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Published in: Cellulose 9/2018

02-07-2018 | Original Paper

In situ controllable synthesis of Ag@AgCl in cellulose film and its effect on anti-fouling properties

Authors: You Shu, Jin Lv, Xia Peng, Xiaomin Zhang, Shengpei Su, Jin Zhu

Published in: Cellulose | Issue 9/2018

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Abstract

Cellulose–Ag@AgCl composite films were fabricated by one-step coagulation of the cellulose/1-Butyl-3-methylimidazolium chloride (BmimCl)solution with AgNO3. AgCl was firstly formed when AgNO3 was added into cellulose/BmimCl solution, and then the formed AgCl was further reacted with excess Cl, leading to the complete dissolution of AgCl. The AgCl crystal would grow again from cellulose matrix in the air after the film formation. Meanwhile, AgCl could be partly decomposed into Ag° and formed Ag@AgCl under visible-light irradiation. The morphology of Ag@AgCl in cellulose matrix could be regulated by changing the molar ratio of BmimCl and AgNO3, the growth time of AgCl crystal and the concentration of cellulose solution. The cellulose composite film with stamen-like Ag@AgCl showed the best anti-fouling properties for methyl orange reagent under visible-light irradiation. This work also provided a simple pathway to regulate the morphology of Ag@AgCl in cellulose or other polymer matrices.

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Metadata
Title
In situ controllable synthesis of Ag@AgCl in cellulose film and its effect on anti-fouling properties
Authors
You Shu
Jin Lv
Xia Peng
Xiaomin Zhang
Shengpei Su
Jin Zhu
Publication date
02-07-2018
Publisher
Springer Netherlands
Published in
Cellulose / Issue 9/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-018-1919-8

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