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Published in: Journal of Nanoparticle Research 12/2016

01-12-2016 | Research Paper

Facile synthesis of uniform hierarchical composites CuO-CeO2 for enhanced dye removal

Authors: Pan Xu, Helin Niu, Jingshuai Chen, Jiming Song, Changjie Mao, Shengyi Zhang, Yuanhao Gao, Changle Chen

Published in: Journal of Nanoparticle Research | Issue 12/2016

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Abstract

The hierarchically shaped CuO-CeO2 composites were prepared through a facile solvothermal method without using any template. The as-prepared products were characterized by X-ray powder diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and N2 adsorption–desorption analysis. In the characterization, we found that CuO-CeO2 composites were showed uniform size and morphology which were consisted of the secondary nanoflakes interconnected with each other. Most interestingly, the composites showed efficient performance to remove methyl blue and Congo red dyes from water with maximum adsorption capacities of 2131.24 and 1072.09 mg g−1, respectively. In addition, because of their larger surface area and the unique hierarchical structures, the adsorption performance of the CuO-CeO2 composites is much better than the materials of CuO and CeO2.

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Appendix
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Literature
go back to reference Anandan C, Bera P (2013) XPS studies on the interaction of CeO2 with silicon in magnetron sputtered CeO2 thin films on Si and Si3N4 substrates. Appl Surf Sci 283:297–303CrossRef Anandan C, Bera P (2013) XPS studies on the interaction of CeO2 with silicon in magnetron sputtered CeO2 thin films on Si and Si3N4 substrates. Appl Surf Sci 283:297–303CrossRef
go back to reference Barbato PS, Colussi S, Benedetto AD, Landi G, Lisi L, Llorca J, Trovarelli A (2016) Origin of high activity and selectivity of CuO/CeO2 catalysts prepared by solution combustion synthesis in CO-PROX reaction. J Phys Chem C 120:13039–13048CrossRef Barbato PS, Colussi S, Benedetto AD, Landi G, Lisi L, Llorca J, Trovarelli A (2016) Origin of high activity and selectivity of CuO/CeO2 catalysts prepared by solution combustion synthesis in CO-PROX reaction. J Phys Chem C 120:13039–13048CrossRef
go back to reference Cámara AL, Chansai S, Hardacre C, Martínez-Arias A (2014) The water–gas shift reaction over CeO2/CuO: operando SSITKA–DRIFTS–mass spectrometry study of low temperature mechanism. Int J Hydrog Energy 39:4095–4101CrossRef Cámara AL, Chansai S, Hardacre C, Martínez-Arias A (2014) The water–gas shift reaction over CeO2/CuO: operando SSITKA–DRIFTS–mass spectrometry study of low temperature mechanism. Int J Hydrog Energy 39:4095–4101CrossRef
go back to reference Dong Y, Lin HM, Jin QM, Li L, Wang D, Zhou D, Qu FY (2013) Synthesis of mesoporous carbon fibers with a high adsorption capacity for bulky dye molecules. J Mater Chem A 1:7391–7398CrossRef Dong Y, Lin HM, Jin QM, Li L, Wang D, Zhou D, Qu FY (2013) Synthesis of mesoporous carbon fibers with a high adsorption capacity for bulky dye molecules. J Mater Chem A 1:7391–7398CrossRef
go back to reference Garg VK, Gupta R, Yadav AB, Kumar R (2003) Dye removal from aqueous solution by adsorption on treated sawdust. Bioresour Technol 89:121–124CrossRef Garg VK, Gupta R, Yadav AB, Kumar R (2003) Dye removal from aqueous solution by adsorption on treated sawdust. Bioresour Technol 89:121–124CrossRef
