Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Cellulose
Published in: Cellulose 15/2022

09-08-2022 | Original Research

Flame retardant and hydrophobic cotton using a unique phosphorus–nitrogen–silicon-containing coating

Authors: Yu-Ting Yang, Jia-Li Huang, Xin Wang, Jaime Grunlan, Lei Song, Yuan Hu

Published in: Cellulose | Issue 15/2022

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Phosphorus–nitrogen–silicon-containing coatings consisting of tris(hydroxymethyl)phosphine oxide (THPO), 3,5-diamino-1,2,4-triazole (guanazole), and polydimethylsiloxane (PDMS) were prepared via a simple spraying deposition technique and applied to the cotton fabric to impart flame retardancy and hydrophobicity. SEM image reveals that THPO/Guanazole/PDMS-coated fabric has a rough surface and XPS spectra confirm the composition of the coating on the cotton surface. Direct flame testing indicates that the as-prepared coating can protect the cotton from burning. The limiting oxygen index increased from 18.0% for the uncoated fabric to 32.0% for the THPO/Guanazole-treated sample and 27.0% for the THPO/Guanazole/PDMS-treated sample. Furthermore, with additional THPO/Guanazole, there was a gradual reduction in PHRR values, 60% (79.0 kW/m2) for C2 and 76% (48.2 kW/m2) for C3 lower than that of untreated cotton. After hydrophobic treatment of C2 with PDMS, the PHRR is reduced to 127.5 kW/m2 (35.5% for C2-PDMS). Additionally, the coated cotton displays impressive hydrophobicity with a water contact angle of 133°. This unique approach provides a facile and effective flame retardant and hydrophobic treatment for cotton fabric.
previous article Preparation of thermochromic and vapochromic cotton fibers finished with poly(N-vinylcaprolactam-co-hydrazone)
next article Correction to: Dye adsorption revisited: application of the cationic dye adsorption method for the quantitative determination of the acidic surface groups of nanocellulose materials

