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Journal of Polymer Research

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01-12-2015 | Original Paper

Influences for preparation of PMMA-b-PtBA block copolymer mediated by DPE-containing macroinitiator

Authors: Minjian Zhao, Zhifeng Fu, Yan Shi, Wantai Yang

Published in: Journal of Polymer Research | Issue 12/2015

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Abstract

Poly(methyl methacrylate)-b-poly(tert-butyl acrylate) (PMMA-b-PtBA) block copolymers were prepared based on the new mechanism of 1,1-diphenylethylene (DPE) controlled radical polymerization in homogeneous systems. Firstly, monomer methyl methacrylate (MMA), initiator 2,2-azobisisoheptonitrile (ABVN) and a control agent DPE were solution polymerized to form DPE-containing PMMA precursor. Then the second monomer tert-butyl acrylate (tBA) was simply heated in the presence of DPE-containing PMMA precursor used as macroinitiator, and block copolymers were synthesized successfully. The effects of polymerization temperature and solvent on molecular weight and molecular weight distribution of polymers throughout the polymerization were investigated. DPE-containing poly(styrene) precursor could not induce block polymerization.

next article Ultra-rapid polyamidation reaction of optically active aromatic diacid containing methionine moieties with aromatic diamines under microwave irradiation

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Li Y, Zhang Y, Yang D, Feng C, Zhai S, Hu J, Lu G, Huang X (2009) J Polym Sci A Polym Chem 47:6032–6043CrossRef

Petruczok CD, Barlow RF, Shipp DA (2008) J Polym Sci A Polym Chem 46:7200–7206CrossRef

Ma JY, Zhang HX (2014) J Polym Res 21(11):590CrossRef

Venkataraman S, Wooley KL (2007) J Polym Sci A Polym Chem 45:5420–5430CrossRef

Sanal T, Oruc O, Ozturk T, et al. (2015) J Polym Res 22(2):3CrossRef

Abu-Surrah A, Ibrahim KA, Abdalla MY, et al. (2011) J Polym Res 18(1):59–66CrossRef

Zhao QL, Liu EH, Wang GX, et al. (2014) J Polym Res 21(5):444CrossRef

Sundaram HS, Raghavachari D (2012) J Polym Sci A Polym Chem 50:996–1007CrossRef

Shen Z, Chen Y, Barriau E, Frey H (2006) Macromol Chem Phys 207:57–64CrossRef

10.

Semsarzadeh MA, Amiri S (2013) J Polym Res 20(5):139CrossRef

11.

Peng LJ, Liu T, Liu SX, et al. (2015) J Polym Res 22(7):126CrossRef

12.

Miura Y, Narumi A, Matsuya S, Satoh T, Duan Q, Kaga H, Kakuchi T (2005) J Polym Sci A Polym Chem 43:4271–4279CrossRef

13.

Xu YY, Shi XH, Qiu YG, et al. (2013) J Polym Res 20(12):325CrossRef

14.

Lessard B, Tervo C, Maric M (2009) Macromol React Eng 3:245–256CrossRef

15.

Gromadzki D, Makuska R, Netopilik M, Holler P, Lokaj J, Janata M, Stepanek P (2008) Eur Polym J 44:59–71CrossRef

16.

Wieland PC, Raether B, Nuyken O (2001) Macromol Rapid Commun 22:700–703CrossRef

17.

Wang WW, Liu MJ, Gu JW, et al. (2014) J Polym Res 21(8):502CrossRef

18.

Guo FG, Zhang QY, Zhang HP, et al. (2011) J Polym Res 18(4):745–751CrossRef

19.

Raether B, Nuyken O, Wieland P, Bremser W (2002) Macromol Symp 177:25–41CrossRef

20.

Luo YD, Chou IC, Chiu WY, Lee CF (2009) J Polym Sci A Polym Chem 47:4435–4445CrossRef

21.

Viala S, Tauer K, Antonietti M, Lacik I, Bremser W (2005) Polymer 46:7843–7854CrossRef

22.

Chen D, Fu ZF, Shi Y (2008) Polym Bull 60:259–269CrossRef

23.

Zhao M, Chen D, Shi Y, Yang W, Fu Z (2013) Macromol Chem Phys 214:1688–1698CrossRef

24.

Zhao M, Shi Y, Fu Z, Yang W (2014) Macromol React Eng 8:555–563CrossRef

25.

Allen CFH, Converse S (1926) DOI: 10.15227/orgsyn.006.0032. Org Synth 6:32CrossRef

26.

Otsu T, Tazaki T (1986) Polym Bull 16:277–284CrossRef

27.

Otsu T, Matsumoto A, Tazaki T (1987) Polym Bull 17:323–330CrossRef

28.

Tazaki T, Otsu T (1987) Polym Bull 17:127–134CrossRef

29.

Otsu T (2000) J Polym Sci A Polym Chem 38:2121–2136CrossRef

Title: Influences for preparation of PMMA-b-PtBA block copolymer mediated by DPE-containing macroinitiator
Authors: Minjian Zhao
Zhifeng Fu
Yan Shi
Wantai Yang
Publication date: 01-12-2015
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 12/2015
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-015-0873-5

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