Skip to main content
Top

2021 | OriginalPaper | Chapter

Hybrid Nanocomposites Based on Graphene and Titanium Dioxide for Wastewater Treatment

Authors : Hanane Chakhtouna, Nadia Zari, Hanane Benzeid, Abou el kacem Qaiss, Rachid Bouhfid

Published in: Graphene and Nanoparticles Hybrid Nanocomposites

Publisher: Springer Singapore

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Since its discovery by Fujishima and Honda, titanium dioxide photocatalyst have been extensively used for environmental management and wastewater purification. TiO2 photocatalyst showed higher photocatalytic performances toward different organic pollutants, pharmaceutical compounds, and bacteria. However, it exhibited large band gap and can only be excited under UV-light irradiation, which presents only 5% of solar terrestrial radiation. In addition, to the fast electron–hole (e/h+) pair recombination that limits its photocatalytic activity. Therefore, the incorporation of graphene and its derivatives, known by their exceptional mix of chemical, physical, mechanical and electronic properties, is found advantageous to enhance electron mobility, suppress the recombination of e/h+ pairs and shift its visible light photocatalytic ability. This chapter aims to introduce TiO2/graphene hybrid nanocomposites from the fundamental component, synthesis methods, physico-chemical and electronic properties to their application as powerful materials in the wastewater treatment field.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Qu X, Alvarez PJJ, Li Q (2013) Applications of nanotechnology in water and wastewater treatment. Water Res 47(12):3931–3946CrossRef Qu X, Alvarez PJJ, Li Q (2013) Applications of nanotechnology in water and wastewater treatment. Water Res 47(12):3931–3946CrossRef
2.
go back to reference Gusain R, Kumar N, Sinha S (2020) Recent advances in carbon nanomaterial-based adsorbents for water purification. Coord Chem Rev 405:213111CrossRef Gusain R, Kumar N, Sinha S (2020) Recent advances in carbon nanomaterial-based adsorbents for water purification. Coord Chem Rev 405:213111CrossRef
3.
go back to reference Kausar A et al (2018) Dyes adsorption using clay and modi fi ed clay : a review. J Molec Liquids 256:395–407 Kausar A et al (2018) Dyes adsorption using clay and modi fi ed clay : a review. J Molec Liquids 256:395–407
4.
go back to reference Mahmoodi NM, Saffar-Dastgerdi MH (2019) Zeolite nanoparticle as a superior adsorbent with high capacity: synthesis, surface modification and pollutant adsorption ability from wastewater. Microchem J 145:74–83CrossRef Mahmoodi NM, Saffar-Dastgerdi MH (2019) Zeolite nanoparticle as a superior adsorbent with high capacity: synthesis, surface modification and pollutant adsorption ability from wastewater. Microchem J 145:74–83CrossRef
5.
go back to reference Hu LJWJS, Zhong LS, Song WG (2008) Synthesis of hierarchically structured metal oxides and their application in heavy metal ion removal. Adv Mater, 2977–2982 Hu LJWJS, Zhong LS, Song WG (2008) Synthesis of hierarchically structured metal oxides and their application in heavy metal ion removal. Adv Mater, 2977–2982
6.
go back to reference Abdeen Z, Mohammad SG (2014) Study of the adsorption efficiency of an eco-friendly carbohydrate polymer for contaminated aqueous solution by organophosphorus pesticide, vol 2014, pp 16–28 Abdeen Z, Mohammad SG (2014) Study of the adsorption efficiency of an eco-friendly carbohydrate polymer for contaminated aqueous solution by organophosphorus pesticide, vol 2014, pp 16–28
7.
go back to reference Mukhopadhyay G, Behera H (2010) Emerging two-dimensional materials : graphene and its other structural analogues, pp 1–12 Mukhopadhyay G, Behera H (2010) Emerging two-dimensional materials : graphene and its other structural analogues, pp 1–12
8.
go back to reference Charles G, Roques-carmes T, Becheikh N, Falk L, Commenge J, Corbel S (2011) Determination of kinetic constants of a photocatalytic reaction in micro-channel reactors in the presence of mass-transfer limitation and axial dispersion. J Photochem Photobiol Chem 223(2–3):202–211 Charles G, Roques-carmes T, Becheikh N, Falk L, Commenge J, Corbel S (2011) Determination of kinetic constants of a photocatalytic reaction in micro-channel reactors in the presence of mass-transfer limitation and axial dispersion. J Photochem Photobiol Chem 223(2–3):202–211
9.
