedCrossRef

Osman Z, Arof AF (2003) FTIR studies of chitosan acetate based polymer electrolytes. Electrochim Acta 48:993–999. https://doi.org/10.1016/S0013-4686(02)00812-5CrossRef

Paluszkiewicz C, Stodolak E, Hasik M, Blazewicz M (2011) FT-IR study of montmorillonite–chitosan nanocomposite materials. SpectrochimicaActa Part A. 79:784–788CrossRef

Periyasamy S, Gopalakannan V, Viswanathan N (2017) Fabrication of magnetic particles imprinted cellulose based biocomposites for chromium (VI) removal. Carbohydrate Polym 174:352–359CrossRef

Preethi J, Karthikeyan P, Vigneshwaran S, Meenakshi S (2021) Facile synthesis of Zr4þ incorporated chitosan/gelatin composite for the sequestration of Chromium(VI) and fluoride from water. Chemosphere 262:128317PubMedCrossRef

Ramya K, John J, Manoj B (2013) Raman spectroscopy: investigation of camphor soot: spectral analysis and structural information. Int J Electrochem Sci 8:9421–9428

Rastmanesh F, Safaie S, Zarasvandi AR, Edraki M (2018) Heavy metal enrichment and ecological risk assessment of surface sediments in Khorramabad River West Iran. Environ Monitor Assess 190(5):1–9CrossRef

Sadezky A, Muckenhuber H, Grothe H (2005) Raman micro spectroscopy of soot and related carbonaceous materials: spectral analysis and structural information. Carbon 43:1731–1742CrossRef

Saravanane R, Sundararajan T, Sivamurthyreddy S (2002) Efficiency of chemically modified low cost adsorbents for the removal of heavy metals from wastewater. a comparative study. Indian J Environ Health 44:78–81PubMed

Toprak A (2020) The effect of pore and surface characteristics of activated carbon produced by coal through N2 and H2O vapor/H3PO4 activation on a single step for CH4 adsorption in the low pressure. Energy Sources Part A Recovery Utilization Environ Effects 42(16):1950–1962CrossRef

Vakiliab MT, Dengb S, Cagnettab G, Wang W, Menga P, Liub D, Yub G (2019) Regeneration of chitosan-based adsorbents used in heavy metal adsorption: A review. Sep Purif Technol 224(1):373–387CrossRef

Vilarigues M, Da Silva RC (2009) The effect of Mn, Fe and Cu ions on potash-glass corrosión. J Non-Cryst Solids 355:1630–1637. https://doi.org/10.1016/j.jnoncrysol.2009.05.051CrossRef

Vo AT, Nguyen VP, Ouakouak A, Nieva A (2019) Efficient removal of Cr(VI) from water by biochar and activated carbon prepared through hydrothermal carbonization and pyrolysis: adsorption-coupled reduction mechanism. Water 11:1164CrossRef

Wu J, Zheng H, Zhang F, Zenga RJ, Xing B (2019) Iron-carbon composite from carbonization of iron-cross linked sodium alginate for Cr(VI) removal. Chem Eng J 362:21–29CrossRef

Yang XK, Omer AM, Khalifa RE, Zhaohong H, Chao L (2019) Fabrication of Tetraethylenepentamine functionalized alginate beads for adsorptive removal of Cr(VI) from aqueous solutions. Int J Biol Macromol 125:1221–1231CrossRef

Yuan Q, Shah J, Hein S, Misra RDK (2010) Controlled and extended drug release behavior of chitosan-based nanoparticle carrier. Acta Biomater 6:1140–1148PubMedCrossRef

Zhang W, Jiang S, Hardacre C, Peter Goodrich P, Wang K, Shao H, Wu Z (2015) A combined raman spectroscopic and thermogravimetric analysis study on oxidation of coal with different ranks. J Anal Methods Chem. https://doi.org/10.1155/2015/306874CrossRefPubMedPubMedCentral

Zhao YT, Liu L, Cui TT, Jin C, Tong GX, Qian Y, Wu WH (2017) Enhanced photocatalytic properties of ZnO/reduced graphene oxide sheets (rGO) composites with controllable morphology and composition Appl. Surf Sci 412:58–68CrossRef

Zhao G, Huang X, Tang Z, Huang Q, Niu F, Wang X (2018) Polymer-based nanocomposites for heavy metal ions removal from aqueous solution: a review. Polym Chem 9(26):3562–3582CrossRef

Zhu HY, Jianga R, Xiao L, Li W (2010) Novel magnetically separable γ-Fe₂O₃/crosslinked chitosan adsorbent: preparation, characterization, and adsorption application for removal of hazardous azo dye. J Hazard Mater 179:251–257. https://doi.org/10.1016/j.jhazmat.2010.02.087CrossRefPubMed

Title: Fabrication of novel valorized ecofriendly olive seed residue/anthracite/chitosan composite for removal of Cr (VI): kinetics, isotherms and thermodynamics modeling
Authors: M. R. El-Aassar
F. M. Mohamed
Ibrahim Hotan Alsohaimi
R. E. Khalifa
Publication date: 01-06-2021
Publisher: Springer Netherlands
Published in: Cellulose / Issue 11/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03963-y

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