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Green Chemistry and Chemical Engineering: An Introduction Read chapter Read first chapter

2019 | OriginalPaper | Chapter

Green Chemical Engineering Based on Ionic Liquids

Authors : Ruixia Liu, Shengxin Chen, Bin He, Fei Dai, Hongguo Tang, Suojiang Zhang

Published in: Green Chemistry and Chemical Engineering

Publisher: Springer New York

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Excerpt

ILs
Ionic liquids
[EtNH3][NO3]
Ethylammonium nitrate
η ∞
Viscosity of infinite high temperature
E η
Energetic barrier of ionic motion
α
Hydrogen bond donating ability
β
Hydrogen bond accepting ability
π*
Bipolarity/polarizability
ET (30)
The molar electron transition energy of Reichardt’s dye 30
H0
Hammett function
[Emim]Cl
1-Ethyl-3-methylimidazolium chloride
Cl−
Chlorine anion
Br−
Bromine anion
I−
Iodine anion
[BF4]−
Tetrafluoroborate anion
[PF6]−
Hexafluorophosphate anion
[AsF4]−
Tetrafluoroarsenic anion
[NO3]−
Nitrate anion
[NO2]−
Nitrite anion
[CB11H12]−
Carbon borane anion
[CB11H6Cl6]−
Chloro-borane anion
[EMIM]+
1-Ethyl-3-methylimidazolium cation
[EMMIM]+
1-Ethyl-2,3-dimethyl imidazolium cation
[BMIM]+
1-Butyl-3-ethylimidazolium cation
[EEIM]+
1, 3-Diethyl imidazole cation
[BEIM]+
1-Butyl-3-methylimidazolium cation
[CF3CO2]-
Trifluoroacetic anion
[C3F7CO2]-
Perfluorinated butyric acid anion
[CH3CO2]-
Acetate anion
[CH3SO3]-
Methyl sulfonic acid anion
[(CF3SO2)2N]-
Trifluoromethyl sulfonyl anion
TSIL
Task-special ionic liquids
[TMG][TFE]
Tetramethylguanidine trifluoroethoxide
GL
Glycerol
GC
Glycerol carbonate
TOF
Turnover frequency
H2SO4
Sulfuric acid
HF
Hydrofluoric acid
[MOEMIM]Br
1-Methoxyethyl-3-methylimidazolium Bromine
[BMIM]Br
1-Butyl-3-methylimidazolium Bromine
[MOEMIM]NTf2
1-Methoxyethyl-3-methylimidazolium Bis(trifluoromethane sulfonimide)
[N111,1O2]NTf2
N,N,N-Trimethyl-N-methoxyethyl ammonium Bis(trifluoromethane sulfonimide)
ε
Dielectric constant
DMSO
Dimethyl sulfoxide
DMF
N,N-Dimethylformamide
[BMIM][H2PO4]
1-Butyl-3-methylimidazolium dihydrogen phosphate
[BMIM][HSO4]
1-Butyl-3-methylimidazolium hydrogen phosphate
[BMIM][DBP]
1-Butyl-3-methylimidazolium dibutyl Phosphate
[BMIM][BMP]
1-Butyl-3-methylimidazolium butylmethylphosphate
[Bmim][OAc]
1-Butyl-3-methylimidazolium acetate
[Bmim][BF4]
1-Butyl-3-methylimidazolium Tetrafluoroborate
MALDI-TOF-TOF-MS
Matrix-assisted Laser Desorption/Ionization Time of Flight Mass Spectrometry
MMA
Methyl methacrylate
HMF
5-Hydroxymethylfural
DFT
Density functional theory
PC
Propylene carbonate
DMC
Dimethyl carbonate
EG
Ethylene glycol
IPE
Institute of Process Engineering
CPCIF
China Petroleum and Chemical Industry Federation
CF3SO3H
Trifluoromethanesulfonic acid
[Cnmim][SbF6]/TFSA
1-Alkyl-3-methylimidazolium
[Bmim][SbF6]
Hexafluoroantimonate/trifluoromethanesulfonic acid
[Hmim][SbF6]
1-Butyl-3-methylimidazolium
[Omim][SbF6]
Hexafluoroantimonate
[Mmim][I]
1,3-Bimethylimidazolium iodide
[Emim][OAc]
1-Ethyl-3-methylimidazolium acetate
[Bmim][NTf2]
1-Butyl-3-methylimidazolium Bis(trifluoromethane sulfonimide)
TPAP
Tetrapropylammonium perruthenate;tetra-N-propylammonium perruthenate
TMP
Trimethylpentanes
DMH
Dimethylhexane
RON
Research Octane Number
…

