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Abstract
The article presents the development of molybdenum oxide (MoO3) reinforced polyvinyl alcohol (PVA) composite as a high-performance dielectric material for flexible electronics. The study focuses on the synthesis and characterization of the composite using green methods, highlighting the improved crystallinity and dielectric properties achieved with the addition of MoO3. The incorporation of MoO3 enhances the interfacial interactions, leading to significant improvements in electrical conductivity and dielectric constant. The composite's potential applications in high-performance energy storage devices are emphasized, making it a valuable contribution to the field of flexible electronics and energy storage materials.
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Abstract
Polymer dielectrics are highlighted as capable energy storing materials due to their better dielectric strength and supreme versatility compared to inorganic ceramic dielectrics in sophisticated electronics and pulsed power systems. The capacity of pristine polymers to store energy, on the other hand, has hardly been constrained by relatively poor internal dielectric properties. This study demonstrates a viable solution-casting method for creating a MoO3 (0%, 1%, 3%, and 5%) doped PVA-based composites for notable dielectric characteristics. The structural variations and morphological properties in the presence of MoO3 nanoparticles within the polymer, connected through intra/intermolecular hydrogen bonding are investigated using XRD and FTIR. The influence of MoO3 content on the complex dielectric properties, conductivities, electric modulus, and impedance parameters of PVA is further investigated. According to the MoO3 proportion in the host matrix, the dielectric properties and relaxation factors associated with polymer cooperative chain segmental migration alter considerably. The improved electrical and dielectric properties of MoO3 doped PVA composite demonstrate its potential in creating compact polymer electrolyte systems.
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1 Introduction
Modern electronics heighten the demand for adaptable, multipurpose, eco-friendly dielectric materials with superior properties. Historically, ceramics were used as dielectric materials; however, it possessed undesirable properties such as brittleness, processing difficulties, and low stability. Polymers have superior flexibility, processability, and light weight when compared to ceramics [1‐3]. And they gained significant interest in science and technology during the last decade as a dielectric or interfacial layer between metals and semiconductors [4]. Among the polymers biodegradable, non-toxic, and hydrophilic ones have specific research interest, as they can be applicable in bio electronics. When such polymer films are made using the solution casting method, they provide better flexibility with improved characteristics [5].
Polyvinyl alcohol (PVA) is widely reported for the preparation of polymer composites because of its good mechanical, chemical and thermal stability, excellent flexibility, and high tensile strength. PVA has a very high dielectric strength and an excellent charge storage capacity, making it widely applicable in various industries [6]. It also has a backbone composed of carbon chains, but rather than methane’s carbon, it possesses hydroxyl groups. These OH groups act as hydrogen bonding sources and thus aid in the production of functionalized composites [7]. Such resilient intra- and intermolecular hydrogen bonds devised by the hydroxyl (–OH) groups result in a variety of useful physicochemical properties, besides superior chemical resistance, exquisite wettability, thermal properties, stretchability, dielectric strength, as well as charge storage capabilities [5]. The high density of hydroxyl groups, also allows cross-linking via irradiation, chemical, or heat treatment. However, water absorption in PVA is one of the most critical elements influencing its characteristics and applications, though the hydrophilicity favors production of composite films. Ion mobility, ion detachment, and increased polymer mechanical strength were noticed by the addition of nano-ceramic due to the significant interfacial interaction around nanoparticles and PVA [8]. The addition of an appropriate filler can customize the electrical characteristics of PVA to a specific requirement. In general, the chemical composition of the filler, distribution in a given polymer and its interaction with the host matrix influence the physical properties of polymers [9]. Therefore, by selecting the appropriate nanofillers, the dielectric characteristics of polymer composites can be efficiently regulated [10].
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As stated in the findings, embedding TiO2 nanoparticles within PVA/CN-Li polymer matrix and doping PVA with graphene oxide promotes electrical conductivity while giving enhanced optical, mechanical, and dielectric properties [11, 12]. According to the literature, pure polymer loaded with nanoparticles offers unique characteristics with diverse uses. When metal oxide nanoparticles are introduced to pure polymer, their characteristics improve dramatically. These compounds are exploited in industry for a variety of purposes, including battery electrodes, display systems, smart windows, lubricants, catalysts, and sensors [13‐16]. In distinction, an n-type molybdenum trioxide (MoO3) semiconductor with a band gap of 3.15 eV is advantageous for a wide range of applications including electro and photochromism, sensors and catalysis, transistors, and portable battery electrodes [17, 18]. Wang et al. [19] studied the dielectric properties of barium titanate-molybdenum composite, prepared using solid state reaction in argon. The prepared composites showed superior dielectric properties and high dielectric constant. The incorporation of molybdenum ions in lead niobium germanosilicate glasses improved the dielectric properties. The distance between the Mo ions decreased with MoO3 concentrations and this reduction increased the chances of electron hopping, subsequently improving the ac conductivity and lowering the activation energy for conduction [20]. Malana et al. [21] also synthesized Molybdenum doped strontium calcium hexagonal ferrites using the sol-gel combustion method, and studied the structural, magnetic and dielectric properties. The dielectric parameters exhibited relaxation behavior in higher frequency region and showed an increasing trend with the molybdenum contents.