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now
Appendix
Available only for authorised users
Literature
Chen W, Liu P, Min L, Zhou Y, Liu Y, Wang Q et al (2018) Non-covalently functionalized graphene oxide-based coating to enhance thermal stability and flame retardancy of PVA film. Nano Micro Lett 10:39CrossRef
Chen X, Ma Y, Cheng YJ, Zhang A, Liu W, Zhou H (2020) Synergistic effect between a novel silane-containing hyperbranched polyphosphamide and ammonium polyphosphate on the flame retardancy and smoke suppression of polypropylene composites. Polym Degrad Stabil 181:109348CrossRef
Fang F, Chen X, Zhang X, Cheng C, Xiao D, Meng Y et al (2016) Environmentally friendly assembly multilayer coating for flame retardant and antimicrobial cotton fabric. Prog Org Coat 90:258–266CrossRef
Gao D, Zhang Y, Lyu B, Wang P, Ma J (2019) Nanocomposite based on poly(acrylic acid)/attapulgite towards flame retardant of cotton fabrics. Carbohydr Polym 206:245–253PubMedCrossRef
Gao YN, Wang Y, Yue TN, Weng YX, Wang M (2021) Multifunctional cotton non-woven fabrics coated with silver nanoparticles and polymers for antibacterial, superhydrophobic and high performance microwave shielding. J Colloid Interface Sci 582:112–123PubMedCrossRef
Grancaric AM, Colleoni C, Guido E, Botteri L, Rosace G (2017) Thermal behaviour and flame retardancy of monoethanolamine-doped sol–gel coatings of cotton fabric. Prog Org Coat 103:174–181CrossRef
Guo WW, Wang X, Huang JL, Zhou YF, Cai W, Wang JL et al (2020) Construction of durable flame-retardant and robust superhydrophobic coatings on cotton fabrics for water–oil separation application. Chem Eng J 398:125661CrossRef
Hu S, Hu Y, Song L, Lu H (2011) Effect of modified organic–inorganic hybrid materials on thermal properties of cotton fabrics. J Therm Anal Calorim 103:423–427CrossRef
Jiang Z, Li H, He Y, Liu Y, Dong C, Zhu P (2019) Flame retardancy and thermal behavior of cotton fabrics based on a novel phosphorus-containing siloxane. Appl Surf Sci 479:765–775CrossRef
Li YC, Mannen S, Morgan AB, Chang S, Yang YH, Condon B et al (2011) Intumescent all-polymer multilayer nanocoating capable of extinguishing flame on fabric. Adv Mater 23:3926–3931PubMedCrossRef
Li S, Lin X, Li Z, Ren X (2019) Hybrid organic–inorganic hydrophobic and intumescent flame-retardant coating for cotton fabrics. Compos Commun 14:15–20CrossRef
Lin D, Zeng X, Li H, Lai X (2018) Facile fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via layer-by-layer assembly. Cellulose 25:3135–3149CrossRef
Niu H, Nabipour H, Wang X, Song L, Hu Y (2021) Phosphorus-free vanillin-derived intrinsically flame-retardant epoxy thermoset with extremely low heat release rate and smoke emission. ACS Sustain Chem Eng 9:5268–5277CrossRef
Qi LY, Qiu SL, Xi JC, Yu B, Hu Y, Xing WY (2022) Construction of super-hydrophobic, highly effective flame retardant coating for cotton fabric with superior washability and abrasion resistance. J Colloid Interface Sci 607:2019–2028PubMedCrossRef
Rahman MZ, Kundu CK, Nabipour H, Wang X, Song L, Hu Y (2020) Hybrid coatings for durable flame retardant and hydrophilic treatment of Polyamide 6.6 fabrics. Prog Org Coat 144:105640CrossRef
Ren X, Kou L, Liang J, Worley SD, Tzou YM, Huang TS (2008) Antimicrobial efficacy and light stability of N-halamine siloxanes bound to cotton. Cellulose 15:593–598CrossRef
Rosace G, Colleoni C, Trovato V, Iacono G, Malucelli G (2017) Vinylphosphonic acid/methacrylamide system as a durable intumescent flame retardant for cotton fabric. Cellulose 24:3095–3108CrossRef
Schartel B, Perret B, Dittrich B, Ciesielski M, Kraemer J, Mueller P et al (2016) Flame retardancy of polymers: the role of specific reactions in the condensed phase. Macromol Mater Eng 301:9–35CrossRef
Shang Q, Hu L, Yang X, Hu Y, Bo C, Pan Z et al (2021) Superhydrophobic cotton fabric coated with tannic acid/polyhedral oligomeric silsesquioxane for highly effective oil/water separation. Prog Org Coat 154:106191CrossRef
Shen ZQ, Chen L, Lin L, Deng CL, Zhao J, Wang YZ (2013) Synergistic effect of layered nanofillers in intumescent flame-retardant EPDM: montmorillonite versus layered double hydroxides. Ind Eng Chem Res 52:8454–8463CrossRef
Shi Y, Liu C, Liu L, Fu L, Yu B, Lv Y et al (2019) Strengthening, toughing and thermally stable ultra-thin MXene nanosheets/polypropylene nanocomposites via nanoconfinement. Chem Eng J 378:122267CrossRef
