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09-09-2016 | Original Paper | Issue 6-7/2017 Open Access

Topics in Catalysis 6-7/2017

Fe Oxides on Ag Surfaces: Structure and Reactivity

Journal:
Topics in Catalysis > Issue 6-7/2017
Authors:
M. Shipilin, E. Lundgren, J. Gustafson, C. Zhang, F. Bertram, C. Nicklin, C. J. Heard, H. Grönbeck, F. Zhang, J. Choi, V. Mehar, J. F. Weaver, L. R. Merte
Important notes

Electronic supplementary material

The online version of this article (doi:10.​1007/​s11244-016-0714-8) contains supplementary material, which is available to authorized users.
This article originally listed an author (J. F. Weaver) incorrectly. The article has been updated.
An erratum to this article is available online at https://​doi.​org/​10.​1007/​s11244-017-0811-3.

Abstract

One layer thick iron oxide films are attractive from both applied and fundamental science perspectives. The structural and chemical properties of these systems can be tuned by changing the substrate, making them promising materials for heterogeneous catalysis. In the present work, we investigate the structure of FeO(111) monolayer films grown on Ag(100) and Ag(111) substrates by means of microscopy and diffraction techniques and compare it with the structure of FeO(111) grown on other substrates reported in literature. We also study the NO adsorption properties of FeO(111)/Ag(100) and FeO(111)/Ag(111) systems utilizing different spectroscopic techniques. We discuss similarities and differences in the data obtained from adsorption experiments and compare it with previous results for FeO(111)/Pt(111).

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