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2017 | OriginalPaper | Chapter

3. Ionic Conductors and Aspects Related to High Temperature

Authors : Xuefeng Zhu, Weishen Yang

Published in: Mixed Conducting Ceramic Membranes

Publisher: Springer Berlin Heidelberg

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Abstract

The ionic conductivity of perovskite-type MIEC membranes is several orders of magnitude lower than their electronic conductivity; however, the ambipolar conductivity determines the diffusion rate of oxygen ions in the membrane bulk. Therefore, the improvement of oxygen ionic conductivity is the key to enhance the oxygen permeability of an MIEC material. In this chapter, the common oxygen ionic conductors with fluorite and perovskite structures are introduced in detail, and other types of oxygen ionic conductors, such as Bi₄V₂O₁₁, La₂Mo₂O₉, and La_10-xSi₆O_26+y, are briefly presented. The critical factors influencing the oxygen ionic conductivity are discussed for the perovskite-type oxygen ionic conductors and MIEC conductors. All the oxygen ionic conducting materials can be made into MIEC membranes for oxygen permeation as long as they are properly doped by elements with variable valence states or mixed with a secondary phase with electronic conduction. MIEC membranes are all operated at high temperatures, and thus, the special properties related to high temperature, such as cationic diffusion, kinetic demixing, thermal expansion, chemical expansion, and creep, are briefly introduced to show that several factors should be considered to design or select a practically applicable MIEC membrane material.

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previous chapter Defects and Diffusion

next chapter Fabrication and Characterization of MIEC Membranes

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Title: Ionic Conductors and Aspects Related to High Temperature
Authors: Xuefeng Zhu
Weishen Yang
Publisher: Springer Berlin Heidelberg
Book: Mixed Conducting Ceramic Membranes
Print ISBN: 978-3-662-53532-5

Electronic ISBN: 978-3-662-53534-9

Copyright Year: 2017
DOI: https://doi.org/10.1007/978-3-662-53534-9_3