Skip to main content
Top
Published in: Journal of Materials Science: Materials in Electronics 23/2017

24-08-2017

Facile preparation of novel Cu–Zn–S film by spray pyrolysis

Authors: Xiaojun Xu, Qinmiao Chen, Hongcun Yuan, Ni Yi, Jin Chen, Xifang Zhu, Yoshinori Yamaguchi, Xiaoming Dou

Published in: Journal of Materials Science: Materials in Electronics | Issue 23/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this work, novel Cu–Zn–S (CZS) thin film for solar cell was successfully synthesized using a facile preparation method of spray pyrolysis. Copper (II) chloride dihydrate, zinc(II) acetate dihydrate and thiourea were used as reagents. The effect of varying the substrate temperature for the spray in terms of structural, optical, compositional, morphological and photovoltaic properties of the fabricated CZS film was investigated via X-ray diffraction, ultraviolet-visible-infrared spectroscopy, energy dispersive X-ray spectroscopy, scanning electron microscopy and J–V tester, respectively. As observed from the results, our novel CZS thin films have good crystallinity phase with bandgap of 2.21 eV and a conversion efficiency of 0.84% under optimal condition.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Q.M. Chen, S.Y. Cheng, S.L. Zhuang, X.M. Dou, Cu2ZnSnS4 solar cell prepared entirely by non-vacuum processes. Thin Solid Films 520, 6256–6261 (2012)CrossRef Q.M. Chen, S.Y. Cheng, S.L. Zhuang, X.M. Dou, Cu2ZnSnS4 solar cell prepared entirely by non-vacuum processes. Thin Solid Films 520, 6256–6261 (2012)CrossRef
2.
go back to reference X.L. Liu, Y. Feng, H.T. Cui, F.Y. Liu, X.J. Hao, G. Conibeer, D.B. Mitzi, M. Green, The current status and future prospects of kesterite solar cells: a brief review. Prog. Photovolt. 24, 879–898 (2016)CrossRef X.L. Liu, Y. Feng, H.T. Cui, F.Y. Liu, X.J. Hao, G. Conibeer, D.B. Mitzi, M. Green, The current status and future prospects of kesterite solar cells: a brief review. Prog. Photovolt. 24, 879–898 (2016)CrossRef
3.
go back to reference M.A. Green, K. Emery, Y. Hishikawa, W. Warta, E.D. Dunlop, D.H. Levi, A.W.Y. Ho-Baillie, Solar cell efficiency tables (version 49). Prog. Photovolt. 25, 3–13 (2017)CrossRef M.A. Green, K. Emery, Y. Hishikawa, W. Warta, E.D. Dunlop, D.H. Levi, A.W.Y. Ho-Baillie, Solar cell efficiency tables (version 49). Prog. Photovolt. 25, 3–13 (2017)CrossRef
4.
go back to reference W. Wang, M.T. Winkler, O. Gunawan, T. Gokmen, T.K. Todorov, Y. Zhu, D.B. Mitzi, Device characteristics of CZTSSe thin-film solar cells with 12.6% efficiency. Adv. Energy Mater. 4, 5 (2014) W. Wang, M.T. Winkler, O. Gunawan, T. Gokmen, T.K. Todorov, Y. Zhu, D.B. Mitzi, Device characteristics of CZTSSe thin-film solar cells with 12.6% efficiency. Adv. Energy Mater. 4, 5 (2014)
5.
go back to reference M. Adelifard, H. Eshghi, M.M.B. Mohagheghi, An investigation on substrate temperature and copper to sulphur molar ratios on optical and electrical properties of nanostructural CuS thin films prepared by spray pyrolysis method. Appl. Surf. Sci. 258, 5733–5738 (2012)CrossRef M. Adelifard, H. Eshghi, M.M.B. Mohagheghi, An investigation on substrate temperature and copper to sulphur molar ratios on optical and electrical properties of nanostructural CuS thin films prepared by spray pyrolysis method. Appl. Surf. Sci. 258, 5733–5738 (2012)CrossRef
