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Nanozymology: An Overview Read chapter Read first chapter

2020 | OriginalPaper | Chapter

10. Noble Metal-Based Nanozymes

Authors : Shuangfei Cai, Rong Yang

Published in: Nanozymology

Publisher: Springer Singapore

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Abstract

Within the last decade, we have witnessed great advances in noble metal-based nanozymes, especially Pt- and Au-containing ones due to the rapidly growing field of nanotechnology driven by various advanced synthetic strategies and characterization techniques. Multiple intriguing enzymatic properties, e.g., oxidase-, peroxidase-, catalase-, and SOD-like activities, were extensively explored. Impressively, noble metals immobilized on various supports are emerging as a class of novel nanozymes, exhibiting synergistically enhanced performance. With significant advantages of tunability in activities, high stability as well as ease of storage and treatment, noble-metal nanozymes show great potential as attractive candidates for natural enzymes. In this chapter, we describe the design and fabrication of noble metal-based nanozymes. We also summarize several methodologies to tune their catalytic activities. Besides, we cover a wide range of applications in numerous fields, such as biosensing, immunoassays, and contaminant removal. Finally, we discuss the catalytic mechanism of noble metal-based nanozymes.

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previous chapter Cerium Oxide Based Nanozymes
next chapter Hybrid Nanozyme: More Than One Plus One
Literature
1.
Gao LZ, Zhuang J, Nie L, Zhang JB, Zhang Y, Gu N, Wang TH, Feng J, Yang DL, Perrett S, Yan XY (2007) Intrinsic peroxidase-like activity of ferromagnetic nanoparticles. Nat Nanotechnol 2(9):577–583
2.
Hashmi ASK, Hutchings GJ (2006) Gold catalysis. Angew Chem Int Ed 45(47):7896–7936
3.
Johansson Seechurn CC, Kitching MO, Colacot TJ, Snieckus V (2012) Palladium-catalyzed cross-coupling: a historical contextual perspective to the 2010 Nobel prize. Angew Chem Int Ed 51(21):5062–5085
4.
Pushkarev VV, Zhu ZW, An K, Hervier A, Somorjai GA (2012) Monodisperse metal nanoparticle catalysts: synthesis, characterizations, and molecular studies under reaction conditions. Top Catal 55(19–20):1257–1275
5.
Borodko Y, Jones L, Lee H, Frei H, Somorjai GA (2009) Spectroscopic study of tetradecyltrimethylammonium bromide Pt-C14TAB nanoparticles: structure and stability. Langmuir 25(12):6665–6671
6.
Ma M, Zhang Y, Gu N (2011) Peroxidase-like catalytic activity of cubic Pt nanocrystals. Colloid Surf A 373(1):6–10
7.
Fu Y, Zhao XY, Zhang JL, Li W (2014) DNA-based platinum nanozymes for peroxidase mimetics. J Phys Chem C 118(31):18116–18125
8.
Li W, Chen B, Zhang HX, Sun YH, Wang J, Zhang JL, Fu Y (2015) BSA-stabilized Pt nanozyme for peroxidase mimetics and its application on colorimetric detection of mercury(II) ions. Biosens Bioelectron 66(66c):251–258
9.
Fan J, Yin JJ, Ning B, Wu XC, Hu Y, Ferrari M, Anderson GJ, Wei JY, Zhao YL, Nie GJ (2011) Direct evidence for catalase and peroxidase activities of ferritin-platinum nanoparticles. Biomaterials 32(6):1611–1618
10.
Liu Y, Wu HH, Li M, Yin JJ, Nie ZH (2014) pH dependent catalytic activities of platinum nanoparticles with respect to the decomposition of hydrogen peroxidase and scavenging of superoxide and singlet oxygen. Nanoscale 6(20):11904–11910
11.
Li JN, Liu WQ, Wu XC, Gao XF (2015) Mechanism of pH-switchable peroxidase and catalase-like activities of gold, silver, platinum and palladium. Biomaterials 48:37–44
12.
Jin LH, Meng Z, Zhang YQ, Cai SJ, Zhang ZH, Li C, Shang L, Shen YH (2017) Ultrasmall Pt nanoclusters as robust peroxidase mimics for colorimetric detection of glucose in human serum. ACS Appl Mater Inter 9(11):10027–10033