go back to reference Gu XR, Li H, Liu LC, Tang CJ, Gao F, Dong L (2014) Promotional effect of CO pretreatment on CuO/CeO2 catalyst for catalytic reduction of NO by CO. J Rare Earth 32:139–145CrossRef Gu XR, Li H, Liu LC, Tang CJ, Gao F, Dong L (2014) Promotional effect of CO pretreatment on CuO/CeO2 catalyst for catalytic reduction of NO by CO. J Rare Earth 32:139–145CrossRef
go back to reference Guo HX, Ke YC, Wang DF, Lin KL, Shen RX, Chen JH, Weng W (2013) Efficient adsorption and photocatalytic degradation of Congo red onto hydrothermally synthesized NiS nanoparticles. J Nanopart Res 15:1475CrossRef Guo HX, Ke YC, Wang DF, Lin KL, Shen RX, Chen JH, Weng W (2013) Efficient adsorption and photocatalytic degradation of Congo red onto hydrothermally synthesized NiS nanoparticles. J Nanopart Res 15:1475CrossRef
go back to reference Jin XY, Yua B, Chen ZL, Arocenad JM, Thringd RW (2014) Adsorption of Orange II dye in aqueous solution onto surfactant-coated zeolite: characterization, kinetic and thermodynamic studies. J Colloid Interface Sci 435:15–20CrossRef Jin XY, Yua B, Chen ZL, Arocenad JM, Thringd RW (2014) Adsorption of Orange II dye in aqueous solution onto surfactant-coated zeolite: characterization, kinetic and thermodynamic studies. J Colloid Interface Sci 435:15–20CrossRef
go back to reference Konsolakis M, Carabineiro SAC, Papista E, Marnellos GE, Tavares PB, Agostinho Moreira J, Romaguera-Barcelay Y, Figueiredo JL (2015) Effect of preparation method on the solid state properties and the deN2O performance of CuO-CeO2 oxides. Catal Sci Technol 5:3714–3728CrossRef Konsolakis M, Carabineiro SAC, Papista E, Marnellos GE, Tavares PB, Agostinho Moreira J, Romaguera-Barcelay Y, Figueiredo JL (2015) Effect of preparation method on the solid state properties and the deN2O performance of CuO-CeO2 oxides. Catal Sci Technol 5:3714–3728CrossRef
go back to reference Landi G, Barbato PS, Benedetto AD, Lisi L (2016) Optimization of the preparation method of CuO/CeO2 structured catalytic monolith for CO preferential oxidation in H2-rich streams. Appl Catal B 181:727–737CrossRef Landi G, Barbato PS, Benedetto AD, Lisi L (2016) Optimization of the preparation method of CuO/CeO2 structured catalytic monolith for CO preferential oxidation in H2-rich streams. Appl Catal B 181:727–737CrossRef
go back to reference Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295CrossRef Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295CrossRef
go back to reference Lin CC, Lin YS, Ho JM (2016) Adsorption of Reactive Red 2 from aqueous solutions using Fe3O4 nanoparticles prepared by co-precipitation in a rotating packed bed. J Alloys Compd 666:153–158CrossRef Lin CC, Lin YS, Ho JM (2016) Adsorption of Reactive Red 2 from aqueous solutions using Fe3O4 nanoparticles prepared by co-precipitation in a rotating packed bed. J Alloys Compd 666:153–158CrossRef
go back to reference Ma XD, Sun HW, Sun Q, Feng X, Guo HW, Fan B, Zhao S, He X, Lv L (2011) Catalytic oxidation of CO and o-DCB over CuO/CeO2 catalysts supported on hierarchically porous silica. Catal Commun 12:426–430CrossRef Ma XD, Sun HW, Sun Q, Feng X, Guo HW, Fan B, Zhao S, He X, Lv L (2011) Catalytic oxidation of CO and o-DCB over CuO/CeO2 catalysts supported on hierarchically porous silica. Catal Commun 12:426–430CrossRef
go back to reference Moscofian ASO, Pires CTGVMT, Vieira AP, Airoldi C (2013) Removal of reactive dyes using organofunctionalized mesoporous silicas. J Porous Mater 20:1179–1188CrossRef Moscofian ASO, Pires CTGVMT, Vieira AP, Airoldi C (2013) Removal of reactive dyes using organofunctionalized mesoporous silicas. J Porous Mater 20:1179–1188CrossRef
