Top

Colloid and Polymer Science

Published in:

01-10-2016 | Original Contribution

Multi-stimuli-responsive poly(NIPA-co-HEMA-co-NVP) with spironaphthoxazine hydrogel for optical data storage application

Authors: Xiaoli Yang, Lihua Zhou, Le Lv, Xin Zhao, Lingyun Hao

Published in: Colloid and Polymer Science | Issue 10/2016

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

A multi-stimuli-responsive poly(NIPA-co-HEMA-co-NVP) with spironaphthoxazine hydrogel (poly(NIPA-co-HEMA-co-NVP-co-SPO)) was prepared by radical polymerization. The structure of this hydrogel was characterized by FTIR, ¹³C NMR spectra, and SEM. Equilibrium swelling measurement and UV-vis spectra were applied into evaluating thermo-responsive, pH-responsive and light-responsive properties. These results exhibited poly(NIPA-co-HEMA-co-NVP-co-SPO) hydrogel with excellent stimuli-responsive characteristics including thermal, pH, and light stimulation. Meanwhile, the obvious change for internal microstructure of hydrogel was observed by SEM after UV irradiation and in acidic condition. In addition, the poly(NIPA-co-HEMA-co-NVP-co-SPO) hydrogel with good mechanical property can be utilized in erasable and rewritable photoimaging based on the photochromic effect, which makes it a potential application in rewritable optical memory media or imaging processes.

previous article Kinetic study of oxidation of paracetamol by water-soluble colloidal MnO2 in the presence of an anionic surfactant

next article Synthesis of nanostructured confetti-like and mace-like particles via dispersion polymerization of alkyl methacrylates on polystyrene seeds

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Peppas NA, Hilt JZ, Khademhosseini A, Langer R (2006) Hydrogels in biology and medicine: from molecular principles to bionanotechnology. Adv Mater 18:1345–1360CrossRef

Kuckling D (2009) Responsive hydrogel layers—from synthesis to applications. Colloid Polym Sci 287:881–891CrossRef

Das D, Ghosh P, Ghosh A, Haldar C, Dhara S, Panda AB, Pal S (2015) Stimulus-responsive, biodegradable, biocompatible, covalently cross-linked hydrogel based on dextrin and poly(N-isopropylacrylamide) for in vitro/in vivo controlled drug release ACS. Appl Mater Interfaces 7:14338–14351CrossRef

Garcia A, Marquez M, Cai T, Rosario R, Gust Z, Hayes M, Vail SA, Park CD (2007) Photo-, thermally, and pH-responsive microgels. Langmuir 23:224–229CrossRef

Rutkevičius M, Mehla 1 G H, Paunov VN, Qin Q, Rubini PA, Stoyanov SD, Petkov J (2013) Sound absorption properties of porous composites fabricated by a hydrogel templating technique. J Mater Res 28:2409–2414

Hoare TR, Kohane DS (2008) Hydrogels in drug delivery: progress and challenges. Polymer 49:1993–2007CrossRef

Eeckman F, Moes AJ, Amighi K (2004) Synthesis and characterization of thermosensitive copolymers for oral controlled drug delivery. Eur Polym J 40:873–881CrossRef

Bassik N, Abebe BT, Laflin KE, Gracias DH (2010) Photolithographically patterned smart hydrogel based bilayer actuators. Polymer 51:6093–6098CrossRef

Mueller M, Tebbe M, Andreeva DV, Karg M, Puebla RAA, Pazos-Perez N, Fery A (2012) Large-area organization of pNIPA-coated nanostars as SERS platforms for polycyclic aromatic hydrocarbons sensing in gas phase. Langmuir 28:9168–9173CrossRef

10.

Richter A, Paschew G, Klatt S (2008) Jens Lienig Karl-Friedrich Arndt and Hans-Jürgen P. Adler, review on hydrogel-based pH sensors and microsensors. Sensors 8:561–581CrossRef

11.

Schroeder V, Korten T, Linke H, Diez S, Maximov I (2013) Dynamic guiding of motor-driven microtubules on electrically heated smart polymer tracks. Nano Lett 13:3434–3438CrossRef

12.

Chatterjee P, Pan Y, Stevens EC, Ma T, Jiang H, Dai LL (2013) Controlled morphology of thin film silicon integrated with environmentally responsive hydrogels. Langmuir 29:6495–6501CrossRef

13.

