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Polymer Bulletin

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01-01-2015 | Original Paper

Facile synthesis of new sodium alginate–anthracene based photosensitizers

Authors: Dharmesh R. Chejara, Stalin Kondaveeti, A. K. Siddhanta

Published in: Polymer Bulletin | Issue 1/2015

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Abstract

Facile syntheses of water-soluble sodium alginate (Na-Alg) derivatives employing anthracene moieties (Anth) have been carried out. Na-Alg amide (Alg-Anth amide), and Na-alg ester (Alg-Anth ester) derivatives were synthesized using 2-amino anthracene and 9-chloromethyl anthracene (9-CMA), respectively. These polymeric materials were characterized (FTIR, ¹³C NMR, GPC, UV–Vis and fluorescence spectroscopy). These derivatives were photoactive and demonstrated photosensitizing capabilities in presence of an acceptor pyrene. Alg-Anth ester was more efficient (63 %) as opposed to Alg-Anth amide (37 %) in transferring energy to the acceptor. Further hydrophilic–lipophilic balance (HLB) values (>10.0) of both the derivatives indicated their suitability as solubilizers. These water-soluble polysaccharide-based polymers may be of potential utility as photosensitizers for reactions of organic compounds in aqueous media as well as in sensory applications.

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Title: Facile synthesis of new sodium alginate–anthracene based photosensitizers
Authors: Dharmesh R. Chejara
Stalin Kondaveeti
A. K. Siddhanta
Publication date: 01-01-2015
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 1/2015
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-014-1257-4

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