7.
go back to reference N. Aihara, H. Araki, A. Takeuchi, K. Jimbo, H. Katagiri, Fabrication of Cu2SnS3 thin films by sulfurization of evaporated Cu–Sn precursors for solar cells. Phys. Status Solidi C 10, 1086–1092 (2013) N. Aihara, H. Araki, A. Takeuchi, K. Jimbo, H. Katagiri, Fabrication of Cu2SnS3 thin films by sulfurization of evaporated Cu–Sn precursors for solar cells. Phys. Status Solidi C 10, 1086–1092 (2013)
8.
go back to reference J. Xu, X. Yang, T.-L. Wong, C.-S. Lee, Large-scale synthesis of Cu2SnS3 and Cu1.8S hierarchical microspheres as efficient counter electrode materials for quantum dot sensitized solar cells. Nanoscale 4, 6537–6542 (2012)CrossRef J. Xu, X. Yang, T.-L. Wong, C.-S. Lee, Large-scale synthesis of Cu2SnS3 and Cu1.8S hierarchical microspheres as efficient counter electrode materials for quantum dot sensitized solar cells. Nanoscale 4, 6537–6542 (2012)CrossRef
9.
go back to reference M.A. Yildirim, A. Ates, A. Astam, Annealing and light effect on structural, optical and electrical properties of CuS, CuZnS and ZnS thin films grown by the SILAR method. Phys. E 41, 1365–1372 (2009)CrossRef M.A. Yildirim, A. Ates, A. Astam, Annealing and light effect on structural, optical and electrical properties of CuS, CuZnS and ZnS thin films grown by the SILAR method. Phys. E 41, 1365–1372 (2009)CrossRef
10.
go back to reference W.Q. Peng, G.W. Cong, S.C. Qu, Z.G. Wang, Synthesis and photoluminescence of ZnS:Cu nanoparticles. Opt. Mater. 29, 313–317 (2006)CrossRef W.Q. Peng, G.W. Cong, S.C. Qu, Z.G. Wang, Synthesis and photoluminescence of ZnS:Cu nanoparticles. Opt. Mater. 29, 313–317 (2006)CrossRef
11.
go back to reference H. Jinman, Y. Yi, X. Shanhua, Y. Bai, L. Shiyong, S. Jiacong, Photoluminescence and electroluminescence of ZnS:Cu nanocrystals in polymeric networks. Appl. Phys. Lett. 70, 2335–2337 (1997)CrossRef H. Jinman, Y. Yi, X. Shanhua, Y. Bai, L. Shiyong, S. Jiacong, Photoluminescence and electroluminescence of ZnS:Cu nanocrystals in polymeric networks. Appl. Phys. Lett. 70, 2335–2337 (1997)CrossRef
12.
go back to reference C.C. Uhuegbu, E.B. Babatunde, C.O. Oluwafemi, The study of copper zinc sulphide (CuZnS2) thin films. Turk. J. Phys. 32, 39–47 (2008) C.C. Uhuegbu, E.B. Babatunde, C.O. Oluwafemi, The study of copper zinc sulphide (CuZnS2) thin films. Turk. J. Phys. 32, 39–47 (2008)
13.
go back to reference M.S. Sreejith, D.R. Deepu, C. SudhaKartha, K. Rajeevkumar, K.P. Vijayakumar, Improvement of sprayed CuZnS/In2S3 solar cell efficiency by making multiple band gap nature more prominent. J. Renew. Sustain. Energy 8, 023502 (2016)CrossRef M.S. Sreejith, D.R. Deepu, C. SudhaKartha, K. Rajeevkumar, K.P. Vijayakumar, Improvement of sprayed CuZnS/In2S3 solar cell efficiency by making multiple band gap nature more prominent. J. Renew. Sustain. Energy 8, 023502 (2016)CrossRef
14.
go back to reference M.S. Sreejith, D.R. Deepu, C.S. Kartha, K. Rajeevkumar, K.P. Vijayakumar, Tuning the properties of sprayed CuZnS films for fabrication of solar cell. Appl. Phys. Lett. 105, 202107 (2014)CrossRef M.S. Sreejith, D.R. Deepu, C.S. Kartha, K. Rajeevkumar, K.P. Vijayakumar, Tuning the properties of sprayed CuZnS films for fabrication of solar cell. Appl. Phys. Lett. 105, 202107 (2014)CrossRef