go back to reference Lee S, Park S (2012) Comprehensive review on synthesis and adsorption behaviors of graphene-based materials 13(2):73–87 Lee S, Park S (2012) Comprehensive review on synthesis and adsorption behaviors of graphene-based materials 13(2):73–87
10.
go back to reference Systems N (2011) The sp2 nanocarbons : prototypes for nanoscience and nanotechnology, pp 3–16 Systems N (2011) The sp2 nanocarbons : prototypes for nanoscience and nanotechnology, pp 3–16
11.
go back to reference Yazdi GR, Iakimov T, Yakimova R (2016) Epitaxial graphene on SiC : a review of growth, no. 0001 Yazdi GR, Iakimov T, Yakimova R (2016) Epitaxial graphene on SiC : a review of growth, no. 0001
12.
go back to reference Properties E, View BS, Do TN (2017) Optical properties of graphene in magnetic and electric field, March 2016 Properties E, View BS, Do TN (2017) Optical properties of graphene in magnetic and electric field, March 2016
13.
go back to reference Shams SS (2015) Graphene synthesis : a review, May 2018 Shams SS (2015) Graphene synthesis : a review, May 2018
14.
go back to reference Choi W et al (2010) Synthesis of graphene and its applications : a review 8436 Choi W et al (2010) Synthesis of graphene and its applications : a review 8436
15.
go back to reference Khan ME, Khan MM, Cho MH (2018) Recent progress of metal–graphene nanostructures in photocatalysis Khan ME, Khan MM, Cho MH (2018) Recent progress of metal–graphene nanostructures in photocatalysis
16.
go back to reference Cao Y, Li X (2014) Adsorption of graphene for the removal of inorganic pollutants in water purification : a review, pp 713–727 Cao Y, Li X (2014) Adsorption of graphene for the removal of inorganic pollutants in water purification : a review, pp 713–727
17.
go back to reference Morales-torres S, Pastrana-martínez LM (2012) Design of graphene-based TiO2 photocatalysts—a review, pp 3676–3687 Morales-torres S, Pastrana-martínez LM (2012) Design of graphene-based TiO2 photocatalysts—a review, pp 3676–3687
18.
go back to reference Wu X, Hu J, Qi J, Hou Y, Wei X (2020) Graphene-supported ordered mesoporous composites used for environmental remediation : a review. Separation and Purification Technology, p 116511 Wu X, Hu J, Qi J, Hou Y, Wei X (2020) Graphene-supported ordered mesoporous composites used for environmental remediation : a review. Separation and Purification Technology, p 116511
19.
go back to reference Al-khateeb LA, Almotiry S, Abdel M (2014) Adsorption of pharmaceutical pollutants onto graphene nanoplatelets. Chem Eng J 248:191–199CrossRef Al-khateeb LA, Almotiry S, Abdel M (2014) Adsorption of pharmaceutical pollutants onto graphene nanoplatelets. Chem Eng J 248:191–199CrossRef
20.
go back to reference Chia C, Nur FR, Mohd SS, Sarani Z, Huang N, Lim H (2013) Methylene blue adsorption on graphene oxide. Sains Malaysiana 42:819–826 Chia C, Nur FR, Mohd SS, Sarani Z, Huang N, Lim H (2013) Methylene blue adsorption on graphene oxide. Sains Malaysiana 42:819–826
21.
go back to reference Jiang X, Liu L, Zeng Y, Xiao G, Hu F, Hu X, Wang X, Li H, Zhou T, Tan L (2016) Removal of 17β-estradiol by few-layered graphene oxide nanosheets from aqueous solutions: external influence and adsorption mechanism. Chem Eng J 284:93–102 Jiang X, Liu L, Zeng Y, Xiao G, Hu F, Hu X, Wang X, Li H, Zhou T, Tan L (2016) Removal of 17β-estradiol by few-layered graphene oxide nanosheets from aqueous solutions: external influence and adsorption mechanism. Chem Eng J 284:93–102
22.
go back to reference Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38CrossRef Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38CrossRef
23.
