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Arabian Journal for Science and Engineering

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11-02-2021 | Research Article-Chemical Engineering

Isotherm and Kinetics Parametric Studies for Aqueous Hg(II) Uptake onto N-[2-(Methylamino)Ethyl]Ethane-1,2-Diaminated Acrylic Fibre

Authors: A. Hashem, A. Okeil, M. Fikry, A. Aly, C. O. Aniagor

Published in: Arabian Journal for Science and Engineering | Issue 7/2021

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Abstract

N-[2-(methylamino)ethyl] ethane-1,2-diaminated acrylic fibre (DAAF) derived adsorbent was prepared by the reaction of acrylic fibre with bis(2-aminoethyl)amine. Fourier transform infrared spectroscopy and scanning electron microscopy were employed for elucidating the surface functional groups and morphology of DAAF, respectively. The influence of several process variables on Hg(II) adsorption was also evaluated. Equilibrium and kinetic studies were conducted using a range of two-parameter models via nonlinear regression methods. Langmuir and pseudo-second-order models emerged the best fit for isotherm and kinetic modelling, respectively. The intraparticle diffusion studies indicate that occurrence of an adsorption process, with multi-mechanistic effect. Similarly, the maximum adsorption capacity (q_max) of 627.5 mg g⁻¹ was recorded in the study at pH 5.0, 30 °C and 15–30 min. The short equilibration time recorded in the study speaks volume of the potential application of DAAF in large-scale Hg(II) adsorption systems.

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Burakov, A.E.; Galunin, E.V.; Burakova, I.V.; Kucherova, A.E.; Agarwal, S.; Tkachev, A.G.; Gupta, V.K.: Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: a review. Ecotoxicol. Environ. Saf. 148, 702–712 (2018)CrossRef

Kim, M.Y.; Seo, H.; Lee, T.G.: Removal of Hg(II) ions from aqueous solution by poly (allylamine-co-methacrylamide-co-dimethylthiourea). J. Ind. Eng. Chem. 84, 82–86 (2020)CrossRef

Meena, A.K.; Kadirvelu, K.; Mishra, G.; Rajagopal, C.; Nagar, P.: Adsorptive removal of heavy metals from aqueous solution by treated sawdust (Acacia arabica). J. Hazard. Mater. 150(3), 604–611 (2008)CrossRef

Moulick, D.; Santra, S.C.; Ghosh, D.: Effect of selenium induced seed priming on arsenic accumulation in rice plant and subsequent transmission in human food chain. Ecotoxicol. Environ. Saf. 152, 67–77 (2018)CrossRef

Fu, Y.; Jiang, J.; Chen, Z.; Ying, S.; Wang, J.; Hu, J.: Rapid and selective removal of Hg(II) ions and high catalytic performance of the spent adsorbent based on functionalized mesoporous silica/poly (m-aminothiophenol) nanocomposite. J. Mol. Liq. 286, 110746 (2019)CrossRef

Saman, N.; Kong, H.; Mohtar, S.S.; Johari, K.; Mansor, A.F.; Hassan, O.; Ali, N.; Mat, H.: A comparative study on dynamic Hg(II) and MeHg (II) removal by functionalized agrowaste adsorbent: breakthrough analysis and adsorber design. Korean J. Chem. Eng. 36(7), 1069–1081 (2019)CrossRef

Aslam, B.; Wang, W.; Arshad, M.I.; Khurshid, M.; Muzammil, S.; Rasool, M.H.; Nisar, M.A.; Alvi, R.F.; Aslam, M.A.; Qamar, M.U.; Salamat, M.K.F.; Baloch, Z.: Antibiotic resistance: a rundown of a global crisis. Infect. Drug Resist. 11, 1645–1658 (2018)CrossRef

Qi, L.; Teng, F.; Deng, X.; Zhang, Y.; Zhong, X.: Experimental study on adsorption of Hg(II) with microwave-assisted alkali-modified fly ash. Powder Technol. 351, 153–158 (2019)CrossRef

Zhang, S.; Yu, C.; Liu, N.; Teng, Y.; Yin, C.: Preparation of transparent anti-pollution cellulose carbamate regenerated cellulose membrane with high separation ability. Int. J. Biol. Macromol. 139, 332–341 (2019)CrossRef

10.

