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Journal of Materials Science
Published in: Journal of Materials Science 18/2018

11-06-2018 | Ceramics

Influence of galia (Ga2O3) addition on the phase transformations and crystal growth behavior of zirconia (ZrO2)

Authors: Chen Barad, Giora Kimmel, Hagay Hayun, Dror Shamir, Michael Shandalov, Gal Shekel, Yaniv Gelbstein

Published in: Journal of Materials Science | Issue 18/2018

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Abstract

The effect of a galia (Ga2O3) addition on the crystallographic phase evolution and the crystal growth behavior of zirconia (ZrO2) rich powder were investigated. Binary compositions of galia–zirconia powder (on the zirconia-rich side of the quasi-binary phase diagram) were obtained by the sol–gel method and calcined at different temperatures for 2 h. Rietveld refinement (FullProf program) was used to determine the crystallographic phase composition. Crystal size was approximated based on X-ray diffractions analysis combined with estimates of average crystal size obtained by processing high-resolution scanning electron microscopy images. The surface area of the powders obtained was measured via the Brunauer–Emmett–Teller method. Zirconia–galia sol–gel powders were found to form tetragonal or mixed tetragonal–monoclinic solid solution phases depending on both composition and calcination temperature. It was shown that galia suppressed crystal growth process in zirconia, producing finer nano-powders with higher surface area compared to pure zirconia.
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Literature
1.
2.
Stambouli AB, Traversa E (2002) Solid oxide fuel cells (SOFCs): a review of an environmentally clean and efficient source of energy. Renew Sustain Energy Rev 6:433–455CrossRef
3.
Manicone PF, Iommetti PR, Raffaelli L (2007) An overview of zirconia ceramics: basic properties and clinical applications. J Dent 35:819–826CrossRef
4.
Yamaguchi T (1994) Application of ZrO2 as a catalyst and a catalyst support. Catal Today 20:199–217CrossRef
5.
Viazzi C, Bonino J, Ansart F et al (2008) Structural study of metastable tetragonal YSZ powders produced via a sol–gel route. J Alloys Compd 452:377–383CrossRef
6.
Stepanov S, Nikolaev V, Bougrov V et al (2016) Gallium oxide: properties and applica a review. Rev Adv Mater Sci 44:63–86
7.
Binet L, Gourier D (1998) Origin of the blue luminescence of β-Ga2O3. J Phys Chem Solids 59:1241–1249CrossRef
8.
Pushkar YN, Parenago O, Fionov A et al (1999) Paramagnetic complexes of the probe molecules with electron accepting sites on the surface of M2O3–ZrO 2:(M = Al, Ga). Colloids Surf Physicochem Eng Asp 158:179–187CrossRef
9.
Štefanić G, Musić S (2008) Thermal behavior of the amorphous precursors of the ZrO2–GaO 1.5 system. J Alloys Compd 460:444–452CrossRef
10.
Barret P, Berthet P (1997) EXAFS study of nanocrystalline solid solutions synthesized in the ZrO2–Ga2O3, System. J Phys IV 7:483–490
11.
Barret P, Berthet P (1997) Preparation and characterization of nanocrystalline ZrO2–Ga2O3 solid solutions. J Phys III 7:C2-1141–C2-1142
12.
Kimmel G, Zabicky J, Goncharov E et al (2004) Phase mapping of multi-component oxides derived from sol–gel precursors. J Metastab Nanocryst Mater 20:576–581
13.
Kimmel G, Zabicky J (2008) Stability, instability, metastability and grain size in nanocrystalline ceramic oxide systems. Solid State Phenom 140:29–36CrossRef
14.
Tekeli S, Erdogan M, Aktas B (2004) Influence of α-Al2O3 addition on sintering and grain growth behaviour of 8 mol% Y2O3-stabilised cubic zirconia (c-ZrO2). Ceram Int 30:2203–2209CrossRef
15.
Yoshida H, Miura K, Fujita J et al (1999) Effect of gallia addition on the sintering behavior of samaria-doped ceria. J Am Ceram Soc 82:219–221CrossRef
16.
Seo S, Park J, Park M et al (2014) Effects of gallia addition on sintering behavior and electrical conductivity of yttria-doped ceria. Electron Mater Lett 10:791–794CrossRef
17.
Alexander KB, Becher PF, Waters SB et al (1994) Grain growth kinetics in alumina–zirconia (CeZTA) composites. J Am Ceram Soc 77:939–946CrossRef
18.
De Aza A, Chevalier J, Fantozzi G et al (2002) Crack growth resistance of alumina, zirconia and zirconia toughened alumina ceramics for joint prostheses. Biomaterials 23:937–945CrossRef
19.
Jayaseelan DD, Rani DA, Nishikawa T et al (2000) Powder characteristics, sintering behavior and microstructure of sol–gel derived ZTA composites. J Eur Ceram Soc 20:267–275CrossRef
20.
Sarkar D, Mohapatra D, Ray S et al (2007) Synthesis and characterization of sol–gel derived ZrO2 doped Al2O3 nanopowder. Ceram Int 33:255–261CrossRef
21.
Haneda M, Kintaichi Y, Shimada H et al (1998) Ga2O3/Al2O3 prepared by sol-gel method as a highly active metal oxide-based catalyst for NO reduction by propene in the presence of oxygen, H2O and SO2. Chem Lett 27
22.
Kuo C, Lee Y, Hung I et al (2008) Crystallization kinetics and growth mechanism of 8 mol% yttria-stabilized zirconia (8YSZ) nano-powders prepared by a sol–gel process. J Alloys Compd 453:470–475CrossRef
23.
24.
Taş AC, Majewski PJ, Aldinger F (2002) Synthesis of gallium oxide hydroxide crystals in aqueous solutions with or without urea and their calcination behavior. J Am Ceram Soc 85:1421–1429CrossRef
Metadata
Title
Influence of galia (Ga2O3) addition on the phase transformations and crystal growth behavior of zirconia (ZrO2)
Authors
Chen Barad
Giora Kimmel
Hagay Hayun
Dror Shamir
Michael Shandalov
Gal Shekel
Yaniv Gelbstein
Publication date
11-06-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 18/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2556-1

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