go back to reference Aravindan V, Lee Y, Yazami R (2015) TiO2 polymorphs in ‘ rocking-chair ’ Li-ion batteries. Biochem Pharmacol Aravindan V, Lee Y, Yazami R (2015) TiO2 polymorphs in ‘ rocking-chair ’ Li-ion batteries. Biochem Pharmacol
24.
go back to reference Bet-Moushoul E, Mansourpanah Y, Farhadi K, Tabatabaei M (2016) TiO2 nanocomposite based polymeric membranes: a review on performance improvement for various applications in chemical engineering processes, vol 283. Elsevier B.V Bet-Moushoul E, Mansourpanah Y, Farhadi K, Tabatabaei M (2016) TiO2 nanocomposite based polymeric membranes: a review on performance improvement for various applications in chemical engineering processes, vol 283. Elsevier B.V
25.
go back to reference Miszczak S, Pietrzyk B (2015) Anatase-rutile transformation of TiO2 sol-gel coatings deposited on different substrates. Ceram Int 41(6):7461–7465CrossRef Miszczak S, Pietrzyk B (2015) Anatase-rutile transformation of TiO2 sol-gel coatings deposited on different substrates. Ceram Int 41(6):7461–7465CrossRef
26.
go back to reference Wang C, Wang H, Chen Q, Ren B, Duan R, Guan R (2019) Synchronous regulation of morphology and crystal phase of TiO2 via a facile green hydrothermal approach and their photocatalytic activity. Mater Res Bull 109:90–97CrossRef Wang C, Wang H, Chen Q, Ren B, Duan R, Guan R (2019) Synchronous regulation of morphology and crystal phase of TiO2 via a facile green hydrothermal approach and their photocatalytic activity. Mater Res Bull 109:90–97CrossRef
27.
go back to reference Mamaghani AH, Haghighat F, Lee C (2018) Hydrothermal/Solvothermal synthesis and treatment of TiO2 for photocatalytic degradation of air pollutants: Preparation, characterization, properties, and performance. Chemosphere Mamaghani AH, Haghighat F, Lee C (2018) Hydrothermal/Solvothermal synthesis and treatment of TiO2 for photocatalytic degradation of air pollutants: Preparation, characterization, properties, and performance. Chemosphere
28.
go back to reference Behzadnia A, Montazer M, Rashidi A, Rad MM (2014) Sonosynthesis of nano TiO 2 on wool using titanium isopropoxide or butoxide in acidic media producing multifunctional fabric. Ultrasonics Sonochemistry Behzadnia A, Montazer M, Rashidi A, Rad MM (2014) Sonosynthesis of nano TiO 2 on wool using titanium isopropoxide or butoxide in acidic media producing multifunctional fabric. Ultrasonics Sonochemistry
29.
go back to reference Nakata K, Fujishima A (2012) TiO2 photocatalysis: design and applications. J Photochem Photobiol, C 13:169–189CrossRef Nakata K, Fujishima A (2012) TiO2 photocatalysis: design and applications. J Photochem Photobiol, C 13:169–189CrossRef
30.
go back to reference Sohrabi MR, Ghavami M (2008) Photocatalytic degradation of direct red 23 dye using UV/TiO2 : effect of operational parameters 153:1235–1239 Sohrabi MR, Ghavami M (2008) Photocatalytic degradation of direct red 23 dye using UV/TiO2 : effect of operational parameters 153:1235–1239
31.
go back to reference Lachheb H et al (2002) Photocatalytic degradation of various types of dyes ( Alizarin S , Crocein Orange G , Methyl Red , Congo Red , Methylene Blue ) in water by UV-irradiated titania, vol 39, pp 75–90 Lachheb H et al (2002) Photocatalytic degradation of various types of dyes ( Alizarin S , Crocein Orange G , Methyl Red , Congo Red , Methylene Blue ) in water by UV-irradiated titania, vol 39, pp 75–90
32.
go back to reference Photosemiconductor TU (1988) Continuous-sterilization system that uses photosemiconductor powders, 54(6):1330–1333 Photosemiconductor TU (1988) Continuous-sterilization system that uses photosemiconductor powders, 54(6):1330–1333
33.
