Skip to main content
Top
Published in: Wood Science and Technology 4/2013

01-07-2013 | Original

Leaching behaviour of benzalkonium chloride homologues in soil and water solutions

Authors: Teruhisa Miyauchi, Mitsunori Mori

Published in: Wood Science and Technology | Issue 4/2013

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Experiments were carried out to determine the leaching mechanism of benzalkonium chloride (BAC) from treated wood in soil. Wood specimens were treated with C12, C14 and C16 BAC homologues and exposed to soil or aqueous solutions containing oxalic acid, sodium oxalate, hydrochloric acid, sodium chloride or sodium humate. The leaching rates of the homologues in soil were close to each other and all higher than in distilled water. The order of the rates in soil (C12 ≈ C14 ≈ C16) was different from that in distilled water (C12 > C14 > C16). The leaching rates of the homologues in the acidic solutions and their salts solution were also higher than in distilled water, and the order of the rates was the same as in distilled water. The aqueous solution of sodium humate also accelerated homologue leaching but resulted in an order of C16 > C14 > C12. The BAC leaching acceleration mechanism by humate was thought to be different from the mechanisms of acids and their salts and plays an important role in the leaching behaviour of BAC in soil.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Albuquerque RM, Cragg SM, Icely JD (1995) Leaching from CCA-treated wood submerged in seawater: effects of high loadings, and a comparison between laboratory and marine condition. International Research Group on Wood Protection, Document No. IRG/WP 96-50080 Albuquerque RM, Cragg SM, Icely JD (1995) Leaching from CCA-treated wood submerged in seawater: effects of high loadings, and a comparison between laboratory and marine condition. International Research Group on Wood Protection, Document No. IRG/WP 96-50080
go back to reference AWPA Standard E20–06 (2007) Standard method for determining the leachability of wood preservatives in soil contact. American Wood-Preservers’ Association, Birmingham AWPA Standard E20–06 (2007) Standard method for determining the leachability of wood preservatives in soil contact. American Wood-Preservers’ Association, Birmingham
go back to reference AWPA Standard P5–07 (2007) Standard for waterborne preservatives. American Wood-Preservers’ Association, Birmingham AWPA Standard P5–07 (2007) Standard for waterborne preservatives. American Wood-Preservers’ Association, Birmingham
go back to reference Conklin AR Jr (2005) Soil basics III: the biological and organic components in soil. In: Conklin AR (ed) Introduction to soil chemistry. Wiley, New York, pp 45–70CrossRef Conklin AR Jr (2005) Soil basics III: the biological and organic components in soil. In: Conklin AR (ed) Introduction to soil chemistry. Wiley, New York, pp 45–70CrossRef
go back to reference Cooper PA, Jeremic D, Taylor JL, Ung YT (2000) Effect of humic acid on leaching of CCA from treated wood. International Research Group on Wood Protection, Document No. IRG/WP 00-50151 Cooper PA, Jeremic D, Taylor JL, Ung YT (2000) Effect of humic acid on leaching of CCA from treated wood. International Research Group on Wood Protection, Document No. IRG/WP 00-50151
go back to reference Crawford D, Fox R, Kamden P, Lebow S, Nicholas D, Pettry D, Schultz T, Sites L, Ziobro R (2002) Laboratory studies of CCA-C leaching: influence of wood and soil properties on extent of arsenic and copper depletion. International Research Group on Wood Protection, Document No. IRG/WP 02-50186 Crawford D, Fox R, Kamden P, Lebow S, Nicholas D, Pettry D, Schultz T, Sites L, Ziobro R (2002) Laboratory studies of CCA-C leaching: influence of wood and soil properties on extent of arsenic and copper depletion. International Research Group on Wood Protection, Document No. IRG/WP 02-50186
go back to reference Doyle AK, Ruddick JNR (1994) The microdistribution of alkylammonium compounds in ponderosa pine sapwood. Holzforschung 48:106–112CrossRef Doyle AK, Ruddick JNR (1994) The microdistribution of alkylammonium compounds in ponderosa pine sapwood. Holzforschung 48:106–112CrossRef
