Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 6/2016

10-05-2016

Microstructure and Scratch Resistance of TaC Dense Ceramic Layer on an Iron Matrix

Authors: Nana Zhao, Yunhua Xu, Lisheng Zhong, Honghua Yan, Vladimir E. Ovcharenko

Published in: Journal of Materials Engineering and Performance | Issue 6/2016

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A tantalum carbide dense ceramic layer with a thickness of ~20 μm was produced on the surface of an iron matrix using an in situ technique. The morphology, microstructure, and phase composition of the layer were characterized by means of SEM, TEM, and XRD. The results show fairly agglomerated and uniformly sized (~200 nm) TaC particulates with a face-cantered cubic structure. The values of nano-hardness for the surface and cross section of reinforcing layer can be as high as 29.5 ± 0.6 and 26.7 ± 0.1 GPa, respectively, which were analyzed using a nano-indentation apparatus. Moreover, the scratch resistance of the layer was measured by scratch tests under a progressively increasing load of 0-100 N. A high critical load of 90.4 N is obtained. It is worthy to note that there are only cracking, slight splitting, and small flaking pits (even at the maximum load) all over the whole scratch process, namely the reinforcing layer can protect the iron matrix from serious abrasion effectively. In addition, the excellent scratch resistance and mechanism are discussed in detail.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference R.W. Bartlett and C.W. Smith, Elastic Constants of Tantalum Monocarbide TaC0.90, J. Appl. Polym. Sci., 1967, 38, p 5428–5429 R.W. Bartlett and C.W. Smith, Elastic Constants of Tantalum Monocarbide TaC0.90, J. Appl. Polym. Sci., 1967, 38, p 5428–5429
2.
go back to reference S.A. Shvab and F.F. Egorov, Structure and Some Properties of Sintered Tantalum Carbide, Sov. Powder Metall. Metal Ceram., 1982, 21, p 894–897CrossRef S.A. Shvab and F.F. Egorov, Structure and Some Properties of Sintered Tantalum Carbide, Sov. Powder Metall. Metal Ceram., 1982, 21, p 894–897CrossRef
3.
go back to reference W.M. Daoush, H.S. Park, K.H. Lee, S.F. Moustafa, and S.H. Hong, Effect of Binder Compositions on Microstructure, Hardness and Magnetic Properties of (Ta, Nb)C-Co and (Ta, Nb)C-Ni Cemented Carbides, Int. J. Refract. Met. Hard Mater., 2009, 27, p 669–675CrossRef W.M. Daoush, H.S. Park, K.H. Lee, S.F. Moustafa, and S.H. Hong, Effect of Binder Compositions on Microstructure, Hardness and Magnetic Properties of (Ta, Nb)C-Co and (Ta, Nb)C-Ni Cemented Carbides, Int. J. Refract. Met. Hard Mater., 2009, 27, p 669–675CrossRef
4.
go back to reference M. Desmaison-Brut, N. Alexandre, and J. Desmaison, Comparison of the Oxidation Behaviour of Two Dense Hot Isostatically Pressed Tantalum Carbide (TaC and Ta2C) Materials, J. Exp. Biol., 1997, 17, p 1325–1334 M. Desmaison-Brut, N. Alexandre, and J. Desmaison, Comparison of the Oxidation Behaviour of Two Dense Hot Isostatically Pressed Tantalum Carbide (TaC and Ta2C) Materials, J. Exp. Biol., 1997, 17, p 1325–1334
5.
go back to reference M.J. Chao, W.L. Wang, E.J. Liang, and D.G. Ouyang, Microstructure and Wear Resistance of TaC Reinforced Ni-Based Coating by Laser Cladding, Surf. Coat. Tech., 2008, 202, p 1918–1922CrossRef M.J. Chao, W.L. Wang, E.J. Liang, and D.G. Ouyang, Microstructure and Wear Resistance of TaC Reinforced Ni-Based Coating by Laser Cladding, Surf. Coat. Tech., 2008, 202, p 1918–1922CrossRef