go back to reference Zeng Lu XEW, Fang Zhou H, Liao JJ, Yang YY, Wang K, Ming Che L, He N, Dong Chen X, Song R, Fang Cai W, Liu H (2019) A facile dopamine-assisted method for the preparation of antibacterial surfaces based on Ag/TiO2 nanopartilces. Appl Surf Sci 481:1270–1276 Zeng Lu XEW, Fang Zhou H, Liao JJ, Yang YY, Wang K, Ming Che L, He N, Dong Chen X, Song R, Fang Cai W, Liu H (2019) A facile dopamine-assisted method for the preparation of antibacterial surfaces based on Ag/TiO2 nanopartilces. Appl Surf Sci 481:1270–1276
34.
go back to reference Zhang H, Lv X, Li Y, Wang Y, Li J (2009) P25-graphene composite as a high performance photocatalyst. Am Chem Soc 4(1) Zhang H, Lv X, Li Y, Wang Y, Li J (2009) P25-graphene composite as a high performance photocatalyst. Am Chem Soc 4(1)
35.
go back to reference Decontamination W (2018) Dioxide/graphene oxide nanocomposites: synthesis, water decontamination Decontamination W (2018) Dioxide/graphene oxide nanocomposites: synthesis, water decontamination
36.
go back to reference Tang B, Chen H, Peng H, Wang Z, Huang W (2018) Graphene modified TiO2 composite photocatalysts: mechanism, progress and perspective, pp 27–30 Tang B, Chen H, Peng H, Wang Z, Huang W (2018) Graphene modified TiO2 composite photocatalysts: mechanism, progress and perspective, pp 27–30
37.
go back to reference Nguyen CH, Juang R (2019) Efficient removal of methylene blue dye by a hybrid adsorption–photocatalysis process using reduced graphene oxide/titanate nanotube composites for water reuse. J Indus Eng Chem Nguyen CH, Juang R (2019) Efficient removal of methylene blue dye by a hybrid adsorption–photocatalysis process using reduced graphene oxide/titanate nanotube composites for water reuse. J Indus Eng Chem
38.
go back to reference Yue HY, Guan H, Gao X, Yao F, Wang Q, Zhang T (2018) Hydrothermal synthesis of TiO2 nanowires-reduced graphene oxide nanocomposite to enhance electrochemical performance in supercapacitor, pp 12455–12460 Yue HY, Guan H, Gao X, Yao F, Wang Q, Zhang T (2018) Hydrothermal synthesis of TiO2 nanowires-reduced graphene oxide nanocomposite to enhance electrochemical performance in supercapacitor, pp 12455–12460
39.
go back to reference Awang H, Talalah NI (2019) Synthesis of reduced graphene oxide-titanium (rGO-TiO2) composite using a solvothermal and hydrothermal methods and characterized via XRD and UV-Vis, pp 17–28 Awang H, Talalah NI (2019) Synthesis of reduced graphene oxide-titanium (rGO-TiO2) composite using a solvothermal and hydrothermal methods and characterized via XRD and UV-Vis, pp 17–28
40.
go back to reference Yadav HM, Kim J (2016) Solvothermal synthesis of anatase TiO2-graphene oxide nanocomposites and their photocatalytic performance. J Alloys Compounds Yadav HM, Kim J (2016) Solvothermal synthesis of anatase TiO2-graphene oxide nanocomposites and their photocatalytic performance. J Alloys Compounds
41.
go back to reference Zhang L, Xi Z, Xing M, Zhang J (2013) Effects of the preparation order of the ternary P25/GO/Pt hybrid photocatalysts on hydrogen production. Int J Hydrogen Energy pp 1–9 Zhang L, Xi Z, Xing M, Zhang J (2013) Effects of the preparation order of the ternary P25/GO/Pt hybrid photocatalysts on hydrogen production. Int J Hydrogen Energy pp 1–9
42.
go back to reference Li Y et al (2016) Removal of Cr(VI) by 3D TiO2-graphene hydrogel via adsorption enriched with photocatalytic reduction. Appl Catal B 199:412–423CrossRef Li Y et al (2016) Removal of Cr(VI) by 3D TiO2-graphene hydrogel via adsorption enriched with photocatalytic reduction. Appl Catal B 199:412–423CrossRef
43.
go back to reference Zhen M, Liu L, Yuan Z (2016) Facile preparation and lithium storage properties of TiO2@graphene composite electrodes with low carbon content. Chem Eur J 22:11943–11948CrossRef Zhen M, Liu L, Yuan Z (2016) Facile preparation and lithium storage properties of TiO2@graphene composite electrodes with low carbon content. Chem Eur J 22:11943–11948CrossRef
44.