go back to reference Dubey B, Townsend T, Solo-Gabriele H, Bitton G (2007) Impact of surface water condition on preservative leaching and aquatic toxicity from treated wood products. Environ Sci Technol 41:3781–3786PubMedCrossRef Dubey B, Townsend T, Solo-Gabriele H, Bitton G (2007) Impact of surface water condition on preservative leaching and aquatic toxicity from treated wood products. Environ Sci Technol 41:3781–3786PubMedCrossRef
go back to reference García MT, Ribosa I, Guindulain T, Sánchez-Leal J, Vives-Rego J (2001) Fate and effect of monoalkyl quaternary ammonium surfactants in the aquatic environment. Environ Pollut 111:169–175PubMedCrossRef García MT, Ribosa I, Guindulain T, Sánchez-Leal J, Vives-Rego J (2001) Fate and effect of monoalkyl quaternary ammonium surfactants in the aquatic environment. Environ Pollut 111:169–175PubMedCrossRef
go back to reference Hingston JA, Collins CD, Murphy RJ, Leater JN (2001) Leaching of chromated copper arsenate wood preservatives: a review. Environ Pollut 111:53–66PubMedCrossRef Hingston JA, Collins CD, Murphy RJ, Leater JN (2001) Leaching of chromated copper arsenate wood preservatives: a review. Environ Pollut 111:53–66PubMedCrossRef
go back to reference Ismail ZZ, Tezel U, Pavlostathis SG (2010) Sorption of quaternary ammonium compounds to municipal sludge. Water Res 44:2303–2313PubMedCrossRef Ismail ZZ, Tezel U, Pavlostathis SG (2010) Sorption of quaternary ammonium compounds to municipal sludge. Water Res 44:2303–2313PubMedCrossRef
go back to reference Japanese Industrial Standard (JIS) (2010) JIS K1570:2010, wood preservatives. Japan Standard Association, Tokyo Japanese Industrial Standard (JIS) (2010) JIS K1570:2010, wood preservatives. Japan Standard Association, Tokyo
go back to reference Jin L, Preston AF (1991) The interaction of wood preservatives with lignocellulosic substrates. Holzforschung 45:455–459CrossRef Jin L, Preston AF (1991) The interaction of wood preservatives with lignocellulosic substrates. Holzforschung 45:455–459CrossRef
go back to reference Kartal SN, Hwang WJ, Imamura Y (2007) Evaluation of effect of leaching medium on the release of copper, chromium, and arsenic from treated wood. Build Environ 42:1188–1193CrossRef Kartal SN, Hwang WJ, Imamura Y (2007) Evaluation of effect of leaching medium on the release of copper, chromium, and arsenic from treated wood. Build Environ 42:1188–1193CrossRef
go back to reference Lebow S (1997) Effects of fixation conditions and seawater on leaching of wood treated with marine retention CCA. International Research Group on Wood Protection, Document No. IRG/WP 97-50088 Lebow S (1997) Effects of fixation conditions and seawater on leaching of wood treated with marine retention CCA. International Research Group on Wood Protection, Document No. IRG/WP 97-50088
go back to reference Loubinoux B, Malek H (1992) Interactions of quaternary ammonium salts with wood. Holzforschung 46(6):537–539CrossRef Loubinoux B, Malek H (1992) Interactions of quaternary ammonium salts with wood. Holzforschung 46(6):537–539CrossRef
go back to reference Loubinoux B, Malek H, Joly JP, Kilbertus G (1992) Interaction of quaternary ammonium salts with wood: influence of cation and anion structure on fixation and leaching. For Prod J 42(10):55–58 Loubinoux B, Malek H, Joly JP, Kilbertus G (1992) Interaction of quaternary ammonium salts with wood: influence of cation and anion structure on fixation and leaching. For Prod J 42(10):55–58
go back to reference Miyauchi T, Mori M (2007) Improved quantitative determination of benzalkonium chloride in treated wood by liquid chromatography. Holzforschung 61:337–341CrossRef Miyauchi T, Mori M (2007) Improved quantitative determination of benzalkonium chloride in treated wood by liquid chromatography. Holzforschung 61:337–341CrossRef
go back to reference Miyauchi T, Mori M (2008) Effect of components of leaching medium on the leaching of benzalkonium chloride from treated wood. J Wood Sci 54:490–494CrossRef Miyauchi T, Mori M (2008) Effect of components of leaching medium on the leaching of benzalkonium chloride from treated wood. J Wood Sci 54:490–494CrossRef
go back to reference Miyauchi T, Mori M (2009) Effects of alkyl chain length and the mixing of homologues with different alkyl chains on the leaching characteristics of benzalkonium chloride. Wood Sci Technol 43:225–235CrossRef Miyauchi T, Mori M (2009) Effects of alkyl chain length and the mixing of homologues with different alkyl chains on the leaching characteristics of benzalkonium chloride. Wood Sci Technol 43:225–235CrossRef
