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2013 | OriginalPaper | Chapter

Microstructure and Properties of Nanostructured Calcium Phosphate/Titania Porous Coatings via Micro Arc Oxidation

Authors : Sakine Abbasi, Hamid Reza Rezaie, Farhad Golestani-Fard

Published in: Characterization and Development of Biosystems and Biomaterials

Publisher: Springer Berlin Heidelberg

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Abstract

Crystalline Calcium Phosphate-TiO2 nanostructured porous layers were fabricated via micro arc oxidation technique under different times to investigate how growth time effects on morphology, topography, phase structure, and chemical composition of the layers. Considering the SEM and AFM observations, the layers showed a porous morphology with a rough surface where the pores size increased with time. The highest porosity and roughness was achieved at intermediate times. XRD technique revealed that the layers consisted of α-Tri Calcium Phosphate (α-TCP), hydroxyapatite (HAp), anatase, and calcium titanate phases. It was observed that the HAp relative content reached its maximum value at intermediate times. It was found that the HAp phase gradually forms over a TiO2 inner layer during the MAO growth. Based on XRD patterns, the α-TCP and HAp crystalline sizes were determined as ~32.4 and ~27.7 nm, respectively.

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Metadata
Title
Microstructure and Properties of Nanostructured Calcium Phosphate/Titania Porous Coatings via Micro Arc Oxidation
Authors
Sakine Abbasi
Hamid Reza Rezaie
Farhad Golestani-Fard
Copyright Year
2013
Publisher
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-642-31470-4_17

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