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Polymer Bulletin
Published in: Polymer Bulletin 6/2012

01-09-2012 | Original Paper

Green preparation and physical properties of maleated sulfur-prevulcanized natural rubber

Authors: Sa-Ad Riyajan, Isara Intharit, Pramuan Tangboriboonrat

Published in: Polymer Bulletin | Issue 6/2012

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Abstract

The maleated sulfur-prevulcanized natural rubber (M-SPNR) was prepared from grafting maleic anhydride (MA) onto SPNR latex particle by using benzoyl peroxide as an initiator. Natural rubber latex particle was vulcanized first, and then it was maleated to M-SPNR. The average particle size of M-SPNR was greater than that of SPNR possibly due to the formation of aggregate after addition of MA. The symmetric (strong) and asymmetric (weak) carbonyl stretching vibrations of succinic anhydride rings were confirmed by ATR–FTIR at 1,780–1,784 and 1,854 cm−1, respectively. The swelling ratios of M-SPNR latex film decreased with increasing MA contents. The tensile strength, modulus, hardness, and elongation at break of SPNR latex film dramatically increased after grafting with MA. Due to the reduction of double bond, the thermal stability of M-SPNR film was better than that of SPNR. The environmental friendly M-SPNR would be further applied as a compatibilizer between NR and biopolymer.
next article In situ polymerization of uniform poly(urea–formaldehyde) microcapsules containing paraffins under the high-speed agitation without emulsifier

