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2019 | OriginalPaper | Chapter

4. Lewis Acidic Solutions: H↔H Fragilization

Author : Prof. Dr. Chang Q Sun

Published in: Solvation Dynamics

Publisher: Springer Singapore

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Abstract

Solvation dissolves the HX into an H+ and an X−. The H+ bonds to a H2O to form a firm H3O+ and a H↔H anti − HB point breaker. The H–O bond due H3O+ is 3% shorter and the associated O:H nonbond is 60% longer than normal. The H↔H compression shortens its nearest O:H nonbond by 11% and lengthens the H–O by 4%. The X− point polarizer shortens the H–O bond and stiffens its phonon but relax the O:H nonbond oppositely in the supersolid hydration shell. The X− solute capability of bond transition follows the I > Br > Cl order in the form of fx(C) ∝ 1 − exp(−C/C0) towards saturation because of the involvement of the X−↔X− interaction that weakens the hydration-shell electric field at higher concentrations. However, the H+ neither hops or tunnels freely nor polarize its neighbors, fH(C) = 0. The H↔H has the same effect of heating on the surface stress and solution viscosity disruption.

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previous chapter Theory: Aqueous Charge Injection by Solvation
next chapter Lewis Basic and H2O2 Solutions: O:⇔:O Compression
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Metadata
Title
Lewis Acidic Solutions: H↔H Fragilization
Author
Prof. Dr. Chang Q Sun
Copyright Year
2019
Publisher
Springer Singapore
Book
Solvation Dynamics

Print ISBN: 978-981-13-8440-0

Electronic ISBN: 978-981-13-8441-7

Copyright Year: 2019

DOI
https://doi.org/10.1007/978-981-13-8441-7_4

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