6.
go back to reference Z.Q. Le, S.M. Bo, and G.J. Wang, Handbook of Fine Inorganic Compounds, Chemistry Industry Press, Beijing, 2001, p 874–876 Z.Q. Le, S.M. Bo, and G.J. Wang, Handbook of Fine Inorganic Compounds, Chemistry Industry Press, Beijing, 2001, p 874–876
7.
go back to reference D.H. Kwon, S.H. Hong, and B.K. Kim, Synthesis of Ultrafine TaC-5 wt% Co Composite Powders by the Spray-Carbothermal Process, Mater. Corros., 2005, 93, p 1–5 D.H. Kwon, S.H. Hong, and B.K. Kim, Synthesis of Ultrafine TaC-5 wt% Co Composite Powders by the Spray-Carbothermal Process, Mater. Corros., 2005, 93, p 1–5
8.
go back to reference X.H. Zhang, G.E. Hilmas, and W.G. Fahrenholtz, Densification and Mechanical Properties of TaC-Based Ceramics, Mater. Sci. Eng. A, 2009, 501, p 37–43CrossRef X.H. Zhang, G.E. Hilmas, and W.G. Fahrenholtz, Densification and Mechanical Properties of TaC-Based Ceramics, Mater. Sci. Eng. A, 2009, 501, p 37–43CrossRef
9.
go back to reference G.L. Zhao, C.Z. Huang, H.L. Liu, L. Xu, X.W. Chong, B. Zou, and H.T. Zhu, A Study on In Situ Growth of TaC Whiskers in Al2O3 Matrix Powder for Ceramic Cutting Tools, Mater. Res. Bull., 2012, 47, p 2027–2031CrossRef G.L. Zhao, C.Z. Huang, H.L. Liu, L. Xu, X.W. Chong, B. Zou, and H.T. Zhu, A Study on In Situ Growth of TaC Whiskers in Al2O3 Matrix Powder for Ceramic Cutting Tools, Mater. Res. Bull., 2012, 47, p 2027–2031CrossRef
10.
go back to reference N.N. Zhao, Y.H. Xu, L.S. Zhong, Y.L. Yan, K. Song, L.L. Shen, and V.E. Ovcharenko, Fabrication, Microstructure and Abrasive Wear Characteristics of an In Situ Tantalum Carbide Ceramic Gradient Composite, Ceram. Int., 2015, 41, p 12950–12957CrossRef N.N. Zhao, Y.H. Xu, L.S. Zhong, Y.L. Yan, K. Song, L.L. Shen, and V.E. Ovcharenko, Fabrication, Microstructure and Abrasive Wear Characteristics of an In Situ Tantalum Carbide Ceramic Gradient Composite, Ceram. Int., 2015, 41, p 12950–12957CrossRef
11.
go back to reference E. Sani, L. Mercatelli, D. Fontani, J.L. Sans, and D. Sciti, Hafnium and Tantalum Carbides for High Temperature Solar Receivers, J. Renew. Sustain. Energy, 2011, 3, p 63–107CrossRef E. Sani, L. Mercatelli, D. Fontani, J.L. Sans, and D. Sciti, Hafnium and Tantalum Carbides for High Temperature Solar Receivers, J. Renew. Sustain. Energy, 2011, 3, p 63–107CrossRef
12.
go back to reference Á. Barna, L. Kotis, B. Pécz, A. Sulyok, G. Sáfrán, A.L. Tóth, M. Menyhárd, A. Kovács, and A. Savenko, Thin TaC Layer Produced by Ion Mixing, Surf. Eng., 2012, 206, p 3917–3922 Á. Barna, L. Kotis, B. Pécz, A. Sulyok, G. Sáfrán, A.L. Tóth, M. Menyhárd, A. Kovács, and A. Savenko, Thin TaC Layer Produced by Ion Mixing, Surf. Eng., 2012, 206, p 3917–3922
13.
go back to reference Y. Lon, A. Javed, J. Chen, Z.K. Chen, and X. Xiong, The Effect of Deposition Temperature on the Microstructure and Mechanical Properties of TaC Coatings, Mater. Lett., 2014, 121, p 202–205CrossRef Y. Lon, A. Javed, J. Chen, Z.K. Chen, and X. Xiong, The Effect of Deposition Temperature on the Microstructure and Mechanical Properties of TaC Coatings, Mater. Lett., 2014, 121, p 202–205CrossRef
14.
