2006 | OriginalPaper | Chapter
MODELING POROSITY DEVELOPMENT DURING KOH ACTIVATION OF COAL AND PITCH-DERIVED CARBONS FOR ELECTROCHEMICAL CAPACITORS
Authors : Krzysztof Kierzek, Grazyna Gryglewicz, Jacek Machnikowski
Published in: New Carbon Based Materials for Electrochemical Energy Storage Systems: Batteries, Supercapacitors and Fuel Cells
Publisher: Springer Netherlands
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High porosity carbons ranging from typically microporous solids of narrow pore size distribution to materials with over 30% of mesopore contribution were produced by the treatment of various polymeric-type (coal) and carbonaceous (mesophase, semi-cokes, commercial active carbon) precursors with an excess of KOH. The effects related to parent material nature, KOH/precursor ratio and reaction temperature and time on the porosity characteristics and surface chemistry is described. The results are discussed in terms of suitability of produced carbons as an electrode material in electric double-layer capacitors.