15.
go back to reference R. Salazar, S. Sanchez, A. Delamoreanu, C. Levy-Clement, V. Ivanova, ZnO nanowire arrays sensitized with different absorber materials for fabrication of nanostructured solar cells. ECS Trans. 41, 119–128 (2011)CrossRef R. Salazar, S. Sanchez, A. Delamoreanu, C. Levy-Clement, V. Ivanova, ZnO nanowire arrays sensitized with different absorber materials for fabrication of nanostructured solar cells. ECS Trans. 41, 119–128 (2011)CrossRef
16.
go back to reference N. Kitagawa, S. Ito, D.C. Nguyen, H. Nishino, Copper zinc sulfur compound solar cells fabricated by spray pyrolysis deposition for solar cells. Nat. Resour. 4, 142–145 (2013) N. Kitagawa, S. Ito, D.C. Nguyen, H. Nishino, Copper zinc sulfur compound solar cells fabricated by spray pyrolysis deposition for solar cells. Nat. Resour. 4, 142–145 (2013)
17.
go back to reference Z. Jia, Q. Chen, J. Chen, T. Wang, Z. Li, X. Dou, The photovoltaic properties of novel narrow band gap Cu 2 SnS 3 films prepared by a spray pyrolysis method. RSC Adv. 5, 28885–28891 (2015)CrossRef Z. Jia, Q. Chen, J. Chen, T. Wang, Z. Li, X. Dou, The photovoltaic properties of novel narrow band gap Cu 2 SnS 3 films prepared by a spray pyrolysis method. RSC Adv. 5, 28885–28891 (2015)CrossRef
18.
go back to reference C. Uhuegbu, E. Babatunde, Spectral analysis of copper zinc sulphide ternary thin film grown by solution growth technique. Am. J. Sci. Ind. Res. 1, 397–400 (2010) C. Uhuegbu, E. Babatunde, Spectral analysis of copper zinc sulphide ternary thin film grown by solution growth technique. Am. J. Sci. Ind. Res. 1, 397–400 (2010)
19.
go back to reference P.S. Patil, Versatility of chemical spray pyrolysis technique. Mater. Chem. Phys. 59, 185–198 (1999)CrossRef P.S. Patil, Versatility of chemical spray pyrolysis technique. Mater. Chem. Phys. 59, 185–198 (1999)CrossRef
20.
go back to reference Q.M. Chen, X.M. Dou, Z.Q. Li, S.Y. Cheng, S.L. Zhuang, Printed ethyl cellulose/CuInSe2 composite light absorber layer and its photovoltaic effect. J. Phys. D: Appl. Phys. 44, 455401 (2011)CrossRef Q.M. Chen, X.M. Dou, Z.Q. Li, S.Y. Cheng, S.L. Zhuang, Printed ethyl cellulose/CuInSe2 composite light absorber layer and its photovoltaic effect. J. Phys. D: Appl. Phys. 44, 455401 (2011)CrossRef
21.
go back to reference Q.M. Chen, X.M. Dou, Y. Ni, S.Y. Cheng, S.L. Zhuang, Study and enhance the photovoltaic properties of narrow-bandgap Cu2SnS3 solar cell by p-n junction interface modification. J. Colloid Interface Sci. 376, 327–330 (2012)CrossRef Q.M. Chen, X.M. Dou, Y. Ni, S.Y. Cheng, S.L. Zhuang, Study and enhance the photovoltaic properties of narrow-bandgap Cu2SnS3 solar cell by p-n junction interface modification. J. Colloid Interface Sci. 376, 327–330 (2012)CrossRef
Metadata
Title
Facile preparation of novel Cu–Zn–S film by spray pyrolysis
Authors
Xiaojun Xu
Qinmiao Chen
Hongcun Yuan
Ni Yi
Jin Chen
Xifang Zhu
Yoshinori Yamaguchi
Xiaoming Dou
Publication date
24-08-2017
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 23/2017
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-7752-2

Other articles of this Issue 23/2017

Journal of Materials Science: Materials in Electronics 23/2017 Go to the issue