Skip to main content
Top
Published in: Journal of Materials Science: Materials in Electronics 11/2019

20-04-2019

Investigation of structural, optical, electrochemical and dielectric properties of SnO2/GO nanocomposite

Authors: Sardarali Khan, Zulfiqar, Tahirzeb Khan, Rajwali Khan, Majid Khan, Shaukat Ali khattak, Gulzar khan

Published in: Journal of Materials Science: Materials in Electronics | Issue 11/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

We report the synthesis of tin dioxide/graphene oxide (SnO2/GO) nanocomposite through simple hydrothermal method. X-ray diffraction (XRD) and transmission electron microscopy (TEM) confirm the rutile tetragonal structure of the nanocomposite with average particle size of 13.37 ± 3.57 nm. The presence of only Sn, O and C in the EDX spectrum confirms the purity of our sample and a large defect density in the composite is found. The 3.7 eV band gap energy, determined by ultra-violet (UV) and photoluminescence (PL), of the nanocomposite is compatible with that of SnO2. Electrochemical measurements have shown that the material has a nice reversible redox process, suggesting its good capacitive behavior as well as a very low internal and charge transfer resistances of 1.43 Ω and 2.12 Ω, respectively. An increase in dielectric constant is observed, which is attributed to small grain size and high defect density. Conduction takes place through hopping process and the rapid increase in conductivity at high frequencies is due to increase in charge density (detached charges from traps + conduction electrons).

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference C. Zhao, X. Wang, J. Kong, J.M. Ang, P.S. Lee, X. Lu, C. Zhao, Liu, Self-Assembly-Induced Alternately Stacked Single-Layer MoS2 and N-doped Graphene: a novel van der Waals heterostructure for lithium-ion batteries. ACS Appl. Mater. Interfaces. 8, 2372 (2016)CrossRef C. Zhao, X. Wang, J. Kong, J.M. Ang, P.S. Lee, X. Lu, C. Zhao, Liu, Self-Assembly-Induced Alternately Stacked Single-Layer MoS2 and N-doped Graphene: a novel van der Waals heterostructure for lithium-ion batteries. ACS Appl. Mater. Interfaces. 8, 2372 (2016)CrossRef
2.
go back to reference M. Wang, H. Zhang, C. Wang, X. Hu, G. Wang, Direct electro synthesis of poly-o-phenylenediamine bulk materials for supercapacitor application. Electrochem. Acta. 91, 144 (2013)CrossRef M. Wang, H. Zhang, C. Wang, X. Hu, G. Wang, Direct electro synthesis of poly-o-phenylenediamine bulk materials for supercapacitor application. Electrochem. Acta. 91, 144 (2013)CrossRef
3.
go back to reference J. Zhang, J. Zhao, L. Yue, Q. Wang, J. Chai, Z. Liu, X. Zhou, H. Li, Y. Guo, G. Cui, L. Chen, High performance solid polymer electrolytes for rechargeable batteries a self-catalyzed strategy toward facile synthesis. Adv. Energy Mater. 5, 150–1082 (2015) J. Zhang, J. Zhao, L. Yue, Q. Wang, J. Chai, Z. Liu, X. Zhou, H. Li, Y. Guo, G. Cui, L. Chen, High performance solid polymer electrolytes for rechargeable batteries a self-catalyzed strategy toward facile synthesis. Adv. Energy Mater. 5, 150–1082 (2015)
4.
go back to reference Y. Zhang, Q. Ji, G.F. Han, J. Ju, J. Shi, D. Ma, J. Sun, Y. Zhang, M. Li, X.Y. Lang, Y. Zhang, Z. Liu, Dendritic, transferable, strictly monolayer MoS2 flakes synthesized on SrTiO3 single crystals for efficient electro catalytic applications. ACS Nano 8, 8617 (2014)CrossRef Y. Zhang, Q. Ji, G.F. Han, J. Ju, J. Shi, D. Ma, J. Sun, Y. Zhang, M. Li, X.Y. Lang, Y. Zhang, Z. Liu, Dendritic, transferable, strictly monolayer MoS2 flakes synthesized on SrTiO3 single crystals for efficient electro catalytic applications. ACS Nano 8, 8617 (2014)CrossRef
5.
