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Published in: Colloid and Polymer Science 10/2016

01-10-2016 | Original Contribution

Interactions between pluronic block polyether and CTAB at air/water interface: interfacial dilational rheology study

Authors: Houjian Gong, Long Xu, Teng Zhu, Guiying Xu, Xiaofeng Shi, Mingzhe Dong, Yajun Li

Published in: Colloid and Polymer Science | Issue 10/2016

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Abstract

The interactions between Pluronic block polyethers (L64 and 17R4) and cetyltrimethyl ammonium bromide (CTAB) were investigated by the measurement of the interfacial dilational viscoelasticity. The dilational moduli of the Pluronic block polyether/CTAB solutions firstly increased, passed through the maximum, and then decreased with the increasing concentration of CTAB. 17R4/CTAB mixed solutions have much larger dilational moduli than L64/CTAB systems, which means that 17R4 and CTAB have stronger interactions than L64 and CTAB. The dilational moduli of 17R4/CTAB systems were different from L64/CTAB systems in the presence of NaBr. The dilational moduli of the L64/CTAB mixed solutions decreased firstly, passed through the minimum value, and then increased with the increasing concentration of NaBr, while the dilational moduli of 17R4/CTAB mixed solutions increased firstly, passed through the maximum, and then decreased. These differences show that NaBr has great influence on the interactions between Pluronic block polyethers and CTAB.

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Metadata
Title
Interactions between pluronic block polyether and CTAB at air/water interface: interfacial dilational rheology study
Authors
Houjian Gong
Long Xu
Teng Zhu
Guiying Xu
Xiaofeng Shi
Mingzhe Dong
Yajun Li
Publication date
01-10-2016
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 10/2016
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-016-3919-2

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