13.
Deng HH, Lin XL, Liu YH, Li KL, Zhang QQ, Peng HP, Liu AL, Xia XH, Chen W (2017) Chitosan-stabilized platinum nanoparticles as effective oxidase mimics for colorimetric detection of acid phosphate. Nanoscale 9(29):10292–10300
14.
Yu CJ, Chen TH, Jiang JY, Tseng WL (2014) Lysozyme-directed synthesis of platinum nanoclusters as a mimic oxidase. Nanoscale 6(16):9618–9624
15.
Clark A, Zhu AP, Sun K, Petty HR (2011) Cerium oxide and platinum nanoparticles protect cells from oxidant-mediated apoptosis. J Nanopart Res 13(10):5547–5555
16.
Zhang LB, Laug L, Münchgesang W, Pippel E, Gösele U, Brandsch M, Knez M (2010) Reducing stress on cells with apoferritin-encapsulated platinum nanoparticles. Nano Lett 10(1):219–223
17.
Wang XX, Wu Q, Shan Z, Huang QM (2011) BSA-stabilized Au clusters as peroxidase mimetics for use in xanthine detection. Biosens Bioelectron 26(8):3614–3619
18.
Ahmed SR, Kim J, Suzuki T, Lee J, Park EY (2016) Detection of influenza virus using peroxidase-mimic of gold nanoparticles. Biotech Bioeng 113(10):2298–2303
19.
Jiang X, Sun CJ, Guo Y, Nie GJ, Xu L (2015) Peroxidase-like activity of apoferritin paired gold clusters for glucose detection. Biosens Bioelectron 64:165–170
20.
Shah J, Purohit R, Singh R, Karakoti AS, Singh S (2015) ATP-enhanced peroxidase-like activity of gold nanoparticles. J Colloid Interface Sci 456:100–107
21.
Wang S, Chen W, Liu AL, Hong L, Deng HH, Lin XH (2012) Comparison of the peroxidase-like activity of unmodified, amino-modified, and citrate-capped gold nanoparticles. ChemPhysChem 13:1199–1204
22.
Ni PJ, Dai HC, Wang YL, Sun YJ, Shi Y, Hu JT, Li Z (2014) Visual detection of melamine based on the peroxidase-like activity enhancement of bare gold nanoparticles. Biosens Bioelectron 60:286–291
23.
Wang C, Shi Y, Dan YY, Nie XG, Li J, Xia XH (2017) Enhanced peroxidase-like performance of gold nanoparticles by hot electrons. Chem Eur J 23(28):6717–6723
24.
Hizir MS, Top M, Balcioglu M, Rana M, Robertson NM, Shen FS, Sheng J, Yigit MV (2016) Multiplexed activity of perAuxidase: DNA-capped AuNPs act as adjustable peroxidase. Anal Chem 88:600–605
25.
Feng JY, Huang PC, Shi SZ, Deng KY, Wu FY (2017) Colorimetric detection of glutathione in cells based on peroxidase-like activity of gold nanoclusters: a promising powerful tool for identifying cancer cells. Anal Chim Acta 967:64–69
26.
Biswas S, Tripathi P, Kumar N, Nara S (2016) Gold nanorods as peroxidase mimetics and its application for colorimetric biosensing of malathion. Sensor Actuat B-Chem 231:584–592
27.
Chang YQ, Zhang Z, Hao JH, Yang WS, Tang JL (2016) BSA-stabilized Au clusters as peroxidase mimetic for colorimetric detection of Ag+. Sensor Actuat B-Chem 232:692–697
28.
Zhu R, Zhou Y, Wang XL, Liang LP, Long YJ, Wang QL, Zhang HJ, Huang XX, Zheng HZ (2013) Detection of Hg2+ based on the selective inhibition of peroxidase mimetic activity of BSA-Au clusters. Talanta 117(22):127–132
29.
Mikami Y, Dhakshinamoorthy A, Alvaro M, García H (2013) Catalytic activity of unsupported gold nanoparticles. Catal Sci Technol 3:58–69
30.
Comotti M, Pina CD, Matarrese R, Rossi M (2004) The catalytic activity of “naked” gold particles. Angew Chem Int Ed 43(43):5812–5815
31.
Beltrame P, Comotti M, Pina CD, Rossi M (2006) Aerobic oxidation of glucose II. Catalysis by colloidal gold. Appl Catal A Gen 297 (1):1–7
32.
Luo WJ, Zhu CF, Su S, Li D, He Y, Huang Q, Fan CH (2010) Self-catalyzed, self-limiting growth of glucose oxidase-mimicking gold nanoparticles. ACS Nano 4(12):7451–7458
33.
Zheng XX, Liu Q, Jing C, Li Y, Li D, Luo WJ, Wen YQ, He Y, Huang Q, Long YT, Fan CH (2011) Catalytic gold nanoparticles for nanoplasmonic detection of DNA hybridization. Angew Chem Int Ed 50(50):11994–11998
34.