go back to reference C.M. Torres Jr., Y.W. Lan, C. Zeng, J.H. Chen, X. Kou, A. Navabi, J. Tang, M. Montazeri, J.R. Adleman, M.B. Lerner, Y.L. Zhong, L.J. Li, C.D. Chen, K.L. Wang, High-current gain two-dimensional MOS2-base hot-electron transistors. Nano Lett. 15, 7905 (2015)CrossRef C.M. Torres Jr., Y.W. Lan, C. Zeng, J.H. Chen, X. Kou, A. Navabi, J. Tang, M. Montazeri, J.R. Adleman, M.B. Lerner, Y.L. Zhong, L.J. Li, C.D. Chen, K.L. Wang, High-current gain two-dimensional MOS2-base hot-electron transistors. Nano Lett. 15, 7905 (2015)CrossRef
6.
go back to reference Y. Tan, R. He, C. Cheng, D. Wang, Y. Chen, F. Chen, Manageable N-doped graphene for high performance oxygen reduction reaction. Sci. Rep. 4, 7523 (2014)CrossRef Y. Tan, R. He, C. Cheng, D. Wang, Y. Chen, F. Chen, Manageable N-doped graphene for high performance oxygen reduction reaction. Sci. Rep. 4, 7523 (2014)CrossRef
7.
go back to reference X. Xiong, W. Luo, X. Hu, C. Chen, L. Qie, D. Hou, Y. Huang, Flexible membranes of MOS2/C nano fibers by electro spinning as binder-free anodes for high-performance sodium-ion batteries. Sci. Rep. 5, 9254 (2015)CrossRef X. Xiong, W. Luo, X. Hu, C. Chen, L. Qie, D. Hou, Y. Huang, Flexible membranes of MOS2/C nano fibers by electro spinning as binder-free anodes for high-performance sodium-ion batteries. Sci. Rep. 5, 9254 (2015)CrossRef
8.
go back to reference L.X. Alvarez, A.B. Sorokin, J. Organomet, Mild oxidation of ethane to acetic acid by H2O2 catalyzed by supported mu-nitride diiron phthalocyanines. Chem. 793, 139 (2015) L.X. Alvarez, A.B. Sorokin, J. Organomet, Mild oxidation of ethane to acetic acid by H2O2 catalyzed by supported mu-nitride diiron phthalocyanines. Chem. 793, 139 (2015)
9.
go back to reference V.S. Arutyunov, L.N. Strekova, A.V. Nikitin, Partial oxidation of light alkanes as a base of new generation of gas chemical processes. Eurasian Chem. Technol. J. 15, 265 (2013)CrossRef V.S. Arutyunov, L.N. Strekova, A.V. Nikitin, Partial oxidation of light alkanes as a base of new generation of gas chemical processes. Eurasian Chem. Technol. J. 15, 265 (2013)CrossRef
10.
go back to reference Z. Cong, O. Shoji, C. Kasai, N. Kawakami, H. Sugimoto, Y. Shiro, Y. Watanabe, Activation of wild-type cytochrome P450BM3 by the Next generation of decoy molecules: enhanced hydroxylation of gaseous alkanes and crystallographic evidence. ACS Catal. 5, 150 (2015)CrossRef Z. Cong, O. Shoji, C. Kasai, N. Kawakami, H. Sugimoto, Y. Shiro, Y. Watanabe, Activation of wild-type cytochrome P450BM3 by the Next generation of decoy molecules: enhanced hydroxylation of gaseous alkanes and crystallographic evidence. ACS Catal. 5, 150 (2015)CrossRef
11.
go back to reference Z. Wang, L. Ma, W. Chen, G. Huang, D. Chen, L. Wang, J.Y. Lee, Facile synthesis of MoS2/graphene composites: effects of different cationic surfactants on microstructures and electrochemical properties of reversible lithium storage. RSC Adv. 3, 21675 (2013)CrossRef Z. Wang, L. Ma, W. Chen, G. Huang, D. Chen, L. Wang, J.Y. Lee, Facile synthesis of MoS2/graphene composites: effects of different cationic surfactants on microstructures and electrochemical properties of reversible lithium storage. RSC Adv. 3, 21675 (2013)CrossRef
12.
go back to reference Z. Guo, D. Zhou, X. Dong, Z. Qiu, Y. Wang, Y. Xia, Ordered hierarchical mesoporous/macro porous carbon: a high-performance catalyst for rechargeable Li–O2 batteries. Adv. Mater. 25, 5668 (2013)CrossRef Z. Guo, D. Zhou, X. Dong, Z. Qiu, Y. Wang, Y. Xia, Ordered hierarchical mesoporous/macro porous carbon: a high-performance catalyst for rechargeable Li–O2 batteries. Adv. Mater. 25, 5668 (2013)CrossRef
13.