In this study, the biopolymer PVA composite containing variable quantities of MoO3 nanoparticles is synthesized by facile calcination treatment. XRD, FTIR, SEM, and impedance analyzer are used to investigate the microstructural, functional, morphological, electrical, and dielectric, characteristics. It is observed that the incorporation of 5 wt% MoO3 into PVA matrix achieved significantly high dielectric constant, suggesting its final application as a separator/ionic transport media in high-performance energy storage devices.
2 Experimental section
2.1 Materials and methods
Pristine Molbdenum (III) oxide powder (99.5%, Sigma-Aldrich) was used as source material. Polyvinyl alcohol (PVA) of molecular weight 78,000 g/mol was purchased from Merck Schuchart, Germany. Ultra-pure Milli- Q water was used as a solvent throughout the study.
2.2 Preparation of MoO3 rods
MoO3 rods were synthesized from commercial Pristine MoO3 powder by using facile calcination treatment and green way. About 2 g of MoO3 was stirred continuously using a magnetic stirrer at 800 rpm for 15 min in 80 mL of deionized (DI) water. The solution was then poured into a 100 ml glass beaker and sonicated for an hour. After sonication, the solution was cleaned, sieved, and dried, in a hot air oven for 5 h at 150 °C. Thereafter the MoO3 nanoparticles were collected.
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2.3 Synthesis of PVA composites
The PVA composites containing MoO3 were synthesized by solution casting. For this, about 2 g of PVA was dissolved in 20 ml distilled water by magnetic stirring (400 rpm) for 5 h at 70 °C. Bath sonication was used to disperse MoO3 in precise weight fractions (1, 3, and 5 wt%) in the same solvent combination (5 ml) for 1 h before mixing with the PVA dispersions. To ensure optimal dispersion, the entire mixture was magnetically agitated overnight. The well-dispersed solution was then casted onto glass petri dish to form thin PVA and PVA/MoO3 composite films.
The obtained films were dried at 80 °C for a few hours to completely remove any residual solvent in a hot air oven. Schematic representation of the composite film fabrication is shown in Fig. 1.
Fig. 1
Schematic diagram for the synthesis process of PVA/MoO3 polymer composite materials
Bruker built an X-ray diffractometer with a 1.540 wavelength and detection angles ranging from 10° to 60° to validate the structure of the composite films. The structure coordination of polymer chains was determined using a Shimadzu IR Tracer 100 spectrometer in the 4000–400 cm−1 wavenumber range. The surface morphology and elemental analyses of the as-developed PVA/MoO3 composite films were evaluated using a scanning electron microscopy (SEM) (Model: ZEISS-EVO 18 Research, Japan) attached with energy dispersive X-ray spectrometer (EDAX). The mechanical properties of the samples were monitored by a universal testing machine (Lloyd 1 KN LF plus, AMETEK, Inc., Bognor Regis, UK) at a speed rate of 5 mm min−1.The Hioki 3532-50 LCR Hi-tester serves to assess the impedance of composite films by applying potential at distinct frequencies (42 Hz to 1 MHz). In the LCR Hi-tester analysis, the resultant polymer composite is sandwiched between two silver electrodes. For the observed complex impedance, the overall resistances of the material are estimated using Z-view fitting software.