Lan J, Xu W, Wan Q, Zhang X, Lin J, Chen J, Chen J (2014) Colorimetric determination of sarcosine in urine samples of prostatic carcinoma by mimic enzyme palladium nanoparticles. Anal Chim Acta 825(2):63–68
35.
Shi W, Fan H, Ai S, Zhu L (2015) Pd nanoparticles supported on nitrogen, sulfur-doped three-dimensional hierarchical nanostructures as peroxidase-like catalysts for colorimetric detection of xanthine. RSC Adv 5(41):32183–32190
36.
Fu Y, Zhang H, Dai S, Zhi X, Zhang J, Li W (2015) Glutathione-stabilized palladium nanozyme for colorimetric assay of silver(I) ions. Analyst 140(19):6676–6683
37.
Li W, Zhi X, Yang JJ, Zhang JL, Fu Y (2016) Colorimetric detection of cysteine and homocysteine based on an oligonucleotide-stabilized Pd nanzyme. Anal Methods 8(25):5111–5116
38.
Fang G, Li WF, Shen XM, Perez-Aguilar JM, Chong Y, Gao XF, Chai ZF, ChenCY Ge CC, Zhou RH (2018) Differential Pd-nanocrystal facets demonstrate distinct antibacterial activity against Gram-positive and Gram-negative bacteria. Nat Commun 9:129
39.
Ye HH, Mohar J, Wang QX, Catalano M, Kim MJ, Xia XH (2016) Peroxidase-like properties of ruthenium nanoframes. Sci Bull 61(22):1739–1745
40.
Cui ML, Zhou JD, Zhao Y, Song QJ (2017) Facile synthesis of iridium nanoparticles with superior peroxidase-like activity for colorimetric detection of H2O2 and xanthine. Sens Actuat B 243:203–210
41.
Choleva TG, Gatselou VA, Tsogas GZ, Giokas DL (2018) Intrinsic peroxidase-like activity of rhodium nanoparticles, and their application to the colorimetric determination of hydrogen peroxide and glucose. Microchim Acta 185(1):22–30
42.
Cai SF, Xiao W, Duan HH, Liang XX, Wang C, Yang R (2018) Single-layer Rh nanosheets with ultrahigh peroxidase-like activity for colorimetric biosensing. Nano Res 11(12):6304–6315
43.
Wang DS, Li YD (2011) Bimetallic nanocrystals: liquid-phase synthesis and catalytic applications. Adv Mater 23(9):1044–1060
44.
Gu J, Zhang YW, Tao F (2012) Shape control of bimetallic nanocatalysts through well-designed colloidal chemistry approaches. Chem Soc Rev 41(24):8050–8065
45.
Tao F (2012) Synthesis, catalysis, surface chemistry and structure of bimetallic nanocatalysts. Chem Soc Rev 41(24):7977–7979
46.
He WW, Liu Y, Yuan JS, Yin JJ, Wu XC, Hu XN, Zhang K, Liu JB, Chen CY, J YL, Guo YT (2011) Au@Pt nanostructures as oxidase and peroxidase mimetics for use in immunoassays. Biomaterials 32:1139–1147
47.
Liu JB, Hu XN, Hou S, Wen T, Lu WQ, Zhu X, Yin JJ, Wu XC (2012) Au@Pt core/shell nanorods with peroxidase- and ascorbate oxidase-like activities for improved detection of glucose. Sensor Actuat B-Chem 166–167(6):708–714
48.
Singh S, Tripathi P, Kumar N, Nara S (2017) Colorimetric sensing of malathion using palladium-gold bimetallic nanozyme. Biosens Bioelectron 92:280–286
49.
Gao ZQ, Xu MD, Lu MH, Chen GN, Tang DP (2015) Urchin-like (gold core)@(platinum shell) nanohybrids: a highly efficient peroxidase-mimetic system for in situ amplified colorimetric immunoassay. Biosens Bioelectron 70:194–201
50.
Pan N, Zhu Y, Wu LL, Xie ZJ, Xue F, Peng CF (2016) Highly sensitive colorimetric detection of copper ions based on regulating the peroxidase-like activity of Au@Pt nanohybrids. Anal Methods 8:7531–7536
51.
Nangia Y, Kumar B, Kaushal J, Suri CR (2012) Palladium@gold bimetallic nanostructures as peroxidase mimic for development of sensitive fluoroimmunoassay. Anal Chim Acta 751:140–145
52.
Wu Z, Fu QQ, Yu ST, Sheng LR, Xu M, Yao CZ, Xiao W, Li XQ, Tang Y (2016) Pt@AuNPs integrated quantitative capillary-based biosensors for point-of-care testing application. Biosens Bioelectron 85:657–663
53.
Lee JW, Son J, Yoo KM, Lo M, Moon B (2014) Characterization of the antioxidant activity of gold@platinum nanoparticles. RSC Adv 4:19824–19830
54.