go back to reference M. Zhang, Z. Huang, X. Wang, H. Zhang, T. Li, Z. Wu, Y. Luo, W. Cao, Magnetic MoS2 pizzas and sandwiches with Mnn (n = 1–4) cluster toppings and fillings: a first-principles investigation. Sci. Rep. 6, 19504 (2016)CrossRef M. Zhang, Z. Huang, X. Wang, H. Zhang, T. Li, Z. Wu, Y. Luo, W. Cao, Magnetic MoS2 pizzas and sandwiches with Mnn (n = 1–4) cluster toppings and fillings: a first-principles investigation. Sci. Rep. 6, 19504 (2016)CrossRef
14.
go back to reference J. Luxa, O. Jankovsky, D. Sedmidubsky, R. Medlin, M. Marysko, M. Pumera, Z. Sofer, Origin of exotic ferromagnetic behavior in exfoliated layered transition metal dichalcogenide MoS2 and WS2. Nanoscale 8, 1960 (2016)CrossRef J. Luxa, O. Jankovsky, D. Sedmidubsky, R. Medlin, M. Marysko, M. Pumera, Z. Sofer, Origin of exotic ferromagnetic behavior in exfoliated layered transition metal dichalcogenide MoS2 and WS2. Nanoscale 8, 1960 (2016)CrossRef
15.
go back to reference D. Cao, H.B. Shu, T.Q. Wu, Z.T. Jiang, Z.W. Jiao, M.Q. Cai, W.Y. Hu, First-principles study of the origin of magnetism induced by intrinsic defects in monolayer MoS2. Appl. Surf. Sci. 361, 199–205 (2016)CrossRef D. Cao, H.B. Shu, T.Q. Wu, Z.T. Jiang, Z.W. Jiao, M.Q. Cai, W.Y. Hu, First-principles study of the origin of magnetism induced by intrinsic defects in monolayer MoS2. Appl. Surf. Sci. 361, 199–205 (2016)CrossRef
16.
go back to reference D. Voiry et al., Conducting MoS2 nanosheets as catalysts for hydrogen evolution reaction. Nano Lett. 13, 6222–6227 (2013)CrossRef D. Voiry et al., Conducting MoS2 nanosheets as catalysts for hydrogen evolution reaction. Nano Lett. 13, 6222–6227 (2013)CrossRef
17.
go back to reference Rao, C. N., Gopalakrishnan, K. & Maitra, Comparative study of potential applications of graphene, MoS2, and other two dimensional materials in energy devices, sensors, and related areas. ACS Appl. Mater. Interfaces 7, 7809–7832 (2015) Rao, C. N., Gopalakrishnan, K. & Maitra, Comparative study of potential applications of graphene, MoS2, and other two dimensional materials in energy devices, sensors, and related areas. ACS Appl. Mater. Interfaces 7, 7809–7832 (2015)
18.
go back to reference G. Wang, L. Zhang, J. Zhang, A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 797–828 (2012)CrossRef G. Wang, L. Zhang, J. Zhang, A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 797–828 (2012)CrossRef
19.
go back to reference X. Wang et al., High supercapacitor and adsorption behaviors of flower-like MoS2 nanostructures. J. Mater. Chem. A 2, 15958–15963 (2014)CrossRef X. Wang et al., High supercapacitor and adsorption behaviors of flower-like MoS2 nanostructures. J. Mater. Chem. A 2, 15958–15963 (2014)CrossRef
20.
go back to reference D. Davies, A. Lipman, A.L. Silver, A.C.C. Tseung, On the effect of anode material in electrophoresis on the emission color of a zinc sulfide phosphor. Eletrochem. Solid State Lett. 4, 1–12 (2001)CrossRef D. Davies, A. Lipman, A.L. Silver, A.C.C. Tseung, On the effect of anode material in electrophoresis on the emission color of a zinc sulfide phosphor. Eletrochem. Solid State Lett. 4, 1–12 (2001)CrossRef
21.
go back to reference Zainab Iqbal Zulfiqar, Yuliang Yuan, Lu Jianguo, Structural, optical, dielectric and magnetic properties of Zn-doped SnO2 nanoparticles. Int. J. Modern Phys. B 31, 1750234 (2017)CrossRef Zainab Iqbal Zulfiqar, Yuliang Yuan, Lu Jianguo, Structural, optical, dielectric and magnetic properties of Zn-doped SnO2 nanoparticles. Int. J. Modern Phys. B 31, 1750234 (2017)CrossRef
22.
go back to reference J. Wang et al., Synthesis and characterization of nanosize cobalt sulfide for rechargeable lithium batteries. J. Power Sources 159, 287–290 (2006)CrossRef J. Wang et al., Synthesis and characterization of nanosize cobalt sulfide for rechargeable lithium batteries. J. Power Sources 159, 287–290 (2006)CrossRef
23.