go back to reference Miyauchi T, Mori M, Ito K (2005) Quantitative determination of benzalkonium chloride in treated wood by solid-phase extraction followed by liquid chromatography with ultraviolet detection. J Chromatogr A 1095:74–80PubMedCrossRef Miyauchi T, Mori M, Ito K (2005) Quantitative determination of benzalkonium chloride in treated wood by solid-phase extraction followed by liquid chromatography with ultraviolet detection. J Chromatogr A 1095:74–80PubMedCrossRef
go back to reference Miyauchi T, Mori M, Imamura Y (2008) Leaching characteristics of homologues of benzalkonium chloride from wood treated with ammoniacal copper quaternary compounds. J Wood Sci 54:225–232CrossRef Miyauchi T, Mori M, Imamura Y (2008) Leaching characteristics of homologues of benzalkonium chloride from wood treated with ammoniacal copper quaternary compounds. J Wood Sci 54:225–232CrossRef
go back to reference Preston AF, Walcheski PJ, McKaig PA, Nicholas DD (1978) Recent research on alkylammonium compounds in the US. American Wood-Preserver’s Association 83:331–348 Preston AF, Walcheski PJ, McKaig PA, Nicholas DD (1978) Recent research on alkylammonium compounds in the US. American Wood-Preserver’s Association 83:331–348
go back to reference Tsunoda K (1990) Effect of alkyl chain length on the fungicidal efficacy of benzalkonium chloride. J Antibact Antifung Agents 18(4):185–189 Tsunoda K (1990) Effect of alkyl chain length on the fungicidal efficacy of benzalkonium chloride. J Antibact Antifung Agents 18(4):185–189
go back to reference Van Eetevelde G, Orsler R, Holland G, Stevens M (1995) Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic applications Part 1: laboratory scale investigation. International Research Group on Wood Protection, Document No. IRG/WP 95-50046 Van Eetevelde G, Orsler R, Holland G, Stevens M (1995) Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic applications Part 1: laboratory scale investigation. International Research Group on Wood Protection, Document No. IRG/WP 95-50046
go back to reference Van Ginkel CG, Kolvenbach M (1991) Relations between the structure of quaternary alkylammonium salts and their biodegradability. Chemosphere 23:281–289CrossRef Van Ginkel CG, Kolvenbach M (1991) Relations between the structure of quaternary alkylammonium salts and their biodegradability. Chemosphere 23:281–289CrossRef
go back to reference Venkatasamy R, Okwara DN (2005) The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication. International Research Group on Wood Protection, Document No. IRG/WP 03-50203 Venkatasamy R, Okwara DN (2005) The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication. International Research Group on Wood Protection, Document No. IRG/WP 03-50203
go back to reference Warner JE, Solomon KR (1990) Acidity as a factor in leaching of copper, chromium and arsenic from CCA-treated dimension lumber. Environ Toxicol Chem 9:1331–1337CrossRef Warner JE, Solomon KR (1990) Acidity as a factor in leaching of copper, chromium and arsenic from CCA-treated dimension lumber. Environ Toxicol Chem 9:1331–1337CrossRef
go back to reference Yanai H (2004) Statcel-The useful add-in software forms on Excel, 2nd edn. OMS, Tokyo Yanai H (2004) Statcel-The useful add-in software forms on Excel, 2nd edn. OMS, Tokyo
go back to reference Yee MM, Miyajima T, Takisawa N (2006) Evaluation of amphiphilic properties of fulvic acid and humic acid by alkylpyridinium binding study. Colloid Surf A 272:182–188CrossRef Yee MM, Miyajima T, Takisawa N (2006) Evaluation of amphiphilic properties of fulvic acid and humic acid by alkylpyridinium binding study. Colloid Surf A 272:182–188CrossRef
go back to reference Zabielska-Matejuk J (2005) The influence of cation and anion structure of new quaternary ammonium salts on adsorption and leaching. Holzforschung 59:190–198CrossRef Zabielska-Matejuk J (2005) The influence of cation and anion structure of new quaternary ammonium salts on adsorption and leaching. Holzforschung 59:190–198CrossRef
Metadata
Title
Leaching behaviour of benzalkonium chloride homologues in soil and water solutions
Authors
Teruhisa Miyauchi
Mitsunori Mori
Publication date
01-07-2013
Publisher
Springer-Verlag
Published in
Wood Science and Technology / Issue 4/2013
Print ISSN: 0043-7719
Electronic ISSN: 1432-5225
DOI
https://doi.org/10.1007/s00226-013-0542-y

Other articles of this Issue 4/2013

Wood Science and Technology 4/2013 Go to the issue