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Physics of Metals and Metallography

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01-03-2021 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Mechanism of the Oxidation of Phases in Heat-Resistant Alloys of the Fe–25Cr–35Ni System

Authors: A. I. Rudskoi, S. Yu. Kondrat’ev, G. P. Anastasiadi, A. V. Tsemenko

Published in: Physics of Metals and Metallography | Issue 3/2021

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Abstract

Using electron microscopy methods, the mechanism and kinetics of the evolution of the microstructure and phase composition of the surface diffusion zone of a cast heat–resistant alloy of the Fe–25Cr–35Ni system have been studied under conditions of long–term high–temperature exposure to an oxidizing atmosphere. The chemical compositions of the phases continuously change during alloy oxidation in accordance with complex laws depending on the environment, temperature, and exposure duration; moreover, each phase is involved in a unique oxidation process. A rigorous exchange of chemical elements takes place between the various phases. After prolonged exposure of the alloy to high temperatures, the process of phase oxidation likely reaches a stable limiting state. The obtained results are compared with those known from the review of publications on the topic.

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D. J. Tillack and J. E. Guthrie, “Wrought and Cast Heat-Resistant Stainless Steels and Nickel Alloys for the Refining and Petrochemical Industries,” in Nickel Development Institute (Technical Series, Toronto, 1998), No. 10, pp. 71–85.

A. A. Kaya, P. Krauklis, and D. J. Young, “Microstructure of HK40 alloy after high-temperature service in oxidizing/carburizing environment: I. Oxidation phenomena,” Mater. Charact. 49, No. 1, 11–21 (2002).CrossRef

A. A. Kaya, “Microstructure of HK40 alloy after high–temperature service in oxidizing/carburizing environment: II. Carburization,” Mater. Charact. 49, No. 1, 23–34 (2002).CrossRef

E. A. Kenik, P. J. Maziasz, R. W. Swindeman, J. Cervenka, and D. May, “Structure and phase stability in cast modified-HP austenite after long-term ageing,” Scr. Mater. 49, 117–122 (2003).CrossRef

L. H. De Almeida, A. F. Ribeiro, and I. Le May, “Microstructural characterization of modified 25Cr–35Ni centrifugally cast steel furnace tubes,” Mater. Charact. 49, 219–229 (2003).CrossRef

A. Ul-Hamid, H. M. Tawancy, A.-R. I. Mohammed, and N. M. Abbas, “Failure analysis of furnace radiant tubes exposed to excessive temperature,” Eng. Failure Anal. 13, 1005–1021 (2006).CrossRef

H. M. Tawancy, A. Ul-Hamid, A. I. Mohammed, and N. M. Abbas, “Effect of materials selection and design on the performance of an engineering product – An example from petrochemical industry,” Mater. Des. 28, 686–703 (2007).CrossRef

F. C. Nunes, L. H. De Almeida, J. Dille, J.-L. Delplancke, and I. Le May, “Microstructural changes caused by yttrium addition to NbTi-modified centrifugally cast HP-type stainless steels,” Mater. Charact. 58, 132–142 (2007).CrossRef

A. Alvino, D. Lega, F. Giacobbe, V. Mazzocchi, and A. Rinaldi, “Damage characterization in two reformer heater tubes after 10 years of service at different operative and maintenance conditions,” Eng. Failure Anal. 17, 1526–1541 (2010).CrossRef

10.

M. Garbiak, W. Jasiňski, and B. Piekarski, “Materials for reformer furnace tubes. History of evolution,” Arch. Foundry Eng. 11, 47–52 (2011).

11.

Y. Jingbo, G. Yimin, Y. Fang, Y. Caiying, Y. Zhaozhong, Y. Dawei, and M. Shengqiang, “Effect of tungsten on the microstructure evolution and mechanical properties of yttrium modified HP40Nb alloy,” Mater. Sci. Eng., A 529, 361–369 (2011).CrossRef

12.

Z. Zhu, C. Cheng, J. Zhao, and L. Wang, “High temperature corrosion and microstructure deterioration of KHR35H radiant tubes in continuous annealing furnace,” Eng. Failure Anal. 21, 59–66 (2012).CrossRef

13.

