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01-06-2015 | Original Article | Issue 11/2015

Environmental Earth Sciences 11/2015

Mechanochemical treatment and structural properties of lead adsorption on kaolinite (Rudovci, Serbia)

Journal:
Environmental Earth Sciences > Issue 11/2015
Authors:
Snežana S. Nenadović, Ljiljana M. Kljajević, Miloš T. Nenadović, Miljana M. Mirković, Smilja B. Marković, Zlatko Lj. Rakočević

Abstract

In the present work, remediation of lead-containing solution using raw and modified kaolinite has been presented. The micro and nanostructure of samples has been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). Laser diffraction and scattering (LDS), was analyzed by particle size analyzer based on laser diffraction and particle size distribution (PSD) was done. The degree of metal adsorption was evaluated analyzing the Pb(II) contaminated samples by inductively coupled plasma atomic emission spectrometry (micro- and nanostructure on immobilization efficiency correlCP AES). The results show the impact of immobilization efficiency and ation between micro- and nanostructure. The thermodynamic data (ΔH°, ΔS°, ΔG°) are calculated from the temperature-dependent sorption isotherms. The results suggest sorption process of Pb(II) on kaolinite as spontaneous and endothermic.

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