Gulgonul, I.; Çelik, M.S.: Understanding the flotation separation of Na and K feldspars in the presence of KCl through ion exchange and ion adsorption. Miner. Eng. 129, 41–46 (2018)CrossRef

11.

Li, M.; Xi, X.; Nie, Z.; Ma, L.; Liu, Q.: Recovery of tungsten from WC–Co hard metal scraps using molten salts electrolysis. J. Mater. Res. Technol. 8(1), 1440–1450 (2019)CrossRef

12.

Wang, T.; Wang, Q.; Soklun, H.; Qu, G.; Xia, T.; Guo, X.; Jia, H.; Zhu, L.: A green strategy for simultaneous Cu (II)-EDTA decomplexation and Cu precipitation from water by bicarbonate-activated hydrogen peroxide/chemical precipitation. Chem. Eng. J. 370, 1298–1309 (2019)CrossRef

13.

Hasanzadeh, V.; Rahmanian, O.; Heidari, M.: Cefixime adsorption onto activated carbon prepared by dry thermochemical activation of date fruit residues. Microchem. J. 152, 104261 (2020)CrossRef

14.

Ma, L.; He, M.; Fu, P.; Jiang, X.; Lv, W.; Huang, Y.; Liu, Y.; Wang, H.: Adsorption of volatile organic compounds on modified spherical activated carbon in a new cyclonic fluidized bed. Sep. Purif. Technol. 235, 116146 (2020)CrossRef

15.

Kwon, J.-S.; Yun, S.-T.; Lee, J.-H.; Kim, S.-O.; Jo, H.Y.: Removal of divalent heavy metals (Cd, Cu, Pb, and Zn) and arsenic (III) from aqueous solutions using scoria: kinetics and equilibria of sorption. J. Hazard. Mater. 174(1–3), 307–313 (2010)CrossRef

16.

Hashem, A.; Hammad, H.A.; Al-Anwar, A.: Modified Camelorum tree particles as a new adsorbent for adsorption of Hg(II) from aqueous solutions: kinetics, thermodynamics and non-linear isotherms. Desalin. Water Treatm. 57(50), 23827–23843 (2016)CrossRef

17.

Hashem, A.; Al-Anwar, A.; Nagy, N.M.; Hussein, D.M.; Eisa, S.: Isotherms and kinetic studies on adsorption of Hg(II) ions onto Ziziphus spina-christi L. from aqueous solutions. Green Process. Synth. 5(2), 213–224 (2016)

18.

Hashem, A.; Hussein, H.A.; Sanousy, M.A.; Adam, E.; Saad, E.E.: Monomethylolated thiourea–sawdust as a new adsorbent for removal of Hg(II) from contaminated water: equilibrium kinetic and thermodynamic studies. Polym. Plast. Technol. Eng. 50(12), 1220–1230 (2011)CrossRef

19.

Hashem, A.; Badawy, S.M.: Sesbania sesban L. biomass as a novel adsorbent for removal of Pb(II) ions from aqueous solution: non-linear and error analysis. Green Process. Synth. 4(3), 179–190 (2015)

20.

Peydayesh, M.; Suter, M.K.; Bolisetty, S.; Boulos, S.; Handschin, S.; Nystrom, L.; Mezzenga, R.: Amyloid fibrils aerogel for sustainable removal of organic contaminants from water. Adv. Mater. 32(12), e1907932 (2020)CrossRef

21.

Abdouss, M.; Shoushtari, A.M.; Shamloo, N.; Haji, A.: Modified PET fibres for metal ion and dye removal from aqueous media. Polym. Polym. Compos. 21(4), 251–258 (2013)

22.

Racho, P.; Phalathip, P.: Modified nylon fibers with amino chelating groups for heavy metal removal. Energy Procedia 118, 195–200 (2017)CrossRef

23.