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previous chapter Application of Ionic Liquids in Separation and Fractionation Processes
Literature
1.
Welton T (1999) Room temperature ionic liquids: solvents for synthesis and catalysis. Chem Rev 99:2071–2084PubMedCrossRef
2.
Marcinek A et al (2001) Ionic liquids: novel media for characterization of radical ions. J Phys Chem A 105(40):9305–9309CrossRef
3.
Stepnowski P, Zaleska A (2005) Comparison of different advanced oxidation processes for the degradation of room temperature ionic liquids. J Photochem Photobiol A Chem 170(1):45–50CrossRef
4.
Sun JM et al (2004) Direct oxidative carboxylation of styrene to styrene carbonate in the presence of ionic liquids. Catal Commun 5(2):83–87CrossRef
5.
Dyson PJ et al (2003) Determination of hydrogen concentration in ionic liquids and the effect (or lack of) on rates of hydrogenation. Chem Commun 3(19):2418–2419CrossRef
6.
Dyson PJ (2002) Synthesis of organometallics and catalytic hydrogenations in ionic liquids. Appl Organomet Chem 16(9):495–500CrossRef
7.
Ellis DJ et al (1999) Hydrogenation of non-activated alkenes catalysed by water-soluble ruthenium carbonyl clusters using a biphasic protocol. J Mol Catal A-Chem 150(1–2):71–75CrossRef
8.
Allardyce CS et al (2001) Inductively coupled plasma mass spectrometry to identify protein drug targets from whole cell systems. Chem Commun (24):2708–2709
9.
Keim W et al (1999) New method to recycle homogeneous catalysts from monophasic reaction mixtures by using an ionic liquid exemplified for the Rh-catalysed hydroformylation of methyl-3-pentenoate. J Catal 186(2):481–484CrossRef
10.
Kottsieper KW, Stelzer O, Wasserscheid P (2001) 1-vinylimidazole – a versatile building block for the synthesis of cationic phosphines useful in ionic liquid biphasic catalysis. J Mol Catal A-Chem 175(1–2):285–288CrossRef
11.
Illner P et al (2005) Mechanistic studies on the formation of Pt(II) hydroformylation catalysts in imidazolium-based ionic liquids. J Organomet Chem 690(15):3567–3576CrossRef
12.
Peng J, Deng Y (2001) Cycloaddition of carbon dioxide to propylene oxide catalyzed by ionic liquids. New J Chem 25(4):639–641CrossRef
13.
Qiao K, Deng Y (2003) A novel reaction in ionic liquids: selective cyclization of 1-dodecene to cyclododecane under moderate pressure. Tetrahedron Lett 44(10):2191–2193CrossRef
14.
Shi F et al (2004) Development of ionic liquids as green reaction media and catalysts. Catal Surv Jpn 8(3):179–186CrossRef
15.
Zhang HH et al (2018) Alkylation of isobutane/butene promoted by fluoride-containing ionic liquids. Fuel 211:233–240CrossRef
16.
Meng XZ et al (2017) Carbon-based materials enhanced emulsification to improve product distribution in isobutane/butene alkylation catalyzed by sulfuric acid. Ind Eng Chem Res 56(27):7700–7707CrossRef
17.
Wang LY et al (2017) Adamantane-based cation and MFn (-) anion synergistically enhanced catalytic performance of sulfuric acid for isobutane alkylation. Ind Eng Chem Res 56(28):7920–7929CrossRef
18.
Zhang HH et al (2017) Stability, acidity and interaction properties of Bmim SbF6 coupled with concentrated sulfuric acid. Sci China Chem 60(9):1243–1249CrossRef
19.
Huddleston JG et al (2001) Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation. Green Chem 3(4):156–164CrossRef
20.
Olivier-Bourbigou H, Magna L, Morvan D (2010) Ionic liquids and catalysis: recent progress from knowledge to applications. Appl Catal A Gen 373(1–2):1–56CrossRef
21.
Mellein BR et al (2007) Solvatochromic studies of ionic liquid/organic mixtures. J Phys Chem B 111(1):131–138PubMedCrossRef
22.
Welton T (2004) Ionic liquids in catalysis. Coord Chem Rev 248(21–24):2459–2477CrossRef
23.
