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Journal of Materials Engineering and Performance

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09-11-2021

High Phosphorus Pig Iron as Sacrificial Anode in Seawater

Authors: Nisheeth Kr. Prasad, A. S. Pathak, S. Kundu, Pankaj Panchal, K. Mondal

Published in: Journal of Materials Engineering and Performance | Issue 4/2022

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Abstract

The possibility of high phosphorus pig irons (1.5, 3.5 and 8.0 wt.%P) for their use as sacrificial anode is discussed by analyzing the electrochemical performance and measurement of anode capacity in artificial seawater for 252 days. Linear and dynamic polarization, impedance spectroscopy and impressed current test were carried out to check the electrochemical performance, whereas impressed direct current test was used to understand anode capacity, consumption rate and efficiency of the pig iron samples. Enrichment of surface with P, inhomogeneous microstructure and presence of entrapped inclusions were found to be conducive to improve the electrochemical performance of pig iron anode. The corrosion of the newly designed anodes was also found to be macroscopically uniform.

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P.R. Roberge, Handbook of Corrosion Engineering, 1st ed. McGraw-Hill, New York, 1999.

A.W. Peabody, Peabody’s Control of Pipeline Corrosion, 2nd ed. NACE International, 2001.

M. Ph Refait, R. Jeannin, H.A. Sabot and S. Pineau, Corrosion and Cathodic Protection of Carbon Steel in the Tidal Zone: Products, Mechanisms, and Kinetics, Corros. Sci., 2015, 90, p 375–382.CrossRef

S.J. Kim, M. Okido and K.M. Moon, An Electrochemical Study of Cathodic Protection of Steel Used for Marine Structures, Korean J. Chem. Eng., 2003, 20, p 560–565.CrossRef

J. Ma and J. Wen, Corrosion Analysis of Al-Zn-In-Mg-Ti-Mn Sacrificial Anode Alloy, J. Alloys Compd., 2010, 496, p 110–115.CrossRef

M.A. Jingling, W. Jiuba, L.I. Gengxin and X.V. Chunhua, The Corrosion Behavior of Al-Zn-In-Mg-Ti Alloy in NaCl Solution, Corros. Sci., 2020, 52, p 534–539.CrossRef

J. Wen, J. He and X. Lu, Influence of Silicon on the Corrosion Behavior of Al-Zn-In-Mg-Ti Sacrificial Anode, Corros. Sci., 2011, 53, p 3861–3865.CrossRef

B.S. Boroujeny, M.R. Ghashghaei and E. Akbari, Effect of SIMA (Strain Induced Melt Activation) on Microstructure and Electrochemical Behavior of Al-Zn-In Sacrificial Anodes, J. Alloys Compd., 2018, 731, p 354–363.CrossRef

A. Muazu and S.A. Yaro, Effects of Zinc Addition on the Performance of Aluminium as Sacrificial Anode in Seawater, J. Min. Mater. Char. Eng., 2011, 10, p 185–198.

10.

S. Khireche, D. Boughrara, A. Kadri, L. Hamadou and N. Benbrahim, Corrosion Mechanism of Al, Al-Zn and Al-Zn-Sn Alloys in 3 wt% NaCl Solution, Corros. Sci., 2014, 87, p 504–516.CrossRef

11.

W. Xiong, G.T. Qi, X.P. Guo and Z.L. Lu, Anodic Dissolution of Al Sacrificial Anodes in NaCl Solution Containing Ce, Corros. Sci., 2011, 53, p 1298–1303.CrossRef

12.

S.M.A. Shibli, V.S. Gireesh and S. George, Surface Catalysis Based on Ruthenium Dioxide for Effective Activation of Aluminium Sacrificial Anodes, Corros. Sci., 2004, 46, p 819–830.CrossRef

13.

I.-C. Park and S.-J. Kim, Determination of Corrosion Protection Current Density Requirement of Zinc Sacrificial Anode for Corrosion Protection of AA5083-H321 in Sea Water, Appl. Surf. Sci., 2020, 509, p 145346–145354.CrossRef

14.

