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Cellulose
Published in: Cellulose 6/2022

28-02-2022 | Review Paper

Heterogeneous strategies for selective conversion of lignocellulosic polysaccharides

Authors: Zhengqiu Yuan, Wei Dai, Shenghong Zhang, Fengxin Wang, Jian Jian, Jianxian Zeng, Hu Zhou

Published in: Cellulose | Issue 6/2022

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Abstract

Lignocellulosic biomass is the most abundant renewable carbon resource on earth, for which many efforts have been made to convert it using various chemocatalytic processes. Heterogeneously chemocatalytic conversion conducted based on reusable solid catalysts is the process with the greatest potential studied presently. This review provides insights into the representative achievements in the research area of heterogeneous chemical catalysis technologies for the production of value-added chemicals from lignocellulosic polysaccharides (cellulose and hemicellulose). Popular approaches for the conversion of lignocellulosic polysaccharides into chemicals, including hydrolyzation (glucose, xylose and arabinose), dehydration (5-hydroxymethylfurfuran, furfural, levulinic acid and lactic acid), hydrogenation/hydrogenolysis (sorbitol, mannitol, xylitol, 1,2-propylene glycol, ethlyene glycol and ethanol), selective oxidation (gluconic acid), have been comprehensively reviewed. However, technological barriers still exist, which have to be overcome to further integrate hydrolysis with the refinery processes based on multifunctional solid catalysts, and convert ligncellulosic polysaccharides into value-added fine chemicals. In general, the approaches and technologies are discussed and critically evaluated in terms of the possibilities and potential for further industrial implementation.

Graphical abstract

Heterogeneously chemocatalytic conversions conducted over reusable solid catalysts are the major processes presently studied. Popular approaches to lignocellulosic polysaccharides (cellulose and hemicellulose) conversion to chemicals have been comprehensively reviewed.
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Metadata
Title
Heterogeneous strategies for selective conversion of lignocellulosic polysaccharides
Authors
Zhengqiu Yuan
Wei Dai
Shenghong Zhang
Fengxin Wang
Jian Jian
Jianxian Zeng
Hu Zhou
Publication date
28-02-2022
Publisher
Springer Netherlands
Published in
Cellulose / Issue 6/2022
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-022-04434-8

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