go back to reference Q. Wang et al., Facile synthesis and superior supercapacitor performances of three-dimensional cobalt sulfide hierarchitectures. Cryst. Eng. Commun. 13, 59–60 (2011) Q. Wang et al., Facile synthesis and superior supercapacitor performances of three-dimensional cobalt sulfide hierarchitectures. Cryst. Eng. Commun. 13, 59–60 (2011)
24.
go back to reference Yuliang Yuan Zulfiqar, Qingjun Jiang, Jie Yang, Weicheng Wang LishaFeng, Zhizhen Ye, Lu Jianguo, Variation in luminescence and bandgap of Zn-doped SnO2 nanoparticles with thermal decomposition. J. Mater. Sci.: Mater. Electron. 27, 9541–9549 (2016) Yuliang Yuan Zulfiqar, Qingjun Jiang, Jie Yang, Weicheng Wang LishaFeng, Zhizhen Ye, Lu Jianguo, Variation in luminescence and bandgap of Zn-doped SnO2 nanoparticles with thermal decomposition. J. Mater. Sci.: Mater. Electron. 27, 9541–9549 (2016)
25.
go back to reference N. Kumar, N. Raman, A. Sundaresan, Synthesis and properties of cobalt sulfide phases: CoS2 and Co9S8. Zeitschrift für Anorg. Und Allg Chem. 640, 1069–1074 (2014)CrossRef N. Kumar, N. Raman, A. Sundaresan, Synthesis and properties of cobalt sulfide phases: CoS2 and Co9S8. Zeitschrift für Anorg. Und Allg Chem. 640, 1069–1074 (2014)CrossRef
26.
go back to reference Y. Sun et al., Electrodeposited cobalt-sulfide catalyst for electrochemical and photo electrochemical hydrogen generation from water. Nanoscale 10, 3–6 (2013) Y. Sun et al., Electrodeposited cobalt-sulfide catalyst for electrochemical and photo electrochemical hydrogen generation from water. Nanoscale 10, 3–6 (2013)
27.
go back to reference Yuliang Yuan Zulfiqar, Jie Yang, Weicheng Wang, Zhizhen Ye, Lu Jianguo, Structural and optical properties of (Zn, Co) co-doped SnO2 nanoparticles. Mater. Sci.: Mater. Electron. 27, 12119–12127 (2016) Yuliang Yuan Zulfiqar, Jie Yang, Weicheng Wang, Zhizhen Ye, Lu Jianguo, Structural and optical properties of (Zn, Co) co-doped SnO2 nanoparticles. Mater. Sci.: Mater. Electron. 27, 12119–12127 (2016)
28.
go back to reference Hongdong Liu, Jiamu Huang, Xinlu Li, Jia Liu, Yuxin Zhang, Du Kun, Flower-like SnO2/graphene composite for high-capacity lithium storage. Appl. Surf. Sci. 258, 4917–4921 (2012)CrossRef Hongdong Liu, Jiamu Huang, Xinlu Li, Jia Liu, Yuxin Zhang, Du Kun, Flower-like SnO2/graphene composite for high-capacity lithium storage. Appl. Surf. Sci. 258, 4917–4921 (2012)CrossRef
29.
go back to reference B. Qu et al., β-cobalt sulfide nanoparticles decorated graphene composite electrodes for high capacity and power supercapacitors. Nanoscale 4, 7806–7810 (2012) B. Qu et al., β-cobalt sulfide nanoparticles decorated graphene composite electrodes for high capacity and power supercapacitors. Nanoscale 4, 7806–7810 (2012)
30.
go back to reference H. Wan et al., Hydrothermal synthesis of cobalt sulfide nanotubes: the size control and its application in supercapacitors. J. Power Sources 243, 396–402 (2013)CrossRef H. Wan et al., Hydrothermal synthesis of cobalt sulfide nanotubes: the size control and its application in supercapacitors. J. Power Sources 243, 396–402 (2013)CrossRef
31.
go back to reference W. Dong et al., Hydrothermal synthesis and structure evolution of hierarchical cobalt sulfide nanostructures. Dalton Trans. 40, 243–248 (2011)CrossRef W. Dong et al., Hydrothermal synthesis and structure evolution of hierarchical cobalt sulfide nanostructures. Dalton Trans. 40, 243–248 (2011)CrossRef
32.