M.E. Parker and E.G. Peattie, Pipeline Corrosion and Cathodic Protection, 3rd ed. Gulf Publishing Company, Houston, 1999, p 245–250

15.

F. Wang, J. Xu, Y. Xu, L. Jiang and G. Ma, A Comparative Investigation on Cathodic Protections of Three Sacrificial Anodes on Chloride-Contaminated Reinforced Concrete, Constr. Build. Mater., 2020, 246, p 118476–118486.CrossRef

16.

D. Ferdian, Y. Pratesa, I. Togina and I. Adelia, Development of Al-Zn-Cu Alloy for Low Voltage Aluminium Sacrificial Anode, Procedia Eng., 2017, 184, p 418–422.CrossRef

17.

E. Mottin, C. Caplat, T. Latire, A. Mottier, M.-L. Mahaut, K. Costil, D. Barillier, J.-M. Lebel and A. Serpentini, Effect of Zinc Sacrificial Anode Degradation on the Defence System of the Pacific Oyster, Crassostrea Gigas; Chronic and Acute Exposures, Mar. Pollut. Bull., 2012, 64, p 1911–1920.CrossRef

18.

T. Kaewmaneekul and G. Lothongkum, Effect of Aluminium on the Passivation of Zinc-Aluminium Alloys in Artificial Seawater at 80 °C, Corros. Sci., 2013, 66, p 67–77.CrossRef

19.

S. Thomas, N. Birbilis, M.S. Venkatraman and I.S. Cole, Corrosion of Zinc as a Function of pH, Corrosion, 2012, 68, p 150091–150099.CrossRef

20.

K. Sarkar, P.K. Rai, P.K. Katiyar, B. Satapathy, A.S. Pathak, M. Dutta, A. Banerjee and K. Mondal, Composite (Glass + Crystalline) Coatings from Blast Furnace Pig Iron by High Velocity Oxy-Fuel (HVOF) Process and Their Electrochemical Behavior, Surf. Coat. Tech., 2019, 372, p 72–83.CrossRef

21.

R. Balasubramaniam and A.V. Ramesh Kumar, Characterization of Delhi Iron Pillar rust by X-ray Diffraction, Fourier Transform Infrared Spectroscopy and Mossbauer Spectroscopy, Curr. Sci., 2002, 82, p 1357–1365.

22.

R. Balasubramaniam, On the Corrosion Resistance of the Delhi Iron Pillar, Corros. Sci., 2000, 42, p 2103–2129.CrossRef

23.

R. Balasubramaniam and A.V.R. Kumar, Corrosion Resistance of the Dhar Iron Pillar, Corros. Sci., 2003, 45, p 2451–2465.CrossRef

24.

H.J. Krautschick, H.J. Grabke and W. Diekmann, The Effect of Phosphorus on the Mechanism of Intergranular Stress Corrosion Cracking of Mild Steels in Nitrate Solutions, Corros. Sci., 1988, 28, p 251–258.CrossRef

25.

N.K. Prasad, S. Kundu and K. Mondal, Possibility of High Phosphorus Pig Iron as Sacrificial Anode, J. Mater. Eng. Perform., 2018, 27, p 3335–3349.CrossRef

26.

N.K. Prasad, A.S. Pathak, S. Kundu, P. Panchal and K. Mondal, On the Novel Approach of Cathodic Protection of Mild Steel in Simulated Concrete Pore Solution and Concrete Mortar Using High Phosphorus Pig Iron Sacrificial Anodes, J. Mater. Res. Technol., 2021, 14, p 582–608.CrossRef

27.

N.K. Prasad, A.S. Pathak, S. Kundu, and K. Mondal, Influence of Deaeration, Cl⁻ Ion and Strong Oxidizer on the Active Behavior of the High Phosphorus Containing Pig Iron and Subsequent Effect on the Sacrificial Anode Behavior, Met. Mater. Int, 2021. https://doi.org/10.1007/s12540-021-01110-7CrossRef

28.

Standard Practice for the Preparation of Substitute Ocean Water, ASTM D1141-98, ASTM International, West Conshohocken, PA (2013)

29.

Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements, ASTM G102-89, ASTM International, West Conshohocken, PA (2015)

30.

Standard Practice for Preparing, Cleaning and Evaluating Corrosion Test Specimens, ASTM G1-03, ASTM International, West Conshohocken, PA (2017)

31.

Standard Practice for Laboratory Immersion Corrosion Testing of Metals, ASTM G31-72, ASTM International, West Conshohocken, PA (2004)

32.

N. Mahata, A. Banerjee, P.K. Rai, P. Bijalwan, A.S. Pathak, S. Kundu, M. Dutta and K. Mondal, Glassy Blast Furnace Pig Iron and Design of Other Glassy Compositions Using Thermodynamic Calculations, J. Non-Cryst. Solids, 2018, 484, p 95–104.CrossRef

33.

R. Balasubramaniam, A.V.R. Kumar and P. Dillmann, Characterization of Rust on Ancient INDIAN Iron, Curr. Sci., 2003, 85, p 1546–1555.

34.

P.K. Rai, S. Shekhar, M. Nakatani, M. Ota, S.K. Vajpai, K. Ameyama and K. Mondal, Effect of Harmonic Microstructure on the Corrosion Behavior of SUS304L Austenitic Stainless Steel, Metall. Mater. Trans. A, 2016, 47, p 6259–6269.CrossRef

35.

P.K. Rai, D. Naidu, B. Satapathy, K. Sarkar, A.S. Pathak, P. Bijalwan, M. Dutta, A. Banerjee and K. Mondal, Amorphous/Nanocrystalline Composite Coatings Using Blast Furnace Pig Iron Composition by Atmospheric Plasma Spray and Their Electrochemical Response, J. Therm. Spray Techn., 2020, 29, p 843–856.CrossRef

36.

C.F. Windish, D.R. Baer, R.H. Jones and M.H. Anglehard, The Influence of Phosphorus on the Corrosion of Iron in Calcium Nitrate, J. Electrochem. Soc., 1992, 139, p 390–398.CrossRef

37.

P.H. Lo, W.T. Tsai, J.T. Lee and M.P. Hung, Role of P in the Electrochemical Behavior of Electroless Ni-P Alloys in 3.5wt% NaCl Solution, Surf. Coat. Tech., 1994, 67, p 27–34.CrossRef

38.

J. Flis and D.J. Duquette, Effect of Phosphorus on Anodic Dissolution and Passivation of Nickel in Near Neutral Solutions, Corrosion, 1985, 41, p 700–706.CrossRef

39.

P.K. Rai, B. Satapathy, K. Sarkar, P. Bijalwan, M. Dutta, A. Banerjee and K. Mondal, Experimental Validation of Glass Forming Ability of Melt Spun Ribbons of Pig Iron and Its Derivative Compositions and Their Corrosion Behavior, J. Non-Cryst. Solids, 2020, 532, p 119883–119895.CrossRef

40.

J. Yang, Y. Lu, Z. Guo, J. Gu and C. Gu, Corrosion Behavior of a Quenched and Partitioned Medium Carbon Steel in 3.5wt% NaCl Solution, Corros. Sci., 2018, 130, p 64–75.CrossRef

41.

W.R. Osorio, J.E. Spinelli, C.R.M. Afonso, L.C. Peixoto and A. Garcia, Electrochemical Corrosion Behavior of Gas Atomized Al-Ni Alloy Powders, Electrochim. Acta, 2012, 69, p 371–378.CrossRef

42.

I.B. Singh, D.P. Mandal, M. Singh and S. Das, Influence of SiC Particles Addition on the Corrosion Behavior of 2014 Al-Cu Alloy in 3.5% NaCl Solution, Corros. Sci., 2009, 51, p 234–241.CrossRef

43.

J. He, J. Wen and X. Li, Effects of Precipitates on the Electrochemical Performance of Al Sacrificial Anode, Corros. Sci., 2011, 53, p 1948–1953.CrossRef

44.