go back to reference Qin JW, Lu JF, Cao MH, Hu CW (2010) Synthesis of porous CuO-CeO2 nanospheres with an enhanced low-temperature CO oxidation activity. Nanoscale 2:2739–2743CrossRef Qin JW, Lu JF, Cao MH, Hu CW (2010) Synthesis of porous CuO-CeO2 nanospheres with an enhanced low-temperature CO oxidation activity. Nanoscale 2:2739–2743CrossRef
go back to reference Saepurahman, Singaravel GP, Hashaikeh R (2016) Fabrication of electrospun LTL zeolite fibers and their application for dye removal. J Mater Sci 51:1133–1141CrossRef Saepurahman, Singaravel GP, Hashaikeh R (2016) Fabrication of electrospun LTL zeolite fibers and their application for dye removal. J Mater Sci 51:1133–1141CrossRef
go back to reference Saravanan R, Joicy S, Gupta VK, Narayanan V, Stephen A (2013) Visible light induced degradation of methylene blue using CeO2/V2O5 and CeO2/CuO catalysts. Mater Sci Eng C 33:4725–4731CrossRef Saravanan R, Joicy S, Gupta VK, Narayanan V, Stephen A (2013) Visible light induced degradation of methylene blue using CeO2/V2O5 and CeO2/CuO catalysts. Mater Sci Eng C 33:4725–4731CrossRef
go back to reference Sarma GK, Sen Gupta S, Bhattacharyya KG (2016) Adsorption of Crystal violet on raw and acid-treated montmorillonite, K10, in aqueous suspension. J Environ Manag 171:1–10CrossRef Sarma GK, Sen Gupta S, Bhattacharyya KG (2016) Adsorption of Crystal violet on raw and acid-treated montmorillonite, K10, in aqueous suspension. J Environ Manag 171:1–10CrossRef
go back to reference Si Y, Ren T, Li Y, Ding B, Yu JY (2012) Fabrication of magnetic polybenzoxazine-based carbon nanofibers with Fe3O4 inclusions with a hierarchical porous structure for water treatment. Carbon 50:5176–5185CrossRef Si Y, Ren T, Li Y, Ding B, Yu JY (2012) Fabrication of magnetic polybenzoxazine-based carbon nanofibers with Fe3O4 inclusions with a hierarchical porous structure for water treatment. Carbon 50:5176–5185CrossRef
go back to reference Song XL, Yang P, Jia CC, Chen L, Postolek KM (2015) Self-assembled synthesis of urchin-like AlOOH microspheres with large surface area for removal of pollutants. RSC Advance 5:33155–33162CrossRef Song XL, Yang P, Jia CC, Chen L, Postolek KM (2015) Self-assembled synthesis of urchin-like AlOOH microspheres with large surface area for removal of pollutants. RSC Advance 5:33155–33162CrossRef
go back to reference Tan IAW, Ahmad AL, Hameed BH (2009) Adsorption isotherms, kinetics, thermodynamics and desorption studies of 2, 4, 6-trichlorophenol on oil palm empty fruit bunch-based activated carbon. J Hazard Mater 164:473–482CrossRef Tan IAW, Ahmad AL, Hameed BH (2009) Adsorption isotherms, kinetics, thermodynamics and desorption studies of 2, 4, 6-trichlorophenol on oil palm empty fruit bunch-based activated carbon. J Hazard Mater 164:473–482CrossRef
go back to reference Tang DD, Zhang GK (2016) Efficient removal of fluoride by hierarchical Ce–Fe bimetal oxides adsorbent: thermodynamics, kinetics and mechanism. Chem Eng J 283:721–729CrossRef Tang DD, Zhang GK (2016) Efficient removal of fluoride by hierarchical Ce–Fe bimetal oxides adsorbent: thermodynamics, kinetics and mechanism. Chem Eng J 283:721–729CrossRef
go back to reference Tang H, Huang H, Wang XS, Wu KQ, Tang GG, Li CS (2016) Hydrothermal synthesis of 3D hierarchical flower-like MoSe2 microspheres and their adsorption performances for methyl orange. Appl Surf Sci 379:296–303CrossRef Tang H, Huang H, Wang XS, Wu KQ, Tang GG, Li CS (2016) Hydrothermal synthesis of 3D hierarchical flower-like MoSe2 microspheres and their adsorption performances for methyl orange. Appl Surf Sci 379:296–303CrossRef
