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Published in: Journal of Coatings Technology and Research 5/2020

06-05-2020

Michael addition curable coatings from renewable resources with enhanced adhesion performance

Authors: Bart Noordover, William Liu, Eric McCracken, Bill DeGooyer, Richard Brinkhuis, Florian Lunzer

Published in: Journal of Coatings Technology and Research | Issue 5/2020

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Abstract

Novel malonate-functional polyesters from biobased and potentially biobased monomers were developed and cured through the base-catalyzed carbon-Michael addition reaction with acryloyl-functional oligomers. Both drop-in monomers, such as fully biobased diethyl malonate, and alternative raw materials, such as isosorbide and vegetable oil, were introduced. Isosorbide-based polyesters show improved performance to humidity in terms of adhesion on epoxy-amine primer, while vegetable oil-containing resins lead to improved coating appearance due to better flow and levelling. This study demonstrates that biobased malonate resins, having renewable contents up to 53%, offer attractive performance benefits in 2K RMA paints. It is anticipated that, with the development of additional fully biobased polyols, renewable contents in excess of 80% can be achieved.

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Metadata
Title
Michael addition curable coatings from renewable resources with enhanced adhesion performance
Authors
Bart Noordover
William Liu
Eric McCracken
Bill DeGooyer
Richard Brinkhuis
Florian Lunzer
Publication date
06-05-2020
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 5/2020
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-020-00351-2

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