3 Result and discussion
3.1 Structural and morphological properties of the molybdenum oxide nanoparticles
Figure 2 displays the microstructures and crystallinity of as-prepared MoO3 nanostructures as evaluated by the SEM and X-ray diffraction (XRD) studies. The MoO3 sample (Fig. 1a) has diffraction peaks at 12.93°, 23.51°, 26°, 27.51°, 29.66°, 33.83°, 35.68°, 39.20°, 46.47°, 49.39°, 52.75°, 55.37°, 57.65°, 58.98°, 64.62°, and 67.75°. All these diffraction peaks can be attributed to orthorhombic MoO3 phase, which is consistent with standard JCPDS pattern (JCPDS #35-0609). The higher intensities of the (110), (040), and (021) diffraction peaks indicate that these nanostructures grew in a highly anisotropic manner. Furthermore, identical diffraction patterns are seen for the original material and the detected nanorods results same crystallinity with the reduced intensity and widening of the peaks after grinding is consistent with smaller lateral dimensions [22]. It corresponded to JCPDS Card No. 05-0508 (MoO3) orthorhombic crystal structure. The morphology and composition of as-prepared MoO3 nanostructures were investigated using SEM and EDX. As shown in Fig. 2b, the MoO3 nanostructures were shown rod shaped dimension with an average diameter of 0.2 to 0.5 μm and length of 1.5 to 3 μm. The elemental analysis in Fig. 2c illustrates the presence of Mo and O only which confirms the successful formation of MoO3 structure.
Fig. 2
a Powder XRD patterns for bulk and MoO3 rods. b SEM image and c EDX spectrum of MoO3 rods
3.2 Structural and morphological properties of the PVA/molybdenum oxide composite films
Importantly, this work demonstrates green synthesis of MoO3 using water as a solvent. The bulk MoO3 possesses a tuneable layered structure. Water molecules have an affinity to intercalate into the MoO3 layers, which results in an expansion of the interlayer distances and thus weakness the bonds holding the MoO3 layers together. Consequently, the reflux of bulk MoO3 in water at an elevated temperature can lead to its exfoliation into rods. The XRD spectra of PVA/MoO3 (1, 3, and 5%) composites films are shown in Fig. 3. At a high concentration of 5 wt% MoO3, additional peaks at angles 12.44° (020), 25.4° (040), and 38.9° (060) are developed, confirming the MoO3 existence in the final product [23‐25]. The incorporation of MoO3 filler improves the crystallinity of the PVA polymer [26]. For a polymer to be dielectric, crystallinity and planar orientation are crucial requirements. Here, the interfacial interactions are improved by the 5 wt% MoO3 filler, which induces crystallinity in PVA and is thus expected to improve the dielectric properties. Various factors, including preparation methods and the presence of nanofillers within the polymer, are to responsible for the PVA composite’s higher crystallinity [27]. In Fig. 3b, the FTIR result reveals the functional assessment of MoO3 filler added polymers in contrast to the pure sample. When the fraction of MoO3 nanoparticles is increased, this peak reaches marginally to 3285 cm−1. The escalating hydrogen bonding is confirmed by the response of lower wave number peak change [28]. The intra/intermolecular H-bonding among the nanoparticles and the adjacent hydroxyl group of PVA were implicated for the recurrent changes in peak positions noticed upon filler addition. Secondly, the charge migration process among the PVA chains and nanoparticles is critical for the considerable alterations in peak position variations. The peaks found in the region of 2920–2927 cm−1 correspond to asymmetric C–H stretching vibrations. Besides that, the C = O stretching, C–H bending, and C–O elongation of PVA are likely responsible for the peak’s appearance in the regions between 1640 and 1648, 1431 and 1436, and 1070 and 1095 cm−1 [12, 29]. When the concentration of MoO3 is increased, the intensity of the peaks changes, indicating that there is a substantial interplay between the pure polymer and MoO3 [30].
Fig. 3
a XRD and b FTIR spectra of pure PVA and at various wt% of MoO3
SEM is a useful technique for studying the morphology of materials. As evident in the SEM images (Fig. 4), structural alterations occur in the samples as a result of MoO3 interactions with pure PVA. A uniform and homogenous surface (Fig. 4a) confirms the miscibility of MoO3 in PVA. When compared to the pure PVA, there is an influence of MoO3 dispersions in the sample containing 1 wt% MoO3 (Fig. 4b). We see considerable changes in morphological growth when the filler level is increased to 3 wt% (Fig. 4c), which could impact the strong interfacial interaction between filler and polymer matrix. At 5 wt% MoO3, the MoO3 fillers are uniformly distributed throughout the polymer, as illustrated in Fig. 4d. Additionally, no surface defects or cracks were observed on the surface of the composite films. These findings imply that the composite films are flexible. The well dispersed and uniform particle nature improves the dielectric properties of the polymer matrix.