go back to reference Tian P, Han XY, Ning GL, Fang HX, Ye JW, Gong WT, Lin Y (2013) Synthesis of porous hierarchical MgO and its superb adsorption properties. ACS Appl Mater Interfaces 5:12411–12418CrossRef Tian P, Han XY, Ning GL, Fang HX, Ye JW, Gong WT, Lin Y (2013) Synthesis of porous hierarchical MgO and its superb adsorption properties. ACS Appl Mater Interfaces 5:12411–12418CrossRef
go back to reference Wang JQ, Zhou QS, Song DQ, Qi B, Zhang YJ, Shao YZ, Shao ZQ (2015a) Chitosan–silica composite aerogels: preparation, characterization and Congo red adsorption. J Sol-Gel Sci Technol 76:501–509CrossRef Wang JQ, Zhou QS, Song DQ, Qi B, Zhang YJ, Shao YZ, Shao ZQ (2015a) Chitosan–silica composite aerogels: preparation, characterization and Congo red adsorption. J Sol-Gel Sci Technol 76:501–509CrossRef
go back to reference Wang DB, Zhang MM, Yuan JZ, Lin YS, Song CX (2015b) Facile route to Ni-doped α-FeOOH and α-Fe2O3 nanostructures and their properties. Mater Lett 157:147–150CrossRef Wang DB, Zhang MM, Yuan JZ, Lin YS, Song CX (2015b) Facile route to Ni-doped α-FeOOH and α-Fe2O3 nanostructures and their properties. Mater Lett 157:147–150CrossRef
go back to reference Wei W, Gao P, Xie JM, Zong SK, Cui HL, Yue XJ (2013) Uniform Cu2Cl(OH)3 hierarchical microspheres: a novel adsorbent for methylene blue adsorptive removal from aqueous solution. J Solid State Chem 204:305–313CrossRef Wei W, Gao P, Xie JM, Zong SK, Cui HL, Yue XJ (2013) Uniform Cu2Cl(OH)3 hierarchical microspheres: a novel adsorbent for methylene blue adsorptive removal from aqueous solution. J Solid State Chem 204:305–313CrossRef
go back to reference Wu Y, Li ZM, Chen J, Yu CG, Huang X, Zhao CZ, Duan LF, Yang Y, Lü W (2015) Graphene nanosheets decorated with tunable magnetic nanoparticles and their efficiency of wastewater treatment. Mater Res Bull 68:234–239CrossRef Wu Y, Li ZM, Chen J, Yu CG, Huang X, Zhao CZ, Duan LF, Yang Y, Lü W (2015) Graphene nanosheets decorated with tunable magnetic nanoparticles and their efficiency of wastewater treatment. Mater Res Bull 68:234–239CrossRef
go back to reference Wu JS, Wang JS, Du YC, Li HY, Jia XJ (2016) Adsorption mechanism and kinetics of azo dye chemicals on oxide nanotubes: a case study using porous CeO2 nanotubes. J Nanopart Res 18:191CrossRef Wu JS, Wang JS, Du YC, Li HY, Jia XJ (2016) Adsorption mechanism and kinetics of azo dye chemicals on oxide nanotubes: a case study using porous CeO2 nanotubes. J Nanopart Res 18:191CrossRef
go back to reference Zeng SH, Liu KW, Zhang L, Qin B, Chen TJ, Yin YL, Su HQ (2014) Deactivation analyses of CeO2/CuO catalysts in the preferential oxidation of carbon monoxide. J Power Sources 261:46–54CrossRef Zeng SH, Liu KW, Zhang L, Qin B, Chen TJ, Yin YL, Su HQ (2014) Deactivation analyses of CeO2/CuO catalysts in the preferential oxidation of carbon monoxide. J Power Sources 261:46–54CrossRef
go back to reference Zou HB, Chen SZ, Liu ZL, Lin WM (2011) Selective CO oxidation over CuO-CeO2 catalysts doped with transition metal oxides. Powder Technol 207:1–3CrossRef Zou HB, Chen SZ, Liu ZL, Lin WM (2011) Selective CO oxidation over CuO-CeO2 catalysts doped with transition metal oxides. Powder Technol 207:1–3CrossRef
Metadata
Title
Facile synthesis of uniform hierarchical composites CuO-CeO2 for enhanced dye removal
Authors
Pan Xu
Helin Niu
Jingshuai Chen
Jiming Song
Changjie Mao
Shengyi Zhang
Yuanhao Gao
Changle Chen
Publication date
01-12-2016
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 12/2016
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-016-3684-7

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