Thomazeau C et al (2003) Determination of an acidic scale in room temperature ionic liquids. J Am Chem Soc 125(18):5264–5265PubMedCrossRef
24.
Dong K, Zhang SJ, Wang Q (2015) A new class of ion-ion interaction: Z-bond. Sci China Chem 58(3):495–500CrossRef
25.
Dymek CJ et al (1989) Evidence for the presence of hydrogen-bonded ion-ion interactions in the molten-salt precursor, 1-methyl-3-ethylimidazolium chloride. J Mol Struct 213:25–34CrossRef
26.
Suojiang Z et al (2006) The periodic change of ionic liquid and its guide graph. Sci China Ser B: Chem 36(1):25–35
27.
Wasserscheid P, Welton T (2002) Ionic liquids in synthesis. Wiley-VCH, New YorkCrossRef
28.
Šebesta R, Kmentová I, Toma Š (2008) Catalysts with ionic tag and their use in ionic liquids. Green Chem 10(5):484CrossRef
29.
Fei Z et al (2004) Brønsted acidic ionic liquids and their zwitterions: synthesis, characterization and pKa determination. Chem Eur J 10(19):4886–4893PubMedCrossRef
30.
Visser AE et al (2001) Task-specific ionic liquids for the extraction of metal ions from aqueous solutions. Chem Commun (1):135–136
31.
Dzyuba SV et al (2002) Expanding the polarity range of ionic liquids. Tetrahedron Lett 43:4657–4659CrossRef
32.
33.
Wang X et al (2017) Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids. Chin J Chem Eng 25(9):1182–1186CrossRef
34.
Zhang M et al (2017) Flow field in a liquid–liquid cyclone reactor for isobutane alkylation catalyzed by ionic liquid. Chem Eng Res Des 125:282–290CrossRef
35.
Wang H et al (2017) Isobutane/butene alkylation catalyzed by ionic liquids: a more sustainable process for clean oil production. Green Chem 19(6):1462–1489CrossRef
36.
Shang D et al (2017) Protic ionic liquid [Bim][NTf2] with strong hydrogen bond donating ability for highly efficient ammonia absorption. Green Chem 19(4):937–945CrossRef
37.
Zhao Y et al (2017) Ionic liquids for absorption and separation of gases: an extensive database and a systematic screening method. AICHE J 63(4):1353–1367CrossRef
38.
Li M et al (2017) Pebax-based composite membranes with high gas transport properties enhanced by ionic liquids for CO2 separation. RSC Adv 7(11):6422–6431CrossRef
39.
Liu X et al (2017) DBN-based ionic liquids with high capability for the dissolution of wool keratin. RSC Adv 7(4):1981–1988CrossRef
40.
Dan LU et al (2015) Isobutane alkylation catalyzed by ether functionalized ionic liquids. CIESC J 66(7):2481–2487
41.
Carmichael AJ, Seddon KR (2000) Polarity study of some 1-alkyl-3-methylimidazolium ambient-temperature ionic liquids with the solvatochromic dye, Nile Red. J Phys Org Chem 13:591–595CrossRef
42.
Muldoon MJ, Gordon CM, Dunkin IR (2001) Investigations of solvent–solute interactions in room temperature ionic liquids using solvatochromic dyes. J Chem Soc Perkin Trans 2(4):433–435CrossRef
43.
Aki SNVK, Brennecke JF, Samanta A (2001) How polar are room-temperature ionic liquids? Chem Commun (5):413–414
44.
Zhang Z et al (2017) Quantitative change in disulfide bonds and microstructure variation of Regenerated Wool Keratin from Various Ionic Liquids. ACS Sustain Chem Eng 5(3):2614–2622CrossRef
45.
Hunt PA, Ashworth CR, Matthews RP (2015) Hydrogen bonding in ionic liquids. Chem Soc Rev 44(5):1257–1288PubMedCrossRef
46.
Yu XX, Wang MM, Huang XR (2016) Spectroscopy and kinetics evidence for the hydrogen-bond activating effect of anion/cation of [Bmim]OAc on the hydrolysis of esters. J Mol Liq 216:354–359CrossRef
47.
48.
Crowhurst L et al (2006) Using Kamlet-Taft solvent descriptors to explain the reactivity of anionic nucleophiles in ionic liquids. J Org Chem 71(23):8847–8853PubMedCrossRef
49.
Jelicic A et al (2009) Prediction of the ionic liquid influence on propagation rate coefficients in methyl methacrylate radical polymerizations based on Kamlet-Taft solvatochromic parameters. Macromolecules 42(22):8801–8808CrossRef