Fig. 4
SEM images of PVA pure doped with (a) 0.0 wt%, (b) 1 wt%, (c) 3 wt% and (d) 5 wt% of MoO3 nanoparticles
The tensile tests on the pure PVA and PVA/MoO3 composite films were carried out in order to evaluate the influence of MoO3 fillers on the mechanical properties of PVA and its composites. It was observed that the mechanical properties of the composite films can be improved significantly, due to the strong adhesion between MoO3 filler and PVA matrix resulting from the hydrogen bonding interactions. The mechanical properties such as tensile strength, Young’s modulus and percent elongation at break evaluated from the tensile tests are provided in Table 1. From the Table 1, the tensile properties of the PVA/MoO3 composite films increased compared to the pure PVA. The mechanical reinforcement with MoO3 was believed to be due to an effective interfacial load transfer resulting from the enhanced interfacial adhesion between the polymer matrixes and the fillers [26].
Table 1
Mechanical properties of the composites
Sample
Tensile strength (MPa)
Young’s modulus (MPa)
Elongation at break (%)
PVA
18.21 ± 1.90
65.30 ± 9.21
10.21 ± 0.65
PVA/1% MoO3
25.31 ± 2.0
74.32 ± 6.00
9.23 ± 1.10
PVA/3% MoO3
36.21 ± 1.8
88.24 ± 7.21
8.42 ± 1.22
PVA/ 5% MoO3
40.21 ± 2.1
92. 54 ± 9.01
7. 21 ± 0.98
3.4 Electrical properties of the composite films
In order to construct composite materials with superior dielectric properties, the effects of varying MoO3 volume fractions in the PVA/MoO3 particles on the electrical properties were investigated. Figure 5a depicts a Nyquist curve derived from EIS findings in the 1 Hz to 100 kHz frequency range. Figure 5b depicts the differences in ac conductivity between composites with MoO3 doping and a pure sample. The ac conductivity increases with the concentration of MoO3 nanoparticles until it reaches 5% by weight. In all films, conductivity increases with frequency (Table 2). The bonds are designed to switch at higher frequencies, resulting in a dielectric transition with vulnerable trustworthy polar functional groups, which causes physiological adaptations within the polymer structure via the formation of charge transfer complexes, implying increased electrical conductivity of the films [31, 32].
Fig. 5
a and b Variation of ac conductivity with frequency for pure and different PVA (1, 3 and 5%) added molybdenum oxide composites films
The complex permittivity, ε* comprises real and imaginary parts and provides detail information about the polarization mechanism [33] and it is given by: \(\varepsilon ^{*} = \varepsilon ^{\prime} - j\varepsilon ^{\prime\prime}\)
The real part (ε′) and imaginary part (ε″) of complex permittivity are given as
Here, Z′ is real part, and Z″ is imaginary part of impedance, f is the applied frequency (ω = 2πf), Co = (εoA/t), A is the area and t is the thickness of the sample.
The frequency dependent values of the dielectric constant’ and dielectric loss’ of the PVA/MoO3 composites samples are shown in Fig. 6. A dielectric material’s electrical energy strong ability (i.e., the strength of dielectric polarization) under the influence of a time-varying electric field is measured by the dielectric constant value, whereas the dielectric loss value represents the electrical energy loss per cycle due to the Joule heating effect [11]. The difference in the dielectric constant (ɛ′) with respect to log (f) shows that the dielectric constant rises at lower frequencies and falls at higher frequencies. This increased dielectric constant is due to Maxwell-Wagner polarization, which is primarily produced by conductor-insulator interactions. Furthermore, this interfacial polarization is caused by the accumulation of space charge polarization at the interfaces.
Table 2
Electrical conductivity (σdc) and relaxation time for PVA/MoO3 composite films
Sample
σdc (s/cm)
Relaxation time (in sec)
PVA/1wt% MoO3
7.314 × 10−9
1.2 × 10−3
PVA/3wt% MoO3
1.416 × 10−8
1.4 × 10−3
PVA/5wt% MoO3
2.8 × 10−8
2.6 × 10−4
Fig. 6
a Variation of dielectric constant, b Variation of dielectric loss (ε″) and c Variation of dielectric loss factor with frequency for pure different PVA (1, 3 and 5%) added molybdenum oxide composites films
Space charges acquire ample time to adapt to an applied electric field in the low-frequency region; but, in the higher frequency range, changes towards an electric field eventuate rapidly for space charges to adjust, and the polarization consequence could not exist. In the sample where percolation occurs, PVA with 5% MoO3 doping possesses greatest possible dielectric constant. Over this percolation threshold, the dielectric constant tends to decrease [34‐37]. As demonstrated in Fig. 6b, the dielectric loss (ε″) reduces as the frequency increases. Higher frequencies hinder the ability for space charges that respond towards the applied field, therefore charge accumulation due to polarization reduces, and hence dielectric loss decreases [38]. The dielectric loss factor is a standard definition of power outage in a dielectric medium (tan δ). The frequency evolution of the dielectric loss factor for all films is shown in Fig. 6c. Tangent loss decreases as frequency increases, as seen by the graph. Dielectric loss can similarly be expressed in terms of the loss tangent (tan δ), and is denoted as
Where ε′ is dielectric constant and ε″ is dielectric loss [39]. It is observed that the tan values of these polymer composite materials are significantly small, indicating that they are suitable as a potential candidate for the fabrication of electronic devices. The maximum peak corresponding frequency of tan δ spectra is used to evaluate the relaxation time \(\tau =\left(\frac{1}{{2\pi f}_{max}}\right),\) (Where fmax is the frequency corresponding to peak maxima in the tan δ vs. f plot) and is summarized in Table 1. The lowest relaxation time is observed for the 5% MoO3 filler. This result demonstrates that the filler content of these polymer composite materials significantly influences the electrostatic interactions between filler and polymer.
