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Shape Memory and Superelasticity
Published in: Shape Memory and Superelasticity 4/2017

27-10-2017 | SPECIAL ISSUE: A TRIBUTE TO PROF. SHUICHI MIYAZAKI – FROM FUNDAMENTALS TO APPLICATIONS, INVITED PAPER

Martensitic Transformation and Superelasticity in Fe–Mn–Al-Based Shape Memory Alloys

Authors: Toshihiro Omori, Ryosuke Kainuma

Published in: Shape Memory and Superelasticity | Issue 4/2017

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Abstract

Ferrous shape memory alloys showing superelasticity have recently been obtained in two alloy systems in the 2010s. One is Fe–Mn–Al–Ni, which undergoes martensitic transformation (MT) between the α (bcc) parent and γ′ (fcc) martensite phases. This MT can be thermodynamically understood by considering the magnetic contribution to the Gibbs energy, and the β-NiAl (B2) nanoprecipitates play an important role in the thermoelastic MT. The temperature dependence of critical stress for the MT is very small (about 0.5 MPa/°C) due to the small entropy difference between the parent and martensite phases in the Fe–Mn–Al–Ni alloy, and consequently, superelasticity can be obtained in a wide temperature range from cryogenic temperature to about 200 °C. Microstructural control is of great importance for obtaining superelasticity, and the relative grain size is among the most crucial factors.
previous article Effect of Cooling Rates on the Transformation Behavior and Mechanical Properties of a Ni-Rich NiTi Alloy
next article Cyclic Degradation Behavior of -Oriented Fe–Mn–Al–Ni Single Crystals in Tension

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Metadata
Title
Martensitic Transformation and Superelasticity in Fe–Mn–Al-Based Shape Memory Alloys
Authors
Toshihiro Omori
Ryosuke Kainuma
Publication date
27-10-2017
Publisher
Springer International Publishing
Published in
Shape Memory and Superelasticity / Issue 4/2017
Print ISSN: 2199-384X
Electronic ISSN: 2199-3858
DOI
https://doi.org/10.1007/s40830-017-0129-9

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