S. Borjali, S. R. Allahkaram, and H. Khosravi, “Effects of working temperature on the microstructure of high pressure heat-resistant stainless steel tubes used in pyrolysis furnaces during service condition,” Mater. Des. 34, 65–73 (2012).CrossRef

14.

A. I. Rudskoy, A. S. Oryshchenko, S. Yu. Kondrat’ev, G. P. Anastasiadi, M. D. Fuks, and S. N. Petrov, “Special features of structure and long-term strength of cast refractory alloy 45Kh26N33S2B2,” Met. Sci. Heat Treat. 55, Nos. 3–4, 209–215 (2013).CrossRef

15.

L. S. Monobe and C. G. Schön, “Microstructural and fractographic investigation of cast 20Cr32Ni + Nb alloy tube in the ̀as cast́ and aged states,” J. Mater. Res. Technol. 2, No. 2, 195–201 (2013).CrossRef

16.

A. I. Rudskoy, A. Yu. Kondrat’ev, G. P. Anastasiadi, A. S. Oryshchenko, M. D. Fuks, and S. N. Petrov, “Transformation of the structure of refractory alloy 0.45C–26Cr–33Ni–2Si–2Nb during a long–term high–temperature hold,” Met. Sci. Heat Treat. 55, Nos. 9–10, 517–525 (2014).CrossRef

17.

L. Bonaccorsi, E. Guglielmino, E. Pino, C. Servetto, and A. Sili, “Damage analysis in Fe–Cr–Ni centrifugally cast alloy tubes for reforming furnaces,” Eng. Failure Anal. 36, 65–74 (2014).CrossRef

18.

A. I. Rudskoy, A. S. Oryshchenko, S. Yu. Kondrat’ev, G. P. Anastasiadi, and M. D. Fuks, “Mechanisms and kinetics of phase transformations in refractory alloy 45Kh26N33S2B2 in long-term high-temperature holds Part 1,” Met. Sci. Heat Treat. 56, Nos. 1–2, 3–8 (2014).CrossRef

19.

A. I. Rudskoy, S. Yu. Kondrat’ev, G. P. Anastasiadi, A. S. Oryshchenko, and M. D. Fuks, “Mechanism and kinetics of phase transformations in refractory alloy 45Kh26N33S2B2 under long-term high-temperature holds. Part 2,” Met. Sci. Heat Treat. 56, Nos. 3–4, 124–130 (2014).CrossRef

20.

K. G. Buchanan and M. V. Kral, “Crystallography and morphology of niobium carbide in as-cast HP-niobium reformer tubes,” Metall. Mater. Trans. A 43, No. 6, 1760–1769 (2012).CrossRef

21.

K. G. Buchanan, M. V. Kral, and C. M. Bishop, “Crystallography and morphology of MC carbides in niobium–titanium modified as-cast HP alloys,” Metall. Mater. Trans. A 45, No. 8, 3373–3385 (2014).CrossRef

22.

A. I. Rudskoy, G. P. Anastasiadi, S. Yu. Kondrat’ev, A. S. Oryshchenko, and M. D. Fuks, “Effect of electron factor (number of electron holes) on kinetics of nucleation, growth, and dissolution of phases during long–term high–temperature holdings of 0.45C–26Cr–33Ni–2Si–2Nb superalloy,” Phys. Met. Metallogr. 115, No. 1, 1–11 (2014).CrossRef

23.

T. Sourmail, “Precipitates in creep resistant austenitic stainless steels,” Mater. Sci. Technol. 17, No. 1, 1–14 (2001).CrossRef

24.

M. Garbiak and R. Chyliňska, “Precipitation kinetics in austenitic 18Cr–30Ni–Nb cast steel,” Arch. Foundry Eng. 8, No. 3, 27–30 (2008).

25.

G. F. Voort Vander, G. M. Lucas, and E. P. Manilova, “Metallography and microstructures of heat-resistant alloys,” In Metallography and Microstructures, Ed. by J. R. Davis, Davis & Associates (ASM International ASM Handbook, 2004), Vol. 9, pp. 820–859.

26.

R. A. P. Ibanez, SoaresG. D. De Almeida, L. H. De Almeida, and I. Le May, “Effects of Si content on the microstructure of modified-HP austenitic steels,” Mater. Charact. 30, 243–249 (1993).CrossRef

27.

