Top

Cellulose

Published in:

02-01-2023 | Original Research

Long-lived luminescence and photochromic cellulose acetate-based fiber: preparation, characterization, and potential applications

Authors: Xiuyu Shen, Qian Hu, Yang Jin, Mingqiao Ge

Published in: Cellulose | Issue 4/2023

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Persistent luminescent fiber with photochromic properties is highly desirable because of its promising applications in smart textiles. However, to our knowledge, preparing the red persistent luminescent fiber with photochromic performance via a facile method has not been investigated. Herein, we report a facile one-step wet spinning method to fabricate red persistent luminous fiber with reversible photochromic performance, by integrating the red luminescent Y₂O₂S:Eu³⁺, Mg²⁺, Ti⁴⁺ phosphor and spiropyran dye into the cellulose acetate (CA) matrix (LPCA). The phosphor and dye are distributed in the LPCA fiber uniformly. The as-synthesized fiber presented reversible and quick photochromic performance with good fatigue resistance for more than 80 cycles. Besides, the LPCA fiber exhibits excellent red persistent luminescence properties after excitation. In particular, the addition of spiropyran dye enhances the luminous color purity of LPCA fiber from 88.81 to 92.3% compared with luminescent CA fiber. In contrast with previously reported luminous fiber that needed a complicated and rigorous fabrication process, the as-prepared fiber can be fabricated with a facile method and exhibits promising applications for smart textile and information encryption.

previous article Preparation and characterization of oxidized pectin/N-succinyl chitosan/graphene oxide hydrogels

next article Creep and stress relaxation behavior of functionalized microcrystalline cellulose/epoxy composites

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Abdollahi A, Mouraki A, Sharifian MH, Mahdavian AR (2018) Photochromic properties of stimuli-responsive cellulosic papers modified by spiropyran-acrylic copolymer in reusable pH-sensors. Carbohyd Polym 200:583–594. https://doi.org/10.1016/j.carbpol.2018.08.042CrossRef

Chen B, Jiang T, Fu H et al (2021) Ultrasensitive, rapid and selective sensing of hazardous fluoride ion in aqueous solution using a zirconium porphyrinic luminescent metal-organic framework. Anal Chim Acta 1145:95–102. https://doi.org/10.1016/j.aca.2020.11.007CrossRefPubMed

Cui C, Jiang G, Huang P et al (2014) Synthesis and characterization of Y₂O₂S:Eu³⁺, Mg²⁺, Ti⁴⁺ nanotubes via hydrothermal method. J Lumin 145:665–668. https://doi.org/10.1016/j.jlumin.2013.08.055CrossRef

Deng S, Xue Z, Liu Y et al (2012) Synthesis and characterization of Y₂O₂S:Eu³⁺, Mg²⁺, Ti⁴⁺ hollow nanospheres via a template-free route. J Alloys Compd 542:207–212. https://doi.org/10.1016/j.jallcom.2012.07.060CrossRef

Dong K, Deng J, Zi Y et al (2017) 3D orthogonal woven triboelectric nanogenerator for effective biomechanical energy harvesting and as self-powered active motion sensors. Adv Mater 29:1702648. https://doi.org/10.1002/adma.201702648CrossRef

Fan J, Bao B, Wang Z et al (2020) High tri-stimulus response photochromic cotton fabrics based on spiropyran dye by thiol-ene click chemistry. Cellulose 27:493–510. https://doi.org/10.1007/s10570-019-02786-2CrossRef

Fang X, Duan D, Ye J, Li K (2021) A sensitive visual detection of thiamethoxam based on fluorescence resonance energy transfer from NH₂–SiO₂@CsPbBr₃ to merocyanine configuration of spiropyran. Anal Chim Acta 1183:338938. https://doi.org/10.1016/j.aca.2021.338938CrossRefPubMed

Gao W, Ge W, Shi J et al (2021) Stretchable, flexible, and transparent SrAl₂O₄:Eu2+@TPU ultraviolet stimulated anti-counterfeiting film. Chem Eng J 405:126949. https://doi.org/10.1016/j.cej.2020.126949CrossRef

Ge F, Yu W, Yin Y, Wang C (2021) Solar-driven thermochromic fabric based on photothermal conversion for light intensity monitoring. J Mater Chem A 9:20565–20575. https://doi.org/10.1039/D1TA04073ACrossRef

Hu W, Liu S, Chen S, Wang H (2011) Preparation and properties of photochromic bacterial cellulose nanofibrous membranes. Cellulose 18:655–661. https://doi.org/10.1007/s10570-011-9520-4CrossRef