Lee EM, Gwon SY, Ji BC, Wang S, Kim SH (2012) Multiple switching behaviors of poly(N-isopropylacrylamide) hydroel with spironaphthoxazine and D-π-a type dye. J Lumin 132:665–670CrossRef

14.

Feng Q, Li F, Yan QZ, Zhu YC, Ge CC (2010) Frontal polymerization synthesis and drug delivery behavior of thermo-responsive poly(N-isopropylacrylamide) hydrogel. Colloid Polym Sci 288:915–921CrossRef

15.

Dutta S, Dhara D (2015) Improved swelling–deswelling behavior of poly(N-isopropyl acrylamide) gels with poly(N,N′-dimethyl aminoethyl methacrylate) grafts. J Appl Polym Sci 132:42749–42758CrossRef

16.

Banerjee R, Dhara D (2014) Functional group-dependent self-assembled nanostructures from thermo-responsive triblock copolymers. Langmuir 30:4137–4146CrossRef

17.

Šťastná J, Hanyková L, Sedláková Z, Valentová H, Spěváček J (2013) Temperature-induced phase transition in hydrogel of interpenetrating networks poly(N-isopropylmethacrylamide)/poly(N-isopropylacrylamide). Colloid Polym Sci 291:2409–2417CrossRef

18.

Petriashvili G, Santo MPD, Devadze L, Zurabishvili T, Sepashvili 1 N, Gary R, Barberi R (2016) Rewritable optical storage with a spiropyran doped liquid crystal polymer film. Macromol Rapid Commun 37:500–505

19.

Yuan W, Sun L, Tang H, Wen Y, Jiang G, Huang W, Jiang L, Song Y, Tian H, Zhu D (2005) A novel thermally stable spironaphthoxazine and its application in rewritable high density optical data storage. Adv Mater 17:156–160CrossRef

20.

Shiraishi Y, Tanaka K, Hirai T (2013) Colorimetric sensing of Cu(II) in aqueous media with a spiropyran derivative via a oxidative dehydrogenation mechanism. ACS Appl Mater Interfaces 5:3456–3463CrossRef

21.

Watkins DL, Fujiwara T (2012) Synthesis characterization, and solvent-independent photochromism of spironaphthooxazine dimers. J Photoch Photobio A 228:51–59CrossRef

22.

Feczkó T, Varga O, Kovács M, Vidóczy T, Voncina B (2011) Preparation and characterization of photochromic poly(methyl methacrylate) and ethyl cellulose nanocapsules containing a spirooxazine dye. J Photoch Photobio A 222:293–298CrossRef

23.

Wang S, Choi MS, Kim SH (2008) Bistable photoswitching in poly(N-isopropylacrylamide) with spironaphthoxazine hydrogel for optical data storage. J Photochem Photobiol A 198:150–155CrossRef

24.

Wang S, Choi MS, Kim SH (2008) Multiple switching photochromic poly(N-isopropylacrylamide) with spironaphthoxazine hydrogel. Dyes Pigments 78:8–14CrossRef

25.

Kulardana E, Mudiyanselage TK, Neckers DC (2009) Dual responsive poly(N-isopropylacrylamide) hydrogels having spironaphthoxazines as pendant groups. J Polym Sci A Polym Chem 47:3318–3325CrossRef

26.

Zırıh T, Orakdogen N (2016) Evaluation of pH/temperature double responsivity of copolymerized methacrylate-based networks: solvent diffusion analysis with adjustable swelling kinetics. Eur Polym J 75:75371–75387

27.

Brahim S, Narinesingh D, Elie AG (2003) Synthesis and hydration properties of pH-sensitive p(HEMA)-based hydrogels containing 3-(trimethoxysilyl)propyl methacrylate. Biomacromolecules 4:497–503CrossRef

28.

Orakdogen N, Celik T (2016) Ion-stimuli responsive dimethylaminoethyl methacrylate/hydroxyethyl methacrylate copolymeric hydrogels: mutual influence of reaction parameters on the swelling and mechanical strength. J Polym Res 23:1–17CrossRef

29.

Fares MM, Assaf SM, Jaber AA (2011) Biodegradable amphiphiles of grafted poly(lactide) onto 2-hydroxyethyl methacrylate-co-N-vinylpyrrolidone copolymers as drug carriers. J Appl Polym Sci 122:840–848CrossRef

30.

