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Journal of Materials Science: Materials in Electronics
Published in:

20-07-2016

In situ synthesis of biocarbon coated Li3V2(PO4)3 cathode material using lotus leaf as carbon source

Authors: Yaoyao Wang, Xudong Zhang, Wen He, Chuanliang Wei, Qiaohuan Cheng, Changgang Li

Published in: Journal of Materials Science: Materials in Electronics | Issue 12/2016

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Abstract

Biocarbon coated Li3V2(PO4)3 cathode material was fabricated using lotus leaf as carbon source by sol gel method. Through the electrostatic interaction between cations and the hydrophilic groups on the surface of the lotus leaf powder, the self-assembling of Li+, VO2+ and V3+ cations was carried out on the surface of lotus leaf powder. The as prepared Li3V2(PO4)3 particles were coated with a carbon layer (about 5 nm). The lithium ion diffusion coefficient of Li3V2(PO4)3 was improved by carbon layer greatly. Compared with pure Li3V2(PO4)3, the Li3V2(PO4)3/C composite delivered a high initial discharge capacity of 130.4 mAh g−1 under the current rate of 0.1 C, and showed a high and stable cycling performance under the current rate of 10 C. The coulombic efficiency very close to 99 %. The initial discharge capacity is 107.3 mAh g−1 at 10 C. Even at the 200th cycle, it can still deliver a discharge capacity of 106. 7 mAh g−1.
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Metadata
Title
In situ synthesis of biocarbon coated Li3V2(PO4)3 cathode material using lotus leaf as carbon source
Authors
Yaoyao Wang
Xudong Zhang
Wen He
Chuanliang Wei
Qiaohuan Cheng
Changgang Li
Publication date
20-07-2016
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 12/2016
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-016-5393-5

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