Huo J, Yu A, Ni Q et al (2020) Efficient energy transfer from trap levels to Eu3+ leads to antithermal quenching effect in high-power white light-emitting diodes. Inorg Chem 59:15514–15525. https://doi.org/10.1021/acs.inorgchem.0c02541CrossRefPubMed

Karimipour K, Keyvan Rad J, Ghomi AR et al (2020) Hydrochromic and photoswitchable polyacrylic nanofibers containing spiropyran in eco-friendly ink-free rewriteable sheets with responsivity to humidity. Dyes Pigments 175:108185. https://doi.org/10.1016/j.dyepig.2020.108185CrossRef

Li J, Huang X, Zhao X et al (2021a) pH-responsive torpedo-like persistent luminescence nanoparticles for autofluorescence-free biosensing and high-level information encryption. Angew Chem Int Ed 60:2398–2405. https://doi.org/10.1002/anie.202011553CrossRef

Li Y, Jiang J, Lv Q et al (2021b) Structural and spectroscopic features of high color purity red-emitting phosphors Sr19Mg2(PO4)14: Re3+ (Re3+= Eu3+, Sm3+, Pr3+). Spectrochim Acta Part A Mol Biomol Spectrosc 251:119417. https://doi.org/10.1016/j.saa.2020.119417CrossRef

Lin S, Gutierrez-Cuevas KG, Zhang X et al (2021) Fluorescent photochromic α-cyanodiarylethene molecular switches: an emerging and promising class of functional diarylethene. Adv Func Mater 31:2007957. https://doi.org/10.1002/adfm.202007957CrossRef

Lin Z, Pan H, Tian Y et al (2022) Photo-pH dual stimuli-responsive multicolor fluorescent polymeric nanoparticles for multicolor security ink, optical data encryption and zebrafish imaging. Dyes Pigments 205:110588. https://doi.org/10.1016/j.dyepig.2022.110588CrossRef

Liu X, Jin X, Li L et al (2020) Air-permeable, multifunctional, dual-energy-driven MXene-decorated polymeric textile-based wearable heaters with exceptional electrothermal and photothermal conversion performance. J Mater Chem A 8:12526–12537. https://doi.org/10.1039/D0TA03048ACrossRef

Lu Y, Zhao J, Zhang R et al (2014) Tunable lifetime multiplexing using luminescent nanocrystals. Nat Photon 8:32–36. https://doi.org/10.1038/nphoton.2013.322CrossRef

Luo Q, Qin L, Zhang P et al (2022) A persistent luminescent nanobeacon for practical detection of lead ions via avoiding background interference. Anal Chim Acta 1198:339555. https://doi.org/10.1016/j.aca.2022.339555CrossRefPubMed

Peng H, Sun X, Cai F et al (2009) Electrochromatic carbon nanotube/polydiacetylene nanocomposite fibres. Nat Nanotech 4:738–741. https://doi.org/10.1038/nnano.2009.264CrossRef

Pugachev AD, Ozhogin IV, Makarova NI et al (2022) Novel polychromogenic fluorine-substituted spiropyrans demonstrating either uni- or bidirectional photochromism as multipurpose molecular switches. Dyes Pigments 199:110043. https://doi.org/10.1016/j.dyepig.2021.110043CrossRef

Qu B, Wang J, Liu K et al (2019) A comprehensive study of the red persistent luminescence mechanism of Y2O2S:Eu, Ti, Mg. Phys Chem Chem Phys 21:25118–25125. https://doi.org/10.1039/C9CP04622DCrossRefPubMed

Rossi S, Simeoni M, Quaranta A (2021) Behavior of chromogenic pigments and influence of binder in organic smart coatings. Dyes Pigments 184:108879. https://doi.org/10.1016/j.dyepig.2020.108879CrossRef

Shen X, Hu Q, Akbarzadeh A et al (2021) Multi-stimuli-responsive composite fibers based on luminescent ceramics for UV/heat detection and anti-counterfeiting. J Mater Chem C 9:15175–15188. https://doi.org/10.1039/D1TC03403KCrossRef

Shen X, Hu Q, Jin Y et al (2022) Tunable full-color emission phosphors: Enhanced security application via a patterned 3-dimensions code. Ceram Int. https://doi.org/10.1016/j.ceramint.2022.08.349CrossRef

Shi M, Lu B, Li X et al (2021) Thermochromic luminescent fiber based on yellow thermochromic microcapsules: preparation, properties, and potential application areas. Cellulose 28:5005–5018. https://doi.org/10.1007/s10570-021-03858-yCrossRef