Abdouss, M.; Shoushtari, M.A.; Haji, A.; Moshref, B.: Fabrication of chelating diethylenetriaminated pan micro-and nano-fibers for heavy metal removal. Chem. Ind. Chem. Eng. Q./CICEQ 18(1), 27–34 (2012)CrossRef

24.

Huang, F.; Xu, Y.; Liao, S.; Yang, D.; Hsieh, Y.-L.; Wei, Q.: Preparation of amidoxime polyacrylonitrile chelating nanofibers and their application for adsorption of metal ions. Materials 6(3), 969–980 (2013)CrossRef

25.

Mohamed, E.F.; El-Hashemy, M.A.; Abdel-Latif, N.M.; Shetaya, W.H.: Production of sugarcane bagasse-based activated carbon for formaldehyde gas removal from potted plants exposure chamber. J. Air Waste Manag. Assoc. 65(12), 1413–1420 (2015)CrossRef

26.

Aniagor, C.; Menkiti, M.: Synthesis, modification and use of lignified bamboo isolate for the renovation of crystal violet dye effluent. Appl. Water Sci. 9(4), 77 (2019)CrossRef

27.

Menkiti, M.; Aniagor, C.; Agu, C.; Ugonabo, V.: Effective adsorption of crystal violet dye from an aqueous solution using lignin-rich isolate from elephant grass. Water Conserv. Sci. Eng. 3(1), 33–46 (2018)CrossRef

28.

Aniagor, C.; Menkiti, M.: Kinetics and mechanistic description of adsorptive uptake of crystal violet dye by lignified elephant grass complexed isolate. J. Environ. Chem. Eng. 6(2), 2105–2118 (2018)CrossRef

29.

Tsai, S.-C.; Juang, K.-W.: Comparison of linear and nonlinear forms of isotherm models for strontium sorption on a sodium bentonite. J. Radioanal. Nucl. Chem. 243(3), 741–746 (2000)CrossRef

30.

Hashem, A.; Badawy, S.; Farag, S.; Mohamed, L.; Fletcher, A.; Taha, G.: Non-linear adsorption characteristics of modified pine wood sawdust optimised for adsorption of Cd(II) from aqueous systems. J. Environ. Chem. Eng. 8, 103966 (2020)CrossRef

31.

Ayawei, N.; Ebelegi, A.N.; Wankasi, D.: Modelling and interpretation of adsorption isotherms. J. Chem. 2017, 3039817 (2017)CrossRef

32.

Al-Ghouti, M.A.; Da’ana, D.A.: Guidelines for the use and interpretation of adsorption isotherm models: a review. J. Hazard. Mater. 393, 122383 (2020)CrossRef

33.

Aniagor, C.O.; Menkiti, M.C.: Relational description of an adsorption system based on isotherm, adsorption density, adsorption potential, hopping number and surface coverage. Sigma 38(3), 1073–1098 (2020)

34.

Temkin, M.: Kinetics of ammonia synthesis on promoted iron catalysts. Acta Physiochim. URSS 12, 327–356 (1940)

35.

Kajjumba, G.W.; Emik, S.; Öngen, A.; Özcan, H.K.; Aydın, S.: Modelling of Adsorption Kinetic Processes—Errors, Theory and Application, in Advanced Sorption Process Applications. IntechOpen, London (2018)

36.

Menkiti, M.; Abonyi, M.; Aniagor, C.: Process equilibrium, kinetics, and mechanisms of ionic-liquid induced Dephenolation of petroleum effluent. Water Conserv. Sci. Eng. 3(3), 205–220 (2018)CrossRef

37.

Thommes, M.; Kaneko, K.; Neimark, A.V.; Olivier, J.P.; Rodriguez-Reinoso, F.; Rouquerol, J.; Sing, K.S.: Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl. Chem. 87(9–10), 1051–1069 (2015)CrossRef

38.

Sing, K.S.: Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Provisional). Pure Appl. Chem. 54(11), 2201–2218 (1982)CrossRef

39.

Hashem, A.; Nasr, M.; Fletcher, A.; Mohamed, L.A.: Aminated acrylic fabric waste derived sorbent for Cd (II) ion removal from aqueous solutions: mechanism, equilibria and kinetics. J. Polym. Environ. 1–12 (2020)

40.