G. P. Anastasiadi, S. Yu. Kondrat’ev, and A. I. Rudskoy, “Selective high-temperature oxidation of phases in a cast refractory alloy of the 25Cr–35Ni–Si–Nb–C system,” Met. Sci. Heat Treat. 56, 403–408 (2014).CrossRef

28.

S. Yu. Kondrat’ev, G. P. Anastasiadi, and A. I. Rudskoy, “Nanostructure mechanism of formation of oxide film in heat-resistant Fe–25Cr–35Ni superalloys,” Met. Sci. Heat Treat. 56, Nos. 9–10, 531–536 (2015).CrossRef

29.

N. McIntyre, N. Chan, and C. Chen, “Characterization of oxide structures formed on nickel–chromium alloy during low pressure oxidation at 500–600°C,” Oxid. Met. 33, Nos. 5–6, 458–479 (1990).CrossRef

30.

A. Yu. Ishlinskii, New Polytechnic Dictionary (Bol’shaya Rossiiskaya entsiklopediya, Moscow, 2000) [in Russian].

31.

A. N. Bugrov and O. V. Al’myasheva, “Formation of Cr₂O₃ nanoparticles under hydrothermal conditions,” Nanosistemy: Fizika, Khimiya, Matematika 2, No. 4, 126–132 (2011).

32.

S. Yu. Kondrat’ev, E. V. Sviatysheva, G. P. Anastasiadi, and S. N. Petrov, “Fragmented structure of niobium carbide particles in as–cast modified HP alloys,” Acta Mater. 127, 267–276 (2017).CrossRef

33.

I. P. Fedorov, Chemical Handbook. Vol. 5. Chromium Oxides (Bol’shaya Rossiiskaya Entsiklopediya, 1991), pp. 311–313 (1999).

34.

R. Zapała and B. Kalandyk, “Identification of scale formed on Cr–Ni cast steel,” Arch. Foundry Eng. 10, No. 4, 217–220 (2010).

35.

R. Voicu, E. Andrieu, D. Poquillon, J. Furtado, and J. Lacaze, “Microstructure evolution of HP40–Nb alloys during aging under air at 1000°C,” Mater. Charact. 60, No. 9, 1020–1027 (2009).CrossRef

36.

S. Yu. Kondrat’ev, A. V. Ptashnik, G. P. Anastasiadi, and S. N. Petrov, “Analysis of transformations of carbide phases in alloy 25Cr35Ni by the method of quantitative electron microscopy,” Met. Sci. Heat Treat. 57, Nos. 7–8, 402–409 (2015).CrossRef

37.

L. H. Koopmans, D. B. Owen, and J. I. Rosenblatt, “Confidence intervals for the coefficient of variation for normal and log normal distributions,” Biometrika 51, 25–32 (1964).CrossRef

38.

J. K. Patel, N. M. Patel, and R. L. Shiyani, “Coefficient of variation in field experiments and yardstick thereof – An empirical study,” Curr. Sci. 81, Nos. 9–10, 1163–1164 (2001).

39.

R. F. Voitovich and É. A. Pugach, “High-temperature oxidation characteristics of the carbides of the Group VI transition metals,” Powder Metall. Met. Ceram. 12, 314–318 (1973).CrossRef

40.

A. M. Babakr, A. Al-Ahmari, K. Al-Jumayiah, and F. Habiby, “Sigma Phase formation and embrittlement of cast iron–chromium–nickel (Fe–Cr–Ni) alloys,” J. Miner. Mater. Charact. Eng. 7, 127–145 (2008).

41.

S. Y. Kondrat’ev, G. P. Anastasiadi, S. N. Petrov, and A. V. Ptashnik, “Kinetics of the formation of intermetallic phases in HP-type heat-resistant alloys at long-term high-temperature exposure,” Metall. Mater. Trans. A 48, 482–492 (2017).CrossRef

Title: Mechanism of the Oxidation of Phases in Heat-Resistant Alloys of the Fe–25Cr–35Ni System
Authors: A. I. Rudskoi
S. Yu. Kondrat’ev
G. P. Anastasiadi
A. V. Tsemenko
Publication date: 01-03-2021
Publisher: Pleiades Publishing
Published in: Physics of Metals and Metallography / Issue 3/2021
Print ISSN: 0031-918X
Electronic ISSN: 1555-6190
DOI: https://doi.org/10.1134/S0031918X21030133

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