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High Performance, Low Sensitivity: The Impossible (or Possible) Dream? Read chapter Read first chapter

2017 | OriginalPaper | Chapter

High Explosives and Propellants Energetics: Their Dissolution and Fate in Soils

Authors : Katerina Dontsova, Susan Taylor

Published in: Energetic Materials

Publisher: Springer International Publishing

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Abstract

Live-fire military training scatters energetic compounds onto range soils. Once deposited on soil the explosives and propellants ingredients can dissolve in water, experience complex interactions with soil constituents, and migrate to groundwater. While in contact with soil these chemicals are also subject to biotic and abiotic (hydrolysis, photolysis, and reaction with metals) transformation both in the solid and in the aqueous state. In this chapter we summarize the current state of knowledge on how energetic residues are deposited on range soils, what the residues look like and how quickly they dissolve. We also describe the key physicochemical properties (aqueous solubility, (S w ) pH, octanol-water partitioning coefficient, (\(K_{ow}\))) of the energetic compounds in high explosives and propellants and how these parameters influence their biogeochemical interactions with soil. Knowing the reaction routes of these chemicals will help us understand their fate, their ecological impact, and how to enhance in situ remediation.

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previous chapter Physical Properties of Select Explosive Components for Assessing Their Fate and Transport in the Environment
next chapter Insensitive Munitions Formulations: Their Dissolution and Fate in Soils
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Metadata
Title
High Explosives and Propellants Energetics: Their Dissolution and Fate in Soils
Authors
Katerina Dontsova
Susan Taylor
Copyright Year
2017
Book
Energetic Materials

Print ISBN: 978-3-319-59206-0

Electronic ISBN: 978-3-319-59208-4

Copyright Year: 2017

DOI
https://doi.org/10.1007/978-3-319-59208-4_11

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