Skip to main content
Top

2014 | OriginalPaper | Chapter

10. Kinetics of NH3-SCR Reactions Over V2O5–WO3/TiO2 Catalyst

Authors : Isabella Nova, Enrico Tronconi

Published in: Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts

Publisher: Springer New York

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

An extensive investigation of the chemistry, the mechanism, and the kinetics of the NO-NO2/NH3 SCR reactions for mobile applications was performed over a commercial vanadium-based catalyst. On the basis of the collected results, a Mars-Van Krevelen dynamic kinetic model was derived, which unifies the rates of the Standard and the Fast SCR into a single Redox-type approach.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Ciardelli C, Nova I, Tronconi E, Konrad B, Chatterjee D, Ecke K, Weibel M, Chemical Engineering Science (2004) 59:5301–5309 Ciardelli C, Nova I, Tronconi E, Konrad B, Chatterjee D, Ecke K, Weibel M, Chemical Engineering Science (2004) 59:5301–5309
2.
go back to reference Ciardelli C, Nova I, Tronconi E, Chatterjee D, Bandl-Konrad B, Chemical Communications (2004) 23:2718–271 Ciardelli C, Nova I, Tronconi E, Chatterjee D, Bandl-Konrad B, Chemical Communications (2004) 23:2718–271
3.
go back to reference Tronconi E, Nova I, Ciardelli C, Chatterjee D, Bandl-Konrad B, Burkhardt T, Catalysis Today (2005) 105(3-4):529–536 Tronconi E, Nova I, Ciardelli C, Chatterjee D, Bandl-Konrad B, Burkhardt T, Catalysis Today (2005) 105(3-4):529–536
4.
go back to reference Nova I, Ciardelli C, Tronconi E, Chatterjee D, Bandl-Konrad B, Catalysis Today (2006) 114(1):3–12 Nova I, Ciardelli C, Tronconi E, Chatterjee D, Bandl-Konrad B, Catalysis Today (2006) 114(1):3–12
5.
go back to reference Nova I, Ciardelli C, Tronconi E, Chatterjee D, Bandl-Konrad B, AIChE Journal (2006) 52(9):3222–3233 Nova I, Ciardelli C, Tronconi E, Chatterjee D, Bandl-Konrad B, AIChE Journal (2006) 52(9):3222–3233
6.
go back to reference Tronconi E, Nova I, Ciardelli C, Chatterjee D, Weibel M., Journal of Catalysis (2007) 245(1):1–10 Tronconi E, Nova I, Ciardelli C, Chatterjee D, Weibel M., Journal of Catalysis (2007) 245(1):1–10
7.
go back to reference Ciardelli C, Nova I, Tronconi E, Bandl-Konrad B, Chatterjee D, Weibel M, Krutzsch B, Applied Catalysis B: Environmental (2007) 70(1-4):80–90 Ciardelli C, Nova I, Tronconi E, Bandl-Konrad B, Chatterjee D, Weibel M, Krutzsch B, Applied Catalysis B: Environmental (2007) 70(1-4):80–90
8.
go back to reference Nova I, Ciardelli C, Tronconi E, Chatterjee D, Weibel M, AIChE Journal (2009) 55(6) 1514–1529 Nova I, Ciardelli C, Tronconi E, Chatterjee D, Weibel M, AIChE Journal (2009) 55(6) 1514–1529
9.
go back to reference Nova I, Ciardelli C, Tronconi E, Chatterjee D, Weibel M, Topics in Catalysis (2007) 42-43(1-4):43–46 Nova I, Ciardelli C, Tronconi E, Chatterjee D, Weibel M, Topics in Catalysis (2007) 42-43(1-4):43–46
10.
go back to reference Ciardelli C, Nova I, Tronconi E, Ascherfeld M, Fabinski W, Topics in Catalysis, (2007) 42-43(1-4):161–164 Ciardelli C, Nova I, Tronconi E, Ascherfeld M, Fabinski W, Topics in Catalysis, (2007) 42-43(1-4):161–164
11.
go back to reference Tronconi E, Nova I, Colombo M, Ind. Eng. Chem. Res. (2010) 49(21):10374–10385 Tronconi E, Nova I, Colombo M, Ind. Eng. Chem. Res. (2010) 49(21):10374–10385
12.