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Literature
1.
Pukkate N, Kitai T, Yamamoto Y, Kawazura T, Sakdapipanich J, Kawahara S (2007) Nano-matrix structure formed by graft-copolymerization of styrene onto rubber. Eur Polym J 43:3208–3214CrossRef
2.
Riyajan S, Tanbumrung K, Pinyocheep P (2010) Physical properties of a ‘green’ polymer blend based on PVA starch and ENR. KGK-Kaust Gummi Kunst 63:371–376
3.
Gan LH, Ng SC (1986) Kinetic studies of the performic acid epoxidation of natural rubber latex stabilized by cationic surfactant. Eur Polym J 22(1986):573–576CrossRef
4.
Riyajan S, Chaiponban S, Tanbumrung K (2009) Investigation of the preparation and physical properties of a novel semi-interpenetrating polymer network based on epoxised NR and PVA using maleic acid as the crosslinking agent. Chem Eng J 153:199–205CrossRef
5.
Johnson T, Thomas S (2000) Effect of epoxidation on the transport behaviour and mechanical properties of natural rubber. Polymer 41:7511–7522CrossRef
6.
Riyajan S (2009) Activation energy and thermodynamic parameters of cyclization in purified natural rubber latex using a trimethyl silyl triflate. J Elastom Plast 41:133–144CrossRef
7.
Riyajan S, Tuampoemsab S, Sakdapipanich JP (2008) Dynamic mechanical and physical properties of cyclized natural rubber blends. KGK-Kaust Gummi Kunst 61:665–670
8.
Riyajan S, Sakdapipanich JT (2009) Thermal property and thermodynamic parameter of rubber blends containing the cyclic structure. KGK-Kaust Gummi Kunst 62:665–670
9.
Mahittikul A, Prasassarakich P, Rempel GL (2009) Hydrogenation of natural rubber latex in the presence of [Ir(cod)(PCy3)(py)]PF6. J Mol Catal A 297:135–141CrossRef
10.
Simma K, Rempel GL, Prasassarakich P (2009) Improving thermal and ozone stability of skim natural rubber by diimide reduction. Polym Degrad Stabil 94:1914–1923CrossRef
11.
Ho CC, Khew MC (1999) Surface characterisation of chlorinated unvulcanised natural rubber latex films. Inter J Adhes Adhes 19:387–398CrossRef
12.
Krentsel LB, Travin SO, Litmanovich AD, Yutujan KK (1985) Initial stage of the chlorination of natural rubber. Eur Polym J 21:405–408CrossRef
13.
Kofman VL, Podmasterev VV, Razumovskii SD, Krentsel LB, Litmanovich AD (1987) Structure of products of the initial stage of chlorination of natural rubber. Polym Sci USSR 29:1224–1230CrossRef
14.
Kongparakul S, Prasassarakich P, Rempel GL (2009) Catalytic hydrogenation of styrene-g-natural rubber (ST-g-NR) in the presence of OsHCl(CO)(O2)(PCy3)2. Eur Polym J 45:2358–2373CrossRef
15.
Oliveira PC, Guimarães A, Cavaillé JY, Chazeau L, Gilbert RG, Santos AM (2005) Poly(dimethylaminoethyl methacrylate) grafted natural rubber from seeded emulsion polymerization. Polymer 46:1105–1111CrossRef
16.
Nakason C, Kaesaman A, Supasanthitikul P (2004) The grafting of maleic anhydride onto natural rubber. Polym Test 23:35–41CrossRef
17.
Nakason C, Saiwari S, Kaesaman A (2006) Rheological properties of maleated natural rubber/polypropylene blends with phenolic modified polypropylene and polypropylene-g-maleic anhydride compatibilizers. Polym Test 25:413–423CrossRef
18.
Ismail H, Rusli A, Rashid AA (2005) Maleated natural rubber as a coupling agent for paper sludge filled natural rubber composites. Polym Test 24:856–862CrossRef
19.
Carone E Jr, Kopcak U, Gonçalves MC, Nunes SP (2000) In situ compatibilization of polyamide 6/natural rubber blends with maleic anhydride. Polymer 41:5929–5935CrossRef
20.
Veyret R, Elaissari A, Marianneau P, Sall AA, Delair T (2005) Magnetic colloids for the generic capture of viruses. Anal Biochem 346:59–68CrossRef
21.
Rippel MM, Lee LT, Leite CAP, Galembeck F (2003) Skim and cream natural rubber particles: colloidal properties, coalescence and film formation. J Colloid Interface Sci 268:330–340CrossRef
22.
Afkhami A, Bahram M, Gholami S, Zand Z (2005) Micell-mediated extraction for the spectrophotometric determination of nitrite in water and biological samples based on its reaction with p-nitroaniline in the presence of diphenylamine. Anal Biochem 336:295–299CrossRef
23.
Abe M, Uchiyama H, Yamaguchi T, Suzuki T, Oginot K (1992) Micelle formation by pure nonionic surfactants and their mixtures. Langmuir 8:2147–2151CrossRef
24.
Bacn NV, Mihailov M, Terlemezyan L (1991) On the stability of natural rubber latex acidified by acetic acid and subsequent epoxidation by peracetic acid. Eur Polym J 27:557–563CrossRef
25.
Romero-Cano MS, Martin-Rodriguez A, Chauveteau G, De Las Nieves FJ (1998) Electrokinetic characterization of polystyrene–non-ionic surfactant complexes. Colloid Surf A 140:347–356CrossRef
26.
Thwala JM, Goodwin JW, Mills PD (2009) Electrokinetic studies of colloidal silica particles dispersed in non-aqueous media in the presence of a nonionic surfactant, dodecylhexaethylene glycol monoether (C12E6). Colloid Surf A 335:33–42CrossRef
27.
Martins MA, Moreno RMB, McMahan CM, Brichta JL, Gonçalves PDS, Mattoso LHC (2008) Thermooxidative study of raw natural rubber from Brazilian IAC 300 series clones. Thermochim Acta 474:62–66CrossRef
28.
Menon ARR, Pillai CKS, Nando GB (1998) Modification of natural rubber with phosphatic plasticizers: a comparison of phosphorylated cashew nut shell liquid prepolymer with 2-ethyl hexyl diphenyl phosphate. Eur Polym J 34:923–929CrossRef
Metadata
Title
Green preparation and physical properties of maleated sulfur-prevulcanized natural rubber
Authors
Sa-Ad Riyajan
Isara Intharit
Pramuan Tangboriboonrat
Publication date
01-09-2012
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 6/2012
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-012-0746-6

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