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Introduction to Electrodeposition: Basic Terms and Fundamental Concepts Read chapter Read first chapter

2011 | OriginalPaper | Chapter

4. Influence of Diffusion on the Rate of Electrochemical Process

Authors : Dr. Yuliy D. Gamburg, Dr. Giovanni Zangari

Published in: Theory and Practice of Metal Electrodeposition

Publisher: Springer New York

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Abstract

The concentration of electroactive ions c i which determines the overall kinetics of the electrode process differs in general from the bulk ion concentration. This is a consequence of the location of ion discharge, which is at a potential ψ′, different from the bulk solution potential, as it have been noted earlier. Additionally, at high overpotentials, the rate of discharge is very fast and ion reduction is limited by the rate of transport to the electrode surface. The steady state rate of the electrochemical process is in this case exactly equal to the rate of transport of the electroactive species from the bulk.

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previous chapter Electrochemical Thermodynamics and Electrochemical Kinetics
next chapter Thermodynamics and Kinetics of Nucleation
Literature
1.
Levich V.G. Physico-chemical hydrodynamics. Moscow, 1952
2.
Gamburg Yu. D. Russian J. Electrochemistry, 2002, v. 38, p. 1273
3.
Engelgardt G.R., Davydov A.D., Soviet J. of Electrochemistry, 1988, v. 24, p.538.
4.
Levich V.G. Acta Physicochim. URSS, 1942, v.17, p. 257
5.
Gregory D.P., Riddiford A.C., J. Chem. Soc., 1956, p. 3756
6.
Frumkin A.N., Tedoradse G.A. , Zeitschrift fuer Elektrochemie,1958, Bd. 62, s. 251
7.
Beck R.Yu. , Lavrova T.A. Trans. Of the Siberian Branch Acad. Sci. USSR, chem.. series, 1971, v. 14, no. 7, p. 1429 (in Russian)
Metadata
Title
Influence of Diffusion diffusion on the Rate of Electrochemical Process
Authors
Dr. Yuliy D. Gamburg
Dr. Giovanni Zangari
Copyright Year
2011
Publisher
Springer New York
Book
Theory and Practice of Metal Electrodeposition

Print ISBN: 978-1-4419-9668-8

Electronic ISBN: 978-1-4419-9669-5

Copyright Year: 2011

DOI
https://doi.org/10.1007/978-1-4419-9669-5_4

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