Telford AM, James M, Meagher L (2010) Thermally cross-linked PNVP films as antifouling coatings for biomedical applications. ACS Appl Mater Interfaces 2:2399–2408CrossRef

31.

Yang XL, Yang BJ, Liu YY, Zhu HJ (2012) Microwave-assisted synthesis of novel spirooxazines and their photochromic behaviors in polymer matrices optoelectronics. Adv Mater 6:1146–1152

32.

Yang J, Webb AR, Ameer GA (2004) Novel citric acid-based biodegradable elastomers for tissue engineering. Adv Mater 16:511–516CrossRef

33.

Kumar V, Chaudhari CV, Bhardwaj YK, Goel NK, Sabharwal S (2006) Radiation induced synthesis and swelling characterization of thermo-responsive N-isopropylacrylamide-co-ionic hydrogels. Eur Polym J 42:235–246CrossRef

34.

Al-Jallo HN, Jalhxoom MG (1975) Spectral correlations for α,β-unsaturated acid halides. Spectrochim Acta A 31:265–271CrossRef

35.

Horak D, Krystufek M, Spevacek J (2000) Effect of reaction parameters on the dispersion polymerization of 1-vinyl-2-pyrrolidone. J Polym Sci A Polym Chem 38:653–663CrossRef

36.

Toman L, Janata M, Spěváček J, Dvořánková B, Látalová P, Vlček P, Sikora A, Michálek J, Pekárek M (2006) One-pot synthesis of isocyanate and methacrylate multifunctionalized polyisobutylene and polyisobutylene-based amphiphilic networks. J Polym Sci A Polym Chem 44:2891–2900CrossRef

37.

Toman L, Janata M, Spěváček J, Brus J, Sikora A, Látalová P, Holler P, Vlček P, Dvořánková B (2006) Amphiphilic conetworks. II. Novel two-step synthesis of poly[2-(dimethylamino)ethyl methacrylate]–polyisobutylene, poly(N-isopropylacrylamide)-polyisobutylene, and poly(N,N-dimethylacrylamide)-polyisobutylene hydrogels. J Polym Sci A Polym Chem 44:6378–6384CrossRef

38.

Zhuang YF, Yang H, Wang GW, Zhu ZQ, Song WQ, Zhao HD (2003) Radiation polymerization and controlled drug release of polymer hydrogels with NIPA and NVP. J Appl Polym Sci 88:724–729CrossRef

39.

Ricka J, Tanaka T (1984) Swelling of ionic gels: quantitative performance of the Donnan theory. Macromolecules 17:2916–2921CrossRef

40.

Zhang XM, ZB H, Li Y (1997) The phase transition and modulus of ionic N-isopropylacrylamide gels in concentrated salt solutions. J Appl Polym Sci 63:1851–1856CrossRef

41.

Liu YY, Fan XD (2003) Preparation and characterization of a novel responsive hydrogel with a β-cyclodextrin-based macromonomer. J Appl Polym Sci 89:361–367CrossRef

42.

Doron A, Katz E, Tao G, Willner I (1997) Photochemically-, chemically-, and pH-controlled electrochemistry at functionalized spiropyran monolayer electrodes. Langmuir 13:1783–1790CrossRef

Title: Multi-stimuli-responsive poly(NIPA-co-HEMA-co-NVP) with spironaphthoxazine hydrogel for optical data storage application
Authors: Xiaoli Yang
Lihua Zhou
Le Lv
Xin Zhao
Lingyun Hao
Publication date: 01-10-2016
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 10/2016
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-016-3915-6

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 10/2016

Polymer brush synthesis on surface modified carbon nanotubes via in situ emulsion polymerization

A novel radiation-induced grafting methodology to synthesize stable zerovalent iron nanoparticles at ambient atmospheric conditions

Noncovalent PEGylation-based enzyme switch in physiological saline conditions using quaternized polyamines

Magnetic hyperthermia with magnetite nanoparticles: electrostatic and polymeric stabilization

PEGylated liposomes prepared with polyborane instead of cholesterol for BNCT: characteristics and biodistribution evaluation

Polyethylene-thermally reduced graphene nanocomposites: comparison of masterbatch and direct melt mixing approaches on mechanical, thermal, rheological, and morphological properties

Premium Partners