Tan Z, Wu C, Zhang M, Lv W, Qiu J, Liu C (2014) Phosphorus-containing polymers from tetrakis(hydroxymethyl) phosphonium sulfate III. A new hydrolysis-resistant tris(allyloxymethyl) phosphine oxide and its thiol-ene reaction under ultraviolet irradiation. RSC Adv 4:41705–41713CrossRef
Wang Z, Wei P, Qian Y, Liu J (2014) The synthesis of a novel graphene-based inorganic-organic hybrid flame retardant and its application in epoxy resin. Compos Part B Eng 60:341–349CrossRef
Wang J, Ma C, Mu X, Cai W, Liu L, Zhou X et al (2018) Construction of multifunctional MoSe2 hybrid towards the simultaneous improvements in fire safety and mechanical property of polymer. J Hazard Mater 352:36–46PubMedCrossRef
Xiao M, Guo Y, Zhang J, Liu Y, Ren Y, Liu X (2021) Diethylene triamine penta methylene phosphonic acid encountered silver ions: a convenient method for preparation of flame retardant and antibacterial lyocell fabric. Cellulose 28:7465–7481CrossRef
Xu F, Zhong L, Zhang C, Wang P, Zhang F, Zhang G (2019) Novel high-efficiency casein-based P–N-containing flame retardants with multiple reactive groups for cotton fabrics. ACS Sustain Chem Eng 7:13999–14008CrossRef
Xu F, Zhang G, Wang P, Dai F (2021) A novel epsilon-polylysine-derived durable phosphorus–nitrogen-based flame retardant for cotton fabrics. Cellulose 28:3807–3822CrossRef
Yan H, Zhao L, Fang Z, Wang H (2017) Construction of multilayer coatings for flame retardancy of ramie fabric using layer-by-layer assembly. J Appl Polym Sci 134:45556CrossRef
Yu M, Gu G, Meng WD, Qing FL (2007) Superhydrophobic cotton fabric coating based on a complex layer of silica nanoparticles and perfluorooctylated quaternary ammonium silane coupling agent. Appl Surf Sci 253:3669–3673CrossRef
Zhang Z, Ma Z, Leng Q, Wang Y (2019) Eco-friendly flame retardant coating deposited on cotton fabrics from bio-based chitosan, phytic acid and divalent metal ions. Int J Biol Macromol 140:303–310PubMedCrossRef
Zhang C, Xiao P, Ni F, Gu J, Chen J, Nie Y et al (2022) Breathable and superhydrophobic photothermic fabric enables efficient interface energy management via confined heating strategy for sustainable seawater evaporation. Chem Eng J 428:131142CrossRef
Zheng D, Zhou J, Wang Y, Zhang F, Zhang G (2018) A reactive flame retardant ammonium salt of diethylenetriaminepenta(methylene-phosphonic acid) for enhancing flame retardancy of cotton fabrics. Cellulose 25:787–797CrossRef
Zheng C, Sun Y, Cui Y, Yang W, Lu Z, Shen S et al (2021) Superhydrophobic and flame-retardant alginate fabrics prepared through a one-step dip-coating surface-treatment. Cellulose 28:5973–5984CrossRef
Zhong H, Wei P, Jiang P, Wu D, Wang G (2007) Synthesis and characteristics of a novel silicon-containing flame retardant and its application in poly 2,2-propane-(bisphenol)carbonate/acrylonitrile butadiene styrene. J Polym Sci Part B Polym Phys 45:1542–1551CrossRef
Zhou L, Liang Z, Li R, Huang D, Ren X (2017) Flame-retardant treatment of cotton fabric with organophosphorus derivative containing nitrogen and silicon. J Therm Anal Calorim 128:653–660CrossRef
Metadata
Title
Flame retardant and hydrophobic cotton using a unique phosphorus–nitrogen–silicon-containing coating
Authors
Yu-Ting Yang
Jia-Li Huang
Xin Wang
Jaime Grunlan
Lei Song
Yuan Hu
Publication date
09-08-2022
Publisher
Springer Netherlands
Published in
Cellulose / Issue 15/2022
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-022-04772-7

Other articles of this Issue 15/2022

Cellulose 15/2022 Go to the issue

Original Research

Efficient preparation of holocellulose nanofibers and their reinforcement potential

Original Research

A method for chemical and physical modification of oriented pulp fibre sheets

Correction

Correction to: Dye adsorption revisited: application of the cationic dye adsorption method for the quantitative determination of the acidic surface groups of nanocellulose materials

Original Research

Structural and chemical characterization of lignin and hemicellulose isolated from corn fibers toward agroindustrial residue valorization

Original Research

Shape memory and underwater superelastic mof@cellulose aerogels for rapid and large-capacity adsorption of metal ions

Review Paper

Polydopamine-based polysaccharide materials for water treatment