go back to reference W. Gapel, K.D. Schierbaum, Schierbaum SnO2 sensors: current status and future prospects. Sens. Actuators B 26–27, 1–12 (1995)CrossRef W. Gapel, K.D. Schierbaum, Schierbaum SnO2 sensors: current status and future prospects. Sens. Actuators B 26–27, 1–12 (1995)CrossRef
33.
go back to reference Yuliang Yuan Zulfiqar, Jie Yang, Weicheng Wang, Zhizhen Ye, Lu Jianguo, Structural, dielectric and ferromagnetic behavior of (Zn, Co) co-doped SnO2 nanoparticles. Ceram. Int. 42, 17128–17136 (2016)CrossRef Yuliang Yuan Zulfiqar, Jie Yang, Weicheng Wang, Zhizhen Ye, Lu Jianguo, Structural, dielectric and ferromagnetic behavior of (Zn, Co) co-doped SnO2 nanoparticles. Ceram. Int. 42, 17128–17136 (2016)CrossRef
34.
go back to reference H. Wang, J.T. Robinson, X. Li, H. Dai, Solvothermal reduction of chemically 793 exfoliated graphene sheets. J. Am. Chem. Soc. 131, 9910–9911 (2009)CrossRef H. Wang, J.T. Robinson, X. Li, H. Dai, Solvothermal reduction of chemically 793 exfoliated graphene sheets. J. Am. Chem. Soc. 131, 9910–9911 (2009)CrossRef
35.
go back to reference G. Huang, T. Chen, Z. Wang, K. Chang, W. Chen, Synthesis and electrochemical performances of cobalt sulfides/graphene nanocomposites as anode material of Li-ion battery. J. Power Sources 235, 122–128 (2013)CrossRef G. Huang, T. Chen, Z. Wang, K. Chang, W. Chen, Synthesis and electrochemical performances of cobalt sulfides/graphene nanocomposites as anode material of Li-ion battery. J. Power Sources 235, 122–128 (2013)CrossRef
36.
go back to reference Q. Guo, X. Qin, High capacity of SnO2 nanoparticles decorated graphene as an anode for lithium-ion batteries. ECS Solid State Lett. 2, 41–43 (2013)CrossRef Q. Guo, X. Qin, High capacity of SnO2 nanoparticles decorated graphene as an anode for lithium-ion batteries. ECS Solid State Lett. 2, 41–43 (2013)CrossRef
37.
go back to reference J. Wang, Y. Xu, X. Chen, X. Du, Electrochemical supercapacitor electrode material based on poly(3,4-ethylenedioxythiophene)/polypyrrole composite. J. Power Sources 163, 1120–1125 (2007)CrossRef J. Wang, Y. Xu, X. Chen, X. Du, Electrochemical supercapacitor electrode material based on poly(3,4-ethylenedioxythiophene)/polypyrrole composite. J. Power Sources 163, 1120–1125 (2007)CrossRef
38.
go back to reference Y. Song, T.W. Noh, S.-I. Lee, J.R. Gaines, Experimental study of the three-dimensional ac conductivity and dielectric constant of a conductor-insulator composite near the percolation threshold. Phys. Rev. B 33, 904–908 (1986)CrossRef Y. Song, T.W. Noh, S.-I. Lee, J.R. Gaines, Experimental study of the three-dimensional ac conductivity and dielectric constant of a conductor-insulator composite near the percolation threshold. Phys. Rev. B 33, 904–908 (1986)CrossRef
39.
go back to reference C. Pecharromán, J.S. Moya, Experimental evidence of a giant capacitance in insulator-conductor composites at the percolation threshold. Adv. Mater. 12, 294–297 (2000)CrossRef C. Pecharromán, J.S. Moya, Experimental evidence of a giant capacitance in insulator-conductor composites at the percolation threshold. Adv. Mater. 12, 294–297 (2000)CrossRef
40.
go back to reference Rajwali Khan Zulfiqar, Yuliang Yuan et al., Variation of structural, optical, dielectric and magnetic properties of SnO2 nanoparticles. J Mater Sci. 28, 4625–4636 (2016) Rajwali Khan Zulfiqar, Yuliang Yuan et al., Variation of structural, optical, dielectric and magnetic properties of SnO2 nanoparticles. J Mater Sci. 28, 4625–4636 (2016)
Metadata
Title
Investigation of structural, optical, electrochemical and dielectric properties of SnO2/GO nanocomposite
Authors
Sardarali Khan
Zulfiqar
Tahirzeb Khan
Rajwali Khan
Majid Khan
Shaukat Ali khattak
Gulzar khan
Publication date
20-04-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 11/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01356-3

Other articles of this Issue 11/2019

Journal of Materials Science: Materials in Electronics 11/2019 Go to the issue