go back to reference Lietti L, Nova I, Camurri S, Tronconi E, Forzatti P, AIChE J. (1997) 43:2559 Lietti L, Nova I, Camurri S, Tronconi E, Forzatti P, AIChE J. (1997) 43:2559
13.
go back to reference Finlayson B, Non Linear Analysis in Chemical Engineering, (1980) McGraw-Hill, New York Finlayson B, Non Linear Analysis in Chemical Engineering, (1980) McGraw-Hill, New York
14.
go back to reference Hindmarsh AC, ACM-Signum Newsletter (1980) 15:10 Hindmarsh AC, ACM-Signum Newsletter (1980) 15:10
15.
go back to reference Donati G, Buzzi-Ferraris G, Chem. Eng. Sci., (1974) 29:1504 Donati G, Buzzi-Ferraris G, Chem. Eng. Sci., (1974) 29:1504
16.
go back to reference Madia G, Elsener M, Koebel M, Raimondi F, Wokaun A, Appl. Catal. B: Environmental (2002) 39:181 Madia G, Elsener M, Koebel M, Raimondi F, Wokaun A, Appl. Catal. B: Environmental (2002) 39:181
17.
go back to reference Amiridis MD, Wachs IE, Deo G, Jehng J, Kimy DS, J. Catal. (1996) 161: 247 Amiridis MD, Wachs IE, Deo G, Jehng J, Kimy DS, J. Catal. (1996) 161: 247
18.
go back to reference Busca G, Lietti L, Ramis G, Berti F, Appl. Catal. B: Environmental (1998) 18:1 Busca G, Lietti L, Ramis G, Berti F, Appl. Catal. B: Environmental (1998) 18:1
19.
go back to reference Forzatti P, Lietti L, Tronconi E, Nitrogen oxides removal in Industrial. Encyclopedia of Catalysis, 2nd Ed., (2010) I.T Horvath (Ed.), John Wiley & Sons, New York Forzatti P, Lietti L, Tronconi E, Nitrogen oxides removal in Industrial. Encyclopedia of Catalysis, 2nd Ed., (2010) I.T Horvath (Ed.), John Wiley & Sons, New York
20.
go back to reference Bosch H, Janssen F, Catal. Today(1988) 2:369 Bosch H, Janssen F, Catal. Today(1988) 2:369
21.
go back to reference Topsøe NY, Topsøe H, Dumesic JA, J. Catal. (1995) 151:226 Topsøe NY, Topsøe H, Dumesic JA, J. Catal. (1995) 151:226
22.
go back to reference Nova I, Lietti L, Tronconi E, Forzatti P, Chem. Eng. Sci. (2001) 56:1229 Nova I, Lietti L, Tronconi E, Forzatti P, Chem. Eng. Sci. (2001) 56:1229
23.
go back to reference Lietti L, Nova I, Tronconi E, Forzatti P in Reaction Engineering for Pollution Prevention M.A. Abraham, R.P. Hesketh (Eds.), Elsevier Science (2000) 85–112 Lietti L, Nova I, Tronconi E, Forzatti P in Reaction Engineering for Pollution Prevention M.A. Abraham, R.P. Hesketh (Eds.), Elsevier Science (2000) 85–112
24.
go back to reference Nova I, Lietti L, Tronconi E, Forzatti P, Catalysis Today, (2000) 60:73–82 Nova I, Lietti L, Tronconi E, Forzatti P, Catalysis Today, (2000) 60:73–82
25.
go back to reference Topsøe NY, Dumesic JA, Topsøe H, J. Catal. (1995) 151:241 Topsøe NY, Dumesic JA, Topsøe H, J. Catal. (1995) 151:241
26.
go back to reference Ramis G, Yi L, Busca G, Catal. Today (1996) 28:373 Ramis G, Yi L, Busca G, Catal. Today (1996) 28:373
27.
go back to reference Lietti L, Alemany JL, Forzatti P, Busca G, Ramis G, Giamello E, Bregani F, Catal. Today (1996) 29:143 Lietti L, Alemany JL, Forzatti P, Busca G, Ramis G, Giamello E, Bregani F, Catal. Today (1996) 29:143
28.
go back to reference Amirids MD, Duevel RV, Wachs IE, Appl. Catal. B (1999) 20:111 Amirids MD, Duevel RV, Wachs IE, Appl. Catal. B (1999) 20:111
29.
go back to reference Srnak TZ, Dumesic JA, Clausen BS, Tornquist E, Topsøe NY, J. Catal. (1991) 135:246 Srnak TZ, Dumesic JA, Clausen BS, Tornquist E, Topsøe NY, J. Catal. (1991) 135:246
30.