R.M. Cornell and U. Schwertmann, The Iron Oxides, Structure, Properties, Occurrences and Uses, VCH, Weinheim, 1996.

45.

J. Alcantara, B. Chico, J. Simancas, I. Diaz, D. Fuente and M. Morcillo, An Attempt to Classify the Morphologies Presented by Different Rust Phases Formed During the Exposure of Carbon Steel to Marine Atmospheres, Mater. Charact., 2016, 118, p 65–78.CrossRef

46.

A. Raman and S. Nasrazadani, Morphology of Rust Phases Formed on Weathering Steels in Various Laboratory Corrosion Test, Metallography, 1989, 22, p 79–96.CrossRef

47.

T. Misawa, T. Kyuno, W. Suetaka and S. Shimodaira, The Mechanism of Atmospheric Rusting and the Effect of Cu and P on the Rust Formation of Low Alloy Steels, Corros. Sci., 1971, 11, p 35–48.CrossRef

48.

J. Dunnwald and A. Otto, An Investigation of Phase Transitions in Rust Layers Using Raman Spectroscopy, Corros. Sci., 1989, 29, p 1167–1176.CrossRef

49.

D. Neff, L.B. Gurlet, P. Dillmann, S. Reguer and L. Legrand, Raman Imaging of Ancient Rust Scales on Archaeological Iron Artefacts For Long-Term Atmospheric Corrosion Mechanisms Study, J. Raman Spectrosc., 2006, 37, p 1228–1237.CrossRef

50.

R.L. Frost, R. Scholz and A. Lopez, A Raman and Infrared Spectroscopic Study of the Phosphate Mineral Laueite, Vib. Spectrosc., 2016, 82, p 31–36.CrossRef

51.

T. Kamimura, S. Hara, H. Miyuki, M. Yamashita and H. Uchida, Composition and Protective Ability of Rust Layer Formed on Weathering Steel Exposed to Various Environments, Corros. Sci., 2006, 48, p 2799–2812.CrossRef

52.

Impressed current laboratory testing of aluminium and zinc alloy anodes, NACE TM0190, NACE International, Houston (2017), pp. 1–13

53.

A. Farooq, M. Hamza, Q. Ahmed and K.M. Deen, Evaluating the Performance of Zinc and Aluminium Sacrificial Anodes in Artificial Seawater, Electrochim. Acta, 2019, 314, p 135–141.CrossRef

54.

T. Misawa, K. Hashimoto and S. Shimodaira, The Mechanism of Formation Of iron Oxide and Oxyhydroxides in Aqueous Solutions at Room Temperature, Corros. Sci., 1974, 14, p 131–149.CrossRef

55.

S. Reguer, P. Dillmann and F. Mirambet, Buried Iron Archaeological Artefacts; Corrosion Mechanisms Related to the Presence of Cl Containing Phases, Corros. Sci., 2007, 49, p 2726–2744.CrossRef

56.

S. Choudhary, A. Garg and K. Mondal, Relation Between Open Circuit Potential and Polarization Resistance with Rust and Corrosion Monitoring of Mild Steel, J. Mater. Eng. Perform., 2016, 25, p 2969–2976.CrossRef

57.

H. Kihira, S. Ito and T. Murata, The Behavior of Phosphorus During Passivation of Weathering Steel by Protective Patina Formation, Corros. Sci., 1990, 31, p 383–388.CrossRef

58.

Cathodic Protection Technologist Course Manual, NACE international, Houston (2008)

59.

Cathodic Protection Design, DNV-RPB401, Det Norske Veritas (2010)

60.

R. Baboian, NACE Corrosion Engineers’s Reference Book, 3rd ed. NACE International, Houston, 2002.

61.

India-mart Home Page. https://dir.indiamart.com/impcat/cathodic-protection-anodes.html

Title: High Phosphorus Pig Iron as Sacrificial Anode in Seawater
Authors: Nisheeth Kr. Prasad
A. S. Pathak
S. Kundu
Pankaj Panchal
K. Mondal
Publication date: 09-11-2021
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 4/2022
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-021-06397-6

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