go back to reference L. Bayarjargal, B. Winkler, A. Friedrich, and E.A. Juarez-Arellano, Synthesis of TaC and Ta2C From Tantalum And Graphite in the Laser-Heated Diamond Anvil Cell, Matter Phys., 2014, 59, p 5283–5289 L. Bayarjargal, B. Winkler, A. Friedrich, and E.A. Juarez-Arellano, Synthesis of TaC and Ta2C From Tantalum And Graphite in the Laser-Heated Diamond Anvil Cell, Matter Phys., 2014, 59, p 5283–5289
15.
go back to reference Y.L. Wang, X. Xiong, G.D. Li, P. Xiao, and Z.K. Chen, Microstructures and Mechanical Properties of Novel C/C-TaC Composite, Chin. J. Nonferrous Met., 2008, 18, p 608–613 Y.L. Wang, X. Xiong, G.D. Li, P. Xiao, and Z.K. Chen, Microstructures and Mechanical Properties of Novel C/C-TaC Composite, Chin. J. Nonferrous Met., 2008, 18, p 608–613
16.
go back to reference M.J. Chao, W.L. Wang, E.J. Liang, and D.X. Ouyang, Microstructure and Wear Resistance of TaC Reinforced Ni-Based Coating by Laser Cladding, Surf. Coat. Technol., 2008, 202, p 1918–1922CrossRef M.J. Chao, W.L. Wang, E.J. Liang, and D.X. Ouyang, Microstructure and Wear Resistance of TaC Reinforced Ni-Based Coating by Laser Cladding, Surf. Coat. Technol., 2008, 202, p 1918–1922CrossRef
17.
go back to reference M. Ali, M. Ürgen, and M.A. Atta, Tantalum Carbide Films Synthesized by Hot-Filament Chemical Vapor Deposition Technique, Surf. Coat. Technol., 2012, 206, p 2833–2838CrossRef M. Ali, M. Ürgen, and M.A. Atta, Tantalum Carbide Films Synthesized by Hot-Filament Chemical Vapor Deposition Technique, Surf. Coat. Technol., 2012, 206, p 2833–2838CrossRef
18.
go back to reference X. Xiang, K.C. Zhao, B.Y. Huang, G.D. Li, F. Zheng, P. Xiao, and H.B. Zhang, Surface Morphology and Preferential Orientation Growth of TaC Crystals Formed by Chemical Vapor Deposition, Thin Solid Films, 2009, 517, p 3235–3239CrossRef X. Xiang, K.C. Zhao, B.Y. Huang, G.D. Li, F. Zheng, P. Xiao, and H.B. Zhang, Surface Morphology and Preferential Orientation Growth of TaC Crystals Formed by Chemical Vapor Deposition, Thin Solid Films, 2009, 517, p 3235–3239CrossRef
19.
go back to reference L. Silvestroni, A. Bellosi, C. Melandri, D. Sciti, J.X. Liu, and G.J. Zhang, Microstructure and Properties of HfC and TaC-Based Ceramics Obtained by Ultrafine Powder, J. Eur. Ceram. Soc., 2011, 31, p 619–627CrossRef L. Silvestroni, A. Bellosi, C. Melandri, D. Sciti, J.X. Liu, and G.J. Zhang, Microstructure and Properties of HfC and TaC-Based Ceramics Obtained by Ultrafine Powder, J. Eur. Ceram. Soc., 2011, 31, p 619–627CrossRef
20.
go back to reference A.X. Fen, Y.K. Zhang, H.K. Xie, M. Zhou, and L. Cai, New Method of Laser Scratching to Determine the Bond Strength of the Film-Substrate Interface, Chin. J. Lasers., 2013, 31, p 329–331 A.X. Fen, Y.K. Zhang, H.K. Xie, M. Zhou, and L. Cai, New Method of Laser Scratching to Determine the Bond Strength of the Film-Substrate Interface, Chin. J. Lasers., 2013, 31, p 329–331
21.
go back to reference D. Nolan, V. Leskovsek, and M. Jenko, Estimation of Fracture Toughness of Nitride Compound Layers on Tool Steel by Application of the Vickers Indentation Method, Surf. Coat. Technol., 2006, 201, p 182–188CrossRef D. Nolan, V. Leskovsek, and M. Jenko, Estimation of Fracture Toughness of Nitride Compound Layers on Tool Steel by Application of the Vickers Indentation Method, Surf. Coat. Technol., 2006, 201, p 182–188CrossRef
22.
