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03-02-2022 | Original Research

High-performance cotton fabric-based supercapacitors consisting of polypyrrole/Ag/graphene oxide nanocomposite prepared via UV-induced polymerization

Authors: Chunliu Liang, Limin Zang, Fangfang Shi, Chao Yang, Jianhui Qiu, Qifan Liu, Zhenming Chen

Published in: Cellulose | Issue 4/2022

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Abstract

Cotton fabric (CF) fabricated by natural cellulose fibers has porous structure, abundant hydrophilic hydroxyl groups and good mechanical flexibility, which is a promising substrate for flexible fabric-based supercapacitors. Graphene oxide (GO) nanosheets were fixed on the CF by vacuum filtration, and then the pyrrole monomers and silver ions (Ag⁺) were adsorbed to the surface of GO/CF by π-π and electrostatic interactions, respectively. Polypyrrole/silver (PPy/Ag) nanoparticles were generated on the surface of GO/CF via in situ UV-induced polymerization, forming the flexible PPy/Ag/GO/CF electrodes. The electrodes combine three active materials (PPy, Ag and GO), which show good electrochemical performance. The electrode prepared under optimum conditions (UV irradiation time: 120 min; mass loading of GO on the CF: 3 mg cm⁻²) exhibits a high specific capacitance of 1664.0 mF cm⁻². The flexible symmetric quasi-solid-state fabric-based supercapacitor (QFSC) based on the optimum electrode also keeps superior electrochemical performance and excellent mechanical flexibility, which has a great application prospect for wearable energy storage devices.

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Title: High-performance cotton fabric-based supercapacitors consisting of polypyrrole/Ag/graphene oxide nanocomposite prepared via UV-induced polymerization
Authors: Chunliu Liang
Limin Zang
Fangfang Shi
Chao Yang
Jianhui Qiu
Qifan Liu
Zhenming Chen
Publication date: 03-02-2022
Publisher: Springer Netherlands
Published in: Cellulose / Issue 4/2022
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04454-4

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