Subaihi A, Al-Qahtani SD, Attar RMS et al (2022) Preparation of fluorescent cotton fibers with antimicrobial activity using lanthanide-doped pigments. Cellulose 29:6393–6404. https://doi.org/10.1007/s10570-022-04665-9CrossRef

Tian W, Zhang J, Yu J et al (2018) Phototunable full-color emission of cellulose-based dynamic fluorescent materials. Adv Func Mater 28:1703548. https://doi.org/10.1002/adfm.201703548CrossRef

Wang L, Fu X, He J et al (2020) Application challenges in fiber and textile electronics. Adv Mater 32:1901971. https://doi.org/10.1002/adma.201901971CrossRef

Wang H, Qian X, An X (2022) Introducing lanthanide metal–organic framework and perovskite onto pulp fibers for fluorescent anti-counterfeiting and encryption. Cellulose 29:1115–1127. https://doi.org/10.1007/s10570-021-04331-6CrossRef

Wei Y, Zhang W, Hou C et al (2021) Independent dual-responsive Janus chromic fibers. Sci China Mater 64:1770–1779. https://doi.org/10.1007/s40843-020-1563-yCrossRef

Wu R-J, Hsu Y-L, Chou W-Y, Cheng H-L (2021) Enhancing functionalities of organic ultraviolet-visible phototransistors incorporating spiropyran-merocyanine photochromic materials. J Mater Chem A 9:22522–22532. https://doi.org/10.1039/D1TA05707CCrossRef

Xu J, Tanabe S (2019) Persistent luminescence instead of phosphorescence: History, mechanism, and perspective. J Lumin 205:581–620. https://doi.org/10.1016/j.jlumin.2018.09.047CrossRef

Xu Y, Sheng J, Yin X et al (2017) Functional modification of breathable polyacrylonitrile/polyurethane/TiO₂ nanofibrous membranes with robust ultraviolet resistant and waterproof performance. J Colloid Interface Sci 508:508–516. https://doi.org/10.1016/j.jcis.2017.08.055CrossRefPubMed

Xue H, Ge M, Zhu Y (2021) Preparation and properties research of a warm tone luminous polyacrylonitrile coaxial fiber based on SrAl₂O₄ phosphor. J Lumin 231:117777. https://doi.org/10.1016/j.jlumin.2020.117777CrossRef

Yang Z, Du J, Martin LIDJ et al (2021) Designing photochromic materials with large luminescence modulation and strong photochromic efficiency for dual-mode rewritable optical storage. Adv Opt Mater 9:2100669. https://doi.org/10.1002/adom.202100669CrossRef

Zhang X, Hou L, Samorì P (2016) Coupling carbon nanomaterials with photochromic molecules for the generation of optically responsive materials. Nat Commun 7:11118. https://doi.org/10.1038/ncomms11118CrossRefPubMedPubMedCentral

Zhang L, Lyu S, Zhang Q et al (2019) Dual-emitting film with cellulose nanocrystal-assisted carbon dots grafted SrAl2O4, Eu2+, Dy3+ phosphors for temperature sensing. Carbohyd Polym 206:767–777. https://doi.org/10.1016/j.carbpol.2018.11.031CrossRef

Zhu Y, Lu B, Ge M (2021) The effect of acid and alkali treatment on the luminous properties of red luminous material: Sr2MgSi2O7:Eu2+, Dy3+/light conversion agent. Optoelectron Adv Mater Rapid Commun 15:169–175

Title: Long-lived luminescence and photochromic cellulose acetate-based fiber: preparation, characterization, and potential applications
Authors: Xiuyu Shen
Qian Hu
Yang Jin
Mingqiao Ge
Publication date: 02-01-2023
Publisher: Springer Netherlands
Published in: Cellulose / Issue 4/2023
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-05034-2

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 4/2023

Optimization of the regioselective synthesis of mixed cellulose 3,5-dimethylphenyl and α-phenylethyl carbamate selectors as separation phases for chiral HPLC

Preparation of porous microcrystalline cellulose from mezcal industry agave bagasse by low reagent loading sequential chemical treatment

Water-insoluble and soluble glucuronoxylans from eucalyptus pulp and their behavior in alkaline pulping

Fabrication of food-safe, degradable and high-barrier air frying paper by chitosan, zein and LCNF coatings

Fabrication of multidimensional bio-nanomaterials from nanocellulose oxalate

Effect of biobased plasticizers, used as dispersing aids, on mechanical, rheological and thermal properties of micro fibrillated cellulose (MFC)/poly (lactic acid) (PLA) biocomposites over the time: how MFC controls the plasticizer migration?