go back to reference S.Y. Chang, S.Y. Lin, Y.C. Huang, and C.L. Wu, Mechanical Properties, Deformation Behaviours and Interface Adhesion of (AlCrTaTiZr)Nx Multi-Component Coatings, Surf. Coat. Technol., 2010, 204, p 3307–3314CrossRef S.Y. Chang, S.Y. Lin, Y.C. Huang, and C.L. Wu, Mechanical Properties, Deformation Behaviours and Interface Adhesion of (AlCrTaTiZr)Nx Multi-Component Coatings, Surf. Coat. Technol., 2010, 204, p 3307–3314CrossRef
23.
go back to reference R. Hoy, J.D. Kamminga, and G.C.A.M. Janssen, Scratch Resistance of CrN Coatings on Nitrided Steel, Surf. Coat. Technol., 2006, 200, p 3856–3860CrossRef R. Hoy, J.D. Kamminga, and G.C.A.M. Janssen, Scratch Resistance of CrN Coatings on Nitrided Steel, Surf. Coat. Technol., 2006, 200, p 3856–3860CrossRef
24.
go back to reference F. Yildiz and A. Alsaran, Multi-Pass Scratch Test Behavior of Modified Layer Formed During Plasma Nitriding, Tribol. Int., 2010, 43, p 1472–1478CrossRef F. Yildiz and A. Alsaran, Multi-Pass Scratch Test Behavior of Modified Layer Formed During Plasma Nitriding, Tribol. Int., 2010, 43, p 1472–1478CrossRef
25.
go back to reference K. Wasmer, M. Parlinska-Wojtan, S. Graça, and J. Michler, Sequence of Deformation And Cracking Behaviours of Galliume-arsenide During Nano-Scratching, Mater. Chem. Phys., 2013, 138, p 38–48CrossRef K. Wasmer, M. Parlinska-Wojtan, S. Graça, and J. Michler, Sequence of Deformation And Cracking Behaviours of Galliume-arsenide During Nano-Scratching, Mater. Chem. Phys., 2013, 138, p 38–48CrossRef
26.
go back to reference T. Ishida, The Interaction of Molten Copper with Solid Iron, J. Mater. Sci., 1986, 21, p 1171–1179CrossRef T. Ishida, The Interaction of Molten Copper with Solid Iron, J. Mater. Sci., 1986, 21, p 1171–1179CrossRef
27.
go back to reference C.J. Feng, S.L. Hu, Y.F. Jiang, N.M. Wu, M.S. Li, L. Xin, S.L. Zhu, and F.H. Wang, Effects of Si Content on Microstructure and Mechanical Properties of TiAlN/Si3N4-Cu Nanocomposite Coatings, Appl. Surf. Sci., 2014, 320, p 689–698CrossRef C.J. Feng, S.L. Hu, Y.F. Jiang, N.M. Wu, M.S. Li, L. Xin, S.L. Zhu, and F.H. Wang, Effects of Si Content on Microstructure and Mechanical Properties of TiAlN/Si3N4-Cu Nanocomposite Coatings, Appl. Surf. Sci., 2014, 320, p 689–698CrossRef
28.
go back to reference X.N. Cong, Z.F. Chen, W.P. Wu, J. Xu, and F.E. Boafo, A Novel Ir-Zr Gradient Coating Prepared on Mo Substrate by Double Glow Plasma, Appl. Surf. Sci., 2012, 258, p 5135–5140CrossRef X.N. Cong, Z.F. Chen, W.P. Wu, J. Xu, and F.E. Boafo, A Novel Ir-Zr Gradient Coating Prepared on Mo Substrate by Double Glow Plasma, Appl. Surf. Sci., 2012, 258, p 5135–5140CrossRef
29.
go back to reference S. Hu, Understanding the Fracture Toughness Testing Method and Toughness Evaluation of WC-Co Based Cemented Carbides, Hunan University, Hunan, 2013, p 6–7 S. Hu, Understanding the Fracture Toughness Testing Method and Toughness Evaluation of WC-Co Based Cemented Carbides, Hunan University, Hunan, 2013, p 6–7
Metadata
Title
Microstructure and Scratch Resistance of TaC Dense Ceramic Layer on an Iron Matrix
Authors
Nana Zhao
Yunhua Xu
Lisheng Zhong
Honghua Yan
Vladimir E. Ovcharenko
Publication date
10-05-2016
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 6/2016
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-016-2100-x

Other articles of this Issue 6/2016

Journal of Materials Engineering and Performance 6/2016 Go to the issue

Premium Partners