Analyzing the modulus (M*) provides more insight into the loss tangent and dielectric permittivity analysis. The ability to separate the polarization effect from the bulk relaxation phenomenon in the polymer electrolyte is one advantage of modulus analysis [40]. Complex electric modulus (M*) and complex permittivity (ε*) are connected by the following equations.
Whereas M is the real dielectric modulus and M″ is an imaginary component. Figure 7a, b depicts how the real and imaginary parts of the modulus. Figure 7a shows a dispersion region for the polymer composite films, and the long tail is located in a low-frequency region. The M′ value increases rapidly at high frequencies, and the high-frequency window contains the peak for the 5% MoO3 [41]. The variation of M″ with frequency is reported to have the same characteristic. The widening in the peak of the modulus plots (M′ & M″) at higher frequency side indicates the dominance of non-debye type relaxation behavior in such systems [42].
The M′ values are seen to rise irregularly with increase in frequency, eventually hitting a constant—current near 1 MHz. The M″ spectrum of the 3 wt% MoO3 doped PVA composite film revealed distinct relaxation signals in the fairly low and intermediate frequency ranges, but merely the relaxation spike in the midway frequency range was detected for the remaining wt% MoO3 and pure PVA samples (Fig. 7b). The low-frequency peak is experienced by the MWS relaxation process, that has been detected in previous polymeric composites [43], but the intermediate frequency zone peak is formed by the PVA chain segmental movements (-relaxation) of the polymers composite materials studied.
Fig. 7
Frequency dependent real part M′ and loss part M″ for pure different PVA (1, 3 and 5%) added molybdenum oxide composites films
Properties of polymer composites are influenced by three main factors, including filler surface properties, nano reinforcing properties, and interfacial interactions between the two. The properties of a polymeric composite also heavily depend on the dispersion and distribution of fillers in the continuous matrix phase for a specific nano reinforcement phase and matrix polymer (Fig. 8).
Fig. 8
Schematic representation of uniform dispersion of filler in the polymer matrix
Table 3 compares the dielectric properties of some polymer/filler composite films reported previously. One can find that the PVA/MoO3 composite films prepared by green method in this work shows good dielectric properties (i.e., high dielectric constant and low dielectric loss). The high dielectric constant of the composite films is due to the uniform distribution of MoO3 fillers in the PVA matrix.
Table 3
Comparison of dielectric constant, dielectric loss of the PVA composite films containing MoO3 particles
In summary, we have successfully prepared PVA/MoO3 composite films by facile and green method. The structural characterization of the samples explored by XRD and FTIR studies. With different wt% ratios of MoO3 added to a PVA polymer matrix, dielectric relaxation and conductivity studies have been investigated. The polymer composite films’ dielectric constant increases as filler MoO3 content increases, reaching its highest level at 5 wt% loading. High conductivity is achieved by dopant ions with the highest dielectric constant. Analysis of the loss tangent spectra reveals a decrease in the relaxation time. It has been found that the conductivity of polymer composite films increases with MoO3 concentration and reaches its maximum value (~ 10−8 S/cm) for the 5 wt% of MoO3 content. Additionally, modulus study supported the above conclusions. The 5 wt% MoO3/polymer composite films showed the lowest value of relaxation time. The prepared polymer composite films may be used as separator/ionic transport media for high-performance energy devices due to their high dielectric constant, conductivity, and low relaxation time.
Declarations
Conflict of interest
The authors have no relevant financial or non-financial interests to disclose.
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