go back to reference Giovannetti R (2017) Recent advances in graphene based TIO2 Giovannetti R (2017) Recent advances in graphene based TIO2
45.
go back to reference Hicham Atouta FM, Álvarezb MG, Cheblia D, Bouguettouchaa A, Tichitc D, Llorcad J (2017) Enhanced photocatalytic degradation of methylene blue: preparation of TiO2/reduced graphene oxide nanocomposites by direct sol-gel and hydrothermal methods. Mater Res Bull 95:578–587 Hicham Atouta FM, Álvarezb MG, Cheblia D, Bouguettouchaa A, Tichitc D, Llorcad J (2017) Enhanced photocatalytic degradation of methylene blue: preparation of TiO2/reduced graphene oxide nanocomposites by direct sol-gel and hydrothermal methods. Mater Res Bull 95:578–587
46.
go back to reference Li W et al (2013) Sol−gel design strategy for ultradispersed TiO2 nanoparticles on graphene for high-performance lithium ion batteries. J Am Chem Soc, pp 0–3 Li W et al (2013) Sol−gel design strategy for ultradispersed TiO2 nanoparticles on graphene for high-performance lithium ion batteries. J Am Chem Soc, pp 0–3
47.
go back to reference Zhou K, Zhu Y, Yang X, Jiang X, Li C (2011) Preparation of graphene—TiO2 composites with enhanced photocatalytic activity. New J Chem, pp 353–359 Zhou K, Zhu Y, Yang X, Jiang X, Li C (2011) Preparation of graphene—TiO2 composites with enhanced photocatalytic activity. New J Chem, pp 353–359
48.
go back to reference Liu J, Wang L, Tang J, Ma J (2016) Photocatalytic degradation of commercially sourced naphthenic acids by TiO2-graphene composite nanomaterial. Chemosphere 149:328–335CrossRef Liu J, Wang L, Tang J, Ma J (2016) Photocatalytic degradation of commercially sourced naphthenic acids by TiO2-graphene composite nanomaterial. Chemosphere 149:328–335CrossRef
49.
go back to reference Kan Z, Park JH (2012) Green synthesis of biphasic TiO2-reduced graphene oxide nanocomposites with highly enhanced photocatalytic activity Kan Z, Park JH (2012) Green synthesis of biphasic TiO2-reduced graphene oxide nanocomposites with highly enhanced photocatalytic activity
50.
go back to reference Gayathri S, Kottaisamy M, Ramakrishnan V (2018) Facile microwave-assisted synthesis of titanium dioxide decorated graphene nanocomposite for photodegradation of organic dyes, vol 127219, no. 2015 Gayathri S, Kottaisamy M, Ramakrishnan V (2018) Facile microwave-assisted synthesis of titanium dioxide decorated graphene nanocomposite for photodegradation of organic dyes, vol 127219, no. 2015
51.
go back to reference Bhanvase BA, Shende TP, Sonawane SH (2017) A review on graphene—TiO2 and doped graphene—TiO2 nanocomposite photocatalyst for water and wastewater treatment, 2515, no. December 2016 Bhanvase BA, Shende TP, Sonawane SH (2017) A review on graphene—TiO2 and doped graphene—TiO2 nanocomposite photocatalyst for water and wastewater treatment, 2515, no. December 2016
52.
go back to reference Noreen Z, Khalid NR, Abbasi R, Javed S, Ahmad I, Bokhari H (2019) Materials science & engineering C visible light sensitive Ag/TiO2/graphene composite as a potential coating material for control of Campylobacter jejuni. Mater Sci Eng C 98:125–133 Noreen Z, Khalid NR, Abbasi R, Javed S, Ahmad I, Bokhari H (2019) Materials science & engineering C visible light sensitive Ag/TiO2/graphene composite as a potential coating material for control of Campylobacter jejuni. Mater Sci Eng C 98:125–133
Metadata
Title
Hybrid Nanocomposites Based on Graphene and Titanium Dioxide for Wastewater Treatment
Authors
Hanane Chakhtouna
Nadia Zari
Hanane Benzeid
Abou el kacem Qaiss
Rachid Bouhfid
Copyright Year
2021
Publisher
Springer Singapore
DOI
https://doi.org/10.1007/978-981-33-4988-9_8

Premium Partners