go back to reference Roduit B, Wokaun A, Baiker A, Ind. Eng. Chem. Res (1998) 37:4577 Roduit B, Wokaun A, Baiker A, Ind. Eng. Chem. Res (1998) 37:4577
31.
go back to reference Lietti L, Nova I, Forzatti P, Topics in Catalysis, (2000) 11/12:111–122 Lietti L, Nova I, Forzatti P, Topics in Catalysis, (2000) 11/12:111–122
32.
go back to reference Willey RJ, Elridge JW, Kittrell JR, Ind. Eng. Chem. Prod. Res. Dev (1985) 24: 226 Willey RJ, Elridge JW, Kittrell JR, Ind. Eng. Chem. Prod. Res. Dev (1985) 24: 226
33.
go back to reference Willey RJ, Lai H, Peri JB, J. Catal. (1991) 130:319 Willey RJ, Lai H, Peri JB, J. Catal. (1991) 130:319
34.
go back to reference Kapteijn F, Singoredjo L, Dekker NJJ, Moulijn JA, Ind. Eng. Chem. Res. (1993) 32:445 Kapteijn F, Singoredjo L, Dekker NJJ, Moulijn JA, Ind. Eng. Chem. Res. (1993) 32:445
35.
go back to reference Koebel M, Elsener M, Chem. Eng. Sci. (1998) 53: 657 Koebel M, Elsener M, Chem. Eng. Sci. (1998) 53: 657
36.
go back to reference Iwasaki IM, Yamazaki K, Shinjoh H, Applied Catalysis A: General (2009) 366:84–92 Iwasaki IM, Yamazaki K, Shinjoh H, Applied Catalysis A: General (2009) 366:84–92
37.
go back to reference Sjövall H, Blint RJ, Gopinath A, Olsson L, Industrial & Engineering Chemistry Research (2010) 49:39–52 Sjövall H, Blint RJ, Gopinath A, Olsson L, Industrial & Engineering Chemistry Research (2010) 49:39–52
38.
go back to reference Malmberg S, Votsmeier M, Gieshoff J, Soger N, Mussmann L, Schuler A, Drochner A, Topics in Catalysis (2007) 42–43:33–36 Malmberg S, Votsmeier M, Gieshoff J, Soger N, Mussmann L, Schuler A, Drochner A, Topics in Catalysis (2007) 42–43:33–36
39.
go back to reference Valdes-Solıs T, Marban G, Fuertes AB, Appl. Catal. B. (2003) 46:261 Valdes-Solıs T, Marban G, Fuertes AB, Appl. Catal. B. (2003) 46:261
40.
go back to reference Valdes-Solıs T, Marban G, Fuertes AB, Ind. Eng. Chem. Res. (2004) 43:2349 Valdes-Solıs T, Marban G, Fuertes AB, Ind. Eng. Chem. Res. (2004) 43:2349
41.
go back to reference Wachs IE, Deo G, Weckhuysen BM, Andreini A, Vuurman MA, de Boer M, Amiridis MD, J. Catal. (1996) 161:211 Wachs IE, Deo G, Weckhuysen BM, Andreini A, Vuurman MA, de Boer M, Amiridis MD, J. Catal. (1996) 161:211
42.
go back to reference Grossale A., Nova I., Tronconi E., Chatterjee, D., Weibel, M., J.Catal. (2008) 256:312-322 Grossale A., Nova I., Tronconi E., Chatterjee, D., Weibel, M., J.Catal. (2008) 256:312-322
43.
go back to reference Yeom Y, Henao J, Li MJ, Sachtler WMH, Weitz E, J. Catal. (2005) 231:181–193 Yeom Y, Henao J, Li MJ, Sachtler WMH, Weitz E, J. Catal. (2005) 231:181–193
44.
go back to reference Despres J, Koebel M, Kröcker O, Elsener M, Wokaun A, Appl. Cat. B: Environmental. (2003) 43:389–395 Despres J, Koebel M, Kröcker O, Elsener M, Wokaun A, Appl. Cat. B: Environmental. (2003) 43:389–395
45.
go back to reference Apostolescu N, Schroder T, Kureti S, App.Cat. B: Environmental (2004) 51:43–50 Apostolescu N, Schroder T, Kureti S, App.Cat. B: Environmental (2004) 51:43–50
46.
go back to reference Grossale A, Nova I, Tronconi E, Cat. Today (2007) 136:18–27 Grossale A, Nova I, Tronconi E, Cat. Today (2007) 136:18–27
Metadata
Title
Kinetics of NH3-SCR Reactions Over V2O5–WO3/TiO2 Catalyst
Authors
Isabella Nova
Enrico Tronconi
Copyright Year
2014
Publisher
Springer New York
DOI
https://doi.org/10.1007/978-1-4899-8071-7_10

Premium Partners