50.
Ohno H, Fukaya Y (2009) Task specific ionic liquids for cellulose technology. Chem Lett 38(1):2–7CrossRef
51.
D'Anna F, Noto R (2007) Amine basicity: measurements of ion pair stability in ionic liquid media. Tetrahedron 63(47):11681–11685CrossRef
52.
O’Mahony AM et al (2008) Effect of water on the electrochemical window and potential limits of room-temperature ionic liquids. J Chem Eng 53:2884–2891
53.
Seddon KR, Stark A, Torres M-J (2000) Influence of chloride, water, and organic solvents on the physical properties of ionic liquids. Pure Appl Chem 72(12):2275–2287CrossRef
54.
Baker SN, Baker GA, Bright FV (2002) Temperature-dependent microscopic solvent properties of ‘dry’ and ‘wet’ 1-butyl-3-methylimidazolium hexafluorophosphate: correlation with ET(30) and Kamlet–Taft polarity scales. Green Chem 4(2):165–169CrossRef
55.
Dyson PJ, Ellis DJ, Laurenczy G (2003) Minor modifications to the ligands surrounding a ruthenium complex lead to major differences in the way in which they catalyse the hydrogenation of arenes. Adv Synth Catal 345(1–2):211–215CrossRef
56.
Stark A et al (2006) Metathesis of 1-octene in ionic liquids and other solvents: effects of substrate solubility, solvent polarity and impurities. Adv Synth Catal 348(14):1934–1941CrossRef
57.
Lin IJB, Vasam CS (2005) Metal-containing ionic liquids and ionic liquid crystals based on imidazolium moiety. J Organomet Chem 690(15):3498–3512CrossRef
58.
Yang X et al (2008) Suzuki coupling reactions in ether-functionalized ionic liquids: the importance of weakly interacting cations. Organometallics 27(15):3971–3977CrossRef
59.
Wang X et al (2007) Cytotoxicity of ionic liquids and precursor compounds towards human cell line HeLa. Green Chem 9(11):1191CrossRef
60.
Mo J, Xu LJ, Xiao JL (2005) Ionic liquid-promoted, highly regioselective heck arylation of electron-rich olefins by aryl halides. J Am Chem Soc 127(2):751–760PubMedCrossRef
61.
Wang L et al (2014) Hydroxyl-functionalized ionic liquid promoted CO2 fixation according to electrostatic attraction and hydrogen bonding interaction. Ind Eng Chem Res 53(20):8426–8435CrossRef
62.
Rocha CC et al (2016) Experimental and theoretical evidences of the influence of hydrogen bonding on the catalytic activity of a series of 2-hydroxy substituted quaternary ammonium salts in the styrene oxide/CO2 coupling reaction. J Catal 333:29–39CrossRef
63.
Liu M et al (2015) Insights into hydrogen bond donor promoted fixation of carbon dioxide with epoxides catalyzed by ionic liquids. Phys Chem Chem Phys 17(8):5959–5965PubMedCrossRef
64.
Li Y et al (2015) Catalytic activity of a series of synthesized and newly designed pyridinium-based ionic liquids on the fixation of carbon dioxide: a DFT investigation. Ind Eng Chem Res 54(33):8093–8099CrossRef
65.
Elageed EHM et al (2016) Selective synthesis of 5-substituted N-aryloxazolidinones by cycloaddition reaction of epoxides with arylcarbamates catalyzed by the ionic liquid BmimOAc. Eur J Org Chem 2016(21):3650–3656CrossRef
66.
Wang JQ et al (2012) Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates. Phys Chem Chem Phys 14(31):11021–11026PubMedCrossRef
67.
Corma A, Martinez A (1993) Chemistry, catalysts and processes for isoparaffin olefin alkylation actual situation and future. Catal Rev Sci Eng 35(4):483–570CrossRef
68.
Hommeltoft SI (2001) Isobutane alkylation: recent developments and future perspectives. Appl Catal A Gen 221:421–428CrossRef
69.
Zhen L, Jing C, Chungu X (2012) Advances in industrial application of ionic liquids. Chem Ind Eng Prog 31:2113–2123
70.
Liu S et al (2015) Alkylation of isobutane/isobutene using Brønsted–Lewis acidic ionic liquids as catalysts. Fuel 159:803–809CrossRef