Martín-Lara, M.; Hernáinz, F.; Calero, M.; Blázquez, G.; Tenorio, G.: Surface chemistry evaluation of some solid wastes from olive-oil industry used for lead removal from aqueous solutions. Biochem. Eng. J. 44(2–3), 151–159 (2009)CrossRef

41.

Hashem, A.; Fletcher, A.; El-Sakhawy, M.; Mohamed, L.A.; Farag, S.: Aminated hydroximoyl camelthorn residues as a novel adsorbent for extracting Hg(II) from contaminated water: studies of isotherm, kinetics, and mechanism. J. Polym. Environ. 28(9), 2498–2510 (2020)CrossRef

42.

Hashem, A.; Fletcher, A.; Safri, A.; Ghith, A.; Hussein, D.: Carbamoylethylated wood pulp as a new sorbent for removal of Hg(II) from contaminated water: isotherm and kinetic studies. J. Polym. Environ. 2020, 1–11 (2020)

43.

Abonyi, M.; Aniagor, C.; Menkiti, M.: Effective dephenolation of effluent from petroleum industry using ionic-liquid-induced hybrid adsorbent. Arab. J. Sci. Eng. 44(12), 10017–10029 (2019)CrossRef

44.

Hashem, A.; Abou-Okeil, A.; El-Shafie, A.; El-Sakhawy, M.: Grafting of high α-cellulose pulp extracted from sunflower stalks for removal of Hg(II) from aqueous solution. Polym. Plast. Technol. Eng. 45(1), 135–141 (2006)CrossRef

45.

Kuang, Y.; Zhang, X.; Zhou, S.: Adsorption of methylene blue in water onto activated carbon by surfactant modification. Water 12(2), 587 (2020)CrossRef

46.

Lagergren, S.K.: About the theory of so-called adsorption of soluble substances. Sven. Vetenskapsakad. Handingarl 24, 1–39 (1898)

47.

El-Khaiary, M.I.: Kinetics and mechanism of adsorption of methylene blue from aqueous solution by nitric-acid treated water-hyacinth. J. Hazard. Mater. 147(1–2), 28–36 (2007)CrossRef

48.

Weber, W.J.; Morris, J.C.: Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. 89(2), 31–60 (1963)CrossRef

49.

Kannan, N.; Sundaram, M.M.: Kinetics and mechanism of removal of methylene blue by adsorption on various carbons—a comparative study. Dyes Pigm. 51(1), 25–40 (2001)CrossRef

50.

Poots, V.; McKay, G.; Healy, J.: Removal of basic dye from effluent using wood as an adsorbent. J. Water Pollut. Control Feder. 1978, 926–935 (1978)

51.

Marrakchi, F.; Ahmed, M.; Khanday, W.; Asif, M.; Hameed, B.: Mesoporous-activated carbon prepared from chitosan flakes via single-step sodium hydroxide activation for the adsorption of methylene blue. Int. J. Biol. Macromol. 98, 233–239 (2017)CrossRef

52.

Kołodyńska, D.; Hałas, P.; Franus, M.; Hubicki, Z.: Zeolite properties improvement by chitosan modification—sorption studies. J. Ind. Eng. Chem. 52, 187–196 (2017)CrossRef

53.

Tsibranska, I.; Hristova, E.: Comparison of different kinetic models for adsorption of heavy metals onto activated carbon from apricot stones. Bul. Chem. Commun. 43(3), 370–377 (2011)

Title: Isotherm and Kinetics Parametric Studies for Aqueous Hg(II) Uptake onto N-[2-(Methylamino)Ethyl]Ethane-1,2-Diaminated Acrylic Fibre
Authors: A. Hashem
A. Okeil
M. Fikry
A. Aly
C. O. Aniagor
Publication date: 11-02-2021
Publisher: Springer Berlin Heidelberg
Published in: Arabian Journal for Science and Engineering / Issue 7/2021
Print ISSN: 2193-567X
Electronic ISSN: 2191-4281
DOI: https://doi.org/10.1007/s13369-021-05416-x

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