Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Science, Series C
Published in: Polymer Science, Series C 1/2019

01-09-2019

Kinetics of Dicyclopentadiene Polymerization in the Presence of the Second Generation Hoveyda-Grubbs Catalyst with N-Chelating Ligand

Authors: A. A. Lyapkov, L. S. Soroka, R. V. Ashirov, D. I. Zemlyakov, D. A. Rusakov, F. Verpoort

Published in: Polymer Science, Series C | Issue 1/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

This article considers the thermodynamic aspects, thermo- and rheokinetics of endo-dicyclopentadiene polymerization in the presence of the original metathesis second Hoveyda-Grubbs catalyst with an N-chelating ligand. The activation energy of endo-dicyclopentadiene polymerization was determined as 88.9–89.2 kJ/mol. The thermal effect of the ring-opening metathesis endo-dicyclopentadiene polymerization reaction reaches 52.7 kJ/mol. This is lower than the values for molybdenum- and tungsten-containing catalysts reported in the literature, which can be explained by a different microstructure of the polymer produced in the presence of ruthenium-based metathesis catalysts.
previous article Promising Catalytic Processes of Dicyclopentadiene Metathesis Polymerization to Obtain a New Class of Polymeric and Polymer–Composite Materials
next article Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
S. Monsaert, A. Lozano Vila, R. Drozdzak, P. Van Der Voort, and F. Verpoort, Chem. Soc. Rev. 38, 3360 (2009).CrossRef
2.
S. Monsaert, N. Ledoux, R. Drozdzak, and F. Verpoort, J. Polym. Sci., Part A: Polym. Chem. 48, 302 (2010).CrossRef
3.
R. Drozdzak, N. Nishioka, G. Recher, and F. Verpoort, Macromol. Symp. 293, 1 (2010).CrossRef
4.
S. Sutthasupa, M. Shiotsuki, T. Masuda, and F. Sanda, J. Am. Chem. Soc. 131, 10546 (2009).CrossRef
5.
6.
C. W. Bielawski, D. Benitez, and R. H. Grubbs, J. Am. Chem. Soc. 123, 11312 (2001).CrossRef
7.
A.J. Boydston, Y. Xia, J. A. Kornfield, I. A. Gorodetskaya, and R. H. Grubbs, J. Am. Chem. Soc. 130, 12775 (2008).CrossRef
8.
Y. Xia, A. J. Boydston, Y. Yao, J. A. Kornfield, I. A. Gorodetskaya, H. W. Spiess, and R. H. Grubbs, J. Am. Chem. Soc. 131, 2670 (2009).CrossRef
9.
10.
K. Weissermel and H.-J. Arpe, Industrielle Organische Chemie, 4th ed. (Wiley-VCH, Weinheim, 1994).
11.
O. M. Singh, J. Sci. Ind. Res.65, 957 (2006).
12.
V. D. Kolesnik, R. V. Ashirov, N. M. Shcheglova, E. S. Novikova, R. V. Yakimov, A. A. Nosikov, M. N. Bogomolova, and N. M. Cheremukhina, RF Patent No. 2,409,420 (2011).
13.
M. R. Kessler, N. R. Sottos, and S. R. White, Composites, Part A 34, 743 (2003).CrossRef
14.
K. Oláh, Period. Polytech., Chem. Eng. 45, 3 (2001).
15.
M. R. Kessler and S. R. White, J. Polym. Sci., Part A: Polym. Chem. 40, 2373 (2002).CrossRef
16.
17.
A. K. Oppenheim, R. Spektor, A. L. Kuhl, in Proceedings of 17th ICDERS, Heidelberg, Germany, 1999 (Heidelberg, 1999), p. 128.
18.
19.
J. H. Flynn and L. A. Wall, J. Polym. Sci., Part B: Polym. Lett. 4, 191 (1966).CrossRef
20.
J. H. Flynn and L. A. Wall, J. Polym. Sci., Part B: Polym. Lett. 5, 323 (1967).CrossRef
21.
22.
T. A. Davidson, K. B. Wagener, and D. B. Priddy, Macromolecules 29, 786 (1996).CrossRef
23.
B. J. Rohde, K.-M. Le, R. Krishnamoorti, and M. L. Robertson, Macromolecules 49, 8960 (2016).CrossRef
24.
M. Cioffi, A. C. Hoffmann, and L. P. B. M. Janssen, Polym. Eng. Sci. 41, 595 (2001).CrossRef
25.
M. R. Kessler, G. E. Larin, and N. Bernklau, J. Therm. Anal. Calorim. 85, 7 (2006).CrossRef
26.
M. Cioffi, K. J. Ganzeveld, A. C. Hoffmann, and L. P. B. M. Janssen, Polym. Eng. Sci. 42, 2383 (2002).CrossRef
Metadata
Title
Kinetics of Dicyclopentadiene Polymerization in the Presence of the Second Generation Hoveyda-Grubbs Catalyst with N-Chelating Ligand
Authors
A. A. Lyapkov
L. S. Soroka
R. V. Ashirov
D. I. Zemlyakov
D. A. Rusakov
F. Verpoort
Publication date
01-09-2019
Publisher
Pleiades Publishing
Published in
Polymer Science, Series C / Issue 1/2019
Print ISSN: 1811-2382
Electronic ISSN: 1555-614X
DOI
https://doi.org/10.1134/S1811238219010107

Other articles of this Issue 1/2019

Polymer Science, Series C 1/2019 Go to the issue

OriginalPaper

Synthesis of Pentablock Copolymers of the Mixed Linear-Brush Topology by Controlled Radical Polymerization and Ring-Opening Polymerization Reactions

OriginalPaper

Norbornene Addition Polymerization with Catalysts Based on Transition Metal Compounds: 2008–2018

OriginalPaper

Metathesis Polymerization in Ionic Media

OriginalPaper

Unusual Structural Changes of PIM-1 Polymer Detected by Means of Chromatographic Technique

OriginalPaper

Iridium-Containing Polymers Based on Norbornene and 7-Oxa-norbornene Monomers: Synthesis and Photophysical and Biological Properties

OriginalPaper

Ruthenium–Carbene Complexes in the Synthesis of Polybutadiene and Its Cross-Metathesis with Polynorbornene

Premium Partners

    Image Credits