71.
Jian L, Yongxiang L (2013) Advances inisobutane/butene alkylation used zeolite. Chem Ind Eng Prog 32:122–126CrossRef
72.
Tang S, Scurto AM, Subramaniam B (2009) Improved 1-butene/isobutane alkylation with acidic ionic liquids and tunable acid/ionic liquid mixtures. J Catal 268(2):243–250CrossRef
73.
Bui TLT, Korth W, Jess A (2012) Influence of acidity of modified chloroaluminate based ionic liquid catalysts on alkylation of iso-butene with butene-2. Catal Commun 25:118–124CrossRef
74.
Kumar P et al (2006) Production of alkylated gasoline using ionic liquids and immobilized ionic liquids. Appl Catal A Gen 304:131–141CrossRef
75.
Bui TLT et al (2009) Alkylation of isobutane with 2-butene using ionic liquids as catalyst. Green Chem 11(12):1961CrossRef
76.
Liu Y et al (2008) Alkylation of isobutene with 2-butene using composite ionic liquid catalysts. Appl Catal A Gen 346(1–2):189–193CrossRef
77.
Wang A et al (2016) Anionic clusters enhanced catalytic performance of protic acid ionic liquids for isobutane alkylation. Ind Eng Chem Res 55(30):8271–8280CrossRef
78.
Xing X, Zhao G, Cui J (2012) Chlorogallate(III) ionic liquids: synthesis, acidity determination and their catalytic performances for isobutane alkylation. Sci China Chem 55(8):1542–1547CrossRef
79.
Xing X et al (2012) Isobutane alkylation using acidic ionic liquid catalysts. Catal Commun 26:68–71CrossRef
80.
Cui P et al (2013) Ionic liquid enhanced alkylation of iso-butane and 1-butene. Catal Today 200:30–35CrossRef
81.
Huang Q et al (2015) Improved catalytic lifetime of H2SO4 for isobutane alkylation with trace amount of ionic liquids buffer. Ind Eng Chem Res 54(5):1464–1469CrossRef
82.
Rogers RD, Seddon KR (2003) Ionic liquids:solvents of the future. Sci China Chem 302:792–793
83.
Seddon KR (1997) Ionic liquids for clean technology. J Chem Tech Biotechnol 68:351–356CrossRef
84.
Liu Z et al (2014) Reaction performance of isobutane alkylation catalyzed by a composite ionic liquid at a short contact time. AICHE J 60(6):2244–2253CrossRef
85.
Huang C et al (2004) Effects of additives on the properties of chloroaluminate ionic liquids catalyst for alkylation of isobutane and butene. Appl Catal A Gen 277(1–2):41–43CrossRef
86.
Cui J et al (2014) Identification of acidic species in chloroaluminate ionic liquid catalysts. J Catal 320:26–32CrossRef
87.
Qi L et al (2015) Droplet size distribution and droplet size correlation of chloroaluminate ionic liquid–heptane dispersion in a stirred vessel. Chem Eng J 268:116–124CrossRef
88.
Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry. Chem Soc Rev 37(1):123–150CrossRefPubMed
89.
Chauvin Y (2006) Olefin metathesis: the early days (Nobel lecture). Angew Chem Int Ed 45(23):3740–3747CrossRef
90.
Steinruck HP, Wasserscheid P (2015) Ionic liquids in catalysis. Catal Lett 145(1):380–397CrossRef
91.
Holbrey JD, Plechkova NV, Seddon KR (2006) Recalling COIL. Green Chem 8(5):411–414CrossRef
92.
Schmid CR et al (2004) Demethylation of 4-methoxyphenylbutyric acid using molten pyridinium hydrochloride on multikilograrn scale. Org Process Res Dev 8(4):670–673CrossRef
93.
Pitawala J et al (2009) Thermal properties and ionic conductivity of imidazolium bis(trifluoromethanesulfonyl)imide dicationic ionic liquids. J Phys Chem B 113(31):10607–10610PubMedCrossRef
94.
95.
Mohanty AD, Bae C (2014) Mechanistic analysis of ammonium cation stability for alkaline exchange membrane fuel cells. J Mater Chem A 2(41):17314–17320CrossRef
96.
97.
Hugar KM, Kostalik HAT, Coates GW (2015) Imidazolium cations with exceptional alkaline stability: a systematic study of structure-stability relationships. J Am Chem Soc 137(27):8730–8737PubMedCrossRef
98.
Xu L et al (2000) Heck Reaction in Ionic Liquids and the in Situ Identification of N-Heterocyclic Carbene Complexes of Palladium. Organometallics 19(6):1123–1127CrossRef
99.
Mathews CJ et al (2001) In situ formation of mixed phosphine-imidazolylidene palladium complexes in room-temperature ionic liquids. Organometallics 20(18):3848–3850CrossRef
100.
McGuinness DS, Yates BF, Cavell KJ (2001) Unprecedented C–H bond oxidative addition of the imidazolium cation to Pt0: a combined density functional analysis and experimental study. Chem Commun (4):355–356
101.
Hsu J-C, Yen Y-H, Chu Y-H (2004) Baylis–Hillman reaction in [bdmim][PF 6] ionic liquid. Tetrahedron Lett 45(24):4673–4676CrossRef
102.
Clough MT et al (2015) Ionic liquids: not always innocent solvents for cellulose. Green Chem 17(1):231–243CrossRef
103.
Zhu Q et al (2007) An unprecedented tandem 1,3-dipolar cycloaddition-cheletropic elimination: a facial approach to novel push-pull olefins. Org Biomol Chem 5(8):1282–1286PubMedCrossRef
104.
Clement ND, Cavell KJ (2004) Transition-metal-catalyzed reactions involving imidazolium salt/N-heterocyclic carbene couples as substrates. Angew Chem 116(29):3933–3935CrossRef
105.
106.
Yang Y et al (2014) A stable anion exchange membrane based on imidazolium salt for alkaline fuel cell. J Membr Sci 467:48–55CrossRef
107.
Ebner G et al (2008) Side reaction of cellulose with common 1-alkyl-3-methylimidazolium-based ionic liquids. Tetrahedron Lett 49(51):7322–7324CrossRef
108.
Heinze T et al (2008) Interactions of ionic liquids with polysaccharides – 2: cellulose. Macromol Symp 262(1):8–22CrossRef
109.
Gurau G et al (2011) Demonstration of chemisorption of carbon dioxide in 1,3-dialkylimidazolium acetate ionic liquids. Angew Chem Int Ed Engl 50(50):12024–12026PubMedCrossRef
110.
Holbrey JD et al (2003) 1,3-dimethylimidazolium-2-carboxylate: the unexpected synthesis of an ionic liquid precursor and carbene-CO2 adduct. Chem Commun (1):28–29
111.
Smiglak M et al (2007) Ionic liquids via reaction of the zwitterionic 1,3-dimethylimidazolium-2-carboxylate with protic acids. Overcoming synthetic limitations and establishing new halide free protocols for the formation of ILs. Green Chem 9(1):90–98CrossRef
112.
Oelkers B, Sundermeyer J (2011) Pentaalkylmethylguanidinium methylcarbonates – versatile precursors for the preparation of halide-free and metal-free guanidinium-based ILs. Green Chem 13(3):608CrossRef
113.
Cabaco MI et al (2013) On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate. Chem Commun (Camb) 49(94):11083–11085CrossRef
114.
Delaude L, Demonceau A, Wouters J (2009) Assessing the potential of zwitterionic NHC·CS2 adducts for probing the stereoelectronic parameters of N-heterocyclic carbenes. Eur J Inorg Chem 2009(13):1882–1891CrossRef
115.
Farmer V, Welton T (2002) The oxidation of alcohols in substituted imidazolium ionic liquids using ruthenium catalysts. Green Chem 4(2):97–102CrossRef
116.
AlNashef IM et al (2010) A novel method for the synthesis of 2-imidazolones. Tetrahedron Lett 51(15):1976–1978CrossRef
117.
Kelemen Z et al (2014) An abnormal N-heterocyclic carbene-carbon dioxide adduct from imidazolium acetate ionic liquids: the importance of basicity. Chemistry 20(40):13002–13008PubMedCrossRef
118.
Zhao D, Liao Y, Zhang Z (2007) Toxicity of ionic liquids. Clean Soil Air Water 35(1):42–48CrossRef
Metadata
Title
Green Chemical Engineering Based on Ionic Liquids
Authors
Ruixia Liu
Shengxin Chen
Bin He
Fei Dai
Hongguo Tang
Suojiang Zhang
Copyright Year
2019
Publisher
Springer New York
Book
Green Chemistry and Chemical Engineering

Print ISBN: 978-1-4939-9059-7

Electronic ISBN: 978-1-4939-9060-3

Copyright Year: 2019

DOI
https://doi.org/10.1007/978-1-4939-9060-3_1018