Wu GW, Shen YM, Shi XQ, Deng HH, Zheng XQ, Peng HP, Liu AL, Xia XH, Chen W (2017) Bimetallic Bi/Pt peroxidase mimic and its bioanalytical applications. Anal Chim Acta 971(8):88–96
55.
He WW, Han XN, Jia HM, Cai JH, Zhou YL, Zheng Z (2016) AuPt alloy nanostructures with tunable composition and enzyme-like activities for colorimetric detection of bisulfide. Sci Rep 7:40103
56.
Sun YH, Wang J, Li W, Zhang JL, Zhang YD, Fu Y (2015) DNA-stabilized bimetallic nanozyme and its application on colorimetric assay of biothiols. Biosens Bioelectron 74:1038–1046
57.
Jiang T, Song Y, Wei TX, Li H, Du D, Zhu MJ, Lin YH (2016) Sensitive detection of Escherichia coli O157:H7 using Pt-Au bimetal nanoparticles with peroxidase-like amplification. Biosens Bioelectron 77:687–694
58.
He WW, Wu XC, Liu JB, Hu XN, Zhang K, Hou S, Zhou WY, Xie SS (2010) Design of AgM bimetallic alloy nanostructures (M = Au, Pd, Pt) with tunable morphology and peroxidase-like activity. Chem Mater 22(9):2988–2994
59.
Wu LL, Wang LY, Xie ZJ, Xue F, Peng CF (2016) Colorimetric detection of Hg2+ based on inhibiting the peroxidase-like activity of DNA-Ag/Pt nanoclusters. RSC Adv 6:75384–75389
60.
Wu LL, Wang LY, Xie ZJ, Pan N, Peng CF (2016) Colorimetric assay of L-cysteine based on peroxidase-mimicking DNA-Ag/Pt nanoclusters. Sensor Actuat B-Chem 235:110–116
61.
Polarz S, Smarsly B (2002) Nanoporous materials. J Nanosci Nanotechno 2(6):581–612
62.
Cai SF, Jia XH, Han QS, Yan XY, Yang R, Wang C (2017) Porous Pt/Ag nanoparticles with excellent multifunctional enzyme mimic activities and antibacterial effects. Nano Res 10(6):2056–2069
63.
Sun HJ, Gao N, Dong K, Ren JS, Qu XG (2014) Graphene quantum dots-band-acids used for wound disinfection. ACS Nano 8(6):6202–6210
64.
Tao Y, Ju EG, Ren JS, Qu XG (2015) Bifunctionalized mesoporous silica-supported gold nanoparticles: intrinsic oxidase and peroxidase catalytic activities for antibacterial applications. Adv Mater 27(6):1097–1104
65.
Ge SG, Liu WY, Liu HY, Liu F, Yu JH, Yan M, Huang JD (2015) Colorimetric detection of the flux of hydrogen peroxide released from living cells based on the high peroxidase-like catalytic performance of porous PtPd nanorods. Biosens Bioelectron 71:456–462
66.
Zhu ZJ, Zhai YL, Zhu CZ, Wang ZX, Dong SJ (2013) Bimetallic alloy nanowires and nanosponges: a comparative study of peroxidase mimetics and as enhanced catalysts for oxygen reduction reaction. Electrochem Commun 36(6):22–25
67.
Lu Y, Ye WC, Yang Q, Yu J, Wang Q, Zhou PP, Wang CM, Xue DS, Zhao SQ (2016) Three-dimensional hierarchical porous PtCu dendrites: a highly efficient peroxidase nanozyme for colorimetric detection of H2O2. Sensor Actuat B-Chem 230:721–730
68.
Cai SF, Qi C, Li YD, Han QS, Yang R, Wang C (2016) PtCo bimetallic nanoparticles with high oxidase-like catalytic activity and their applications for magnetic-enhanced colorimetric biosensing. J Mater Chem B 4(10):1869–1877
69.
Xia XH, Zhang JT, Lu N, Kim MJ, Ghale K, Xu Y, McKenzie E, Liu JB, Ye HH (2015) Pd-Ir core-shell nanocubes: a type of highly efficient and versatile peroxidase mimic. ACS Nano 9(10):9994–10004
70.
Jiang T, Song Y, Du D, Liu XT, Lin YH (2016) Detection of p53 protein based on mesoporous Pt-Pd nanoparticles with enhanced peroxidase-like catalysis. ACS Sensors 1(6):717–724
71.
Wang QQ, Zhang LL, Shang CS, Zhang ZQ, Dong SJ (2016) Triple-enzyme mimetic activity of nickel-palladium hollow nanoparticles and their application in colorimetric biosensing of glucose. Chem Commun 52(31):5410–5413
72.
Han L, Li CC, Zhang T, Lang QL, Liu AH (2015) Au@Ag heterogeneous nanorods as nanozyme interfaces with peroxidase-like activity and their application for one-pot analysis of glucose at nearly neutral pH. ACS Appl Mater Inter 7(26):14463–14470
73.
Cai Z, Kuang Y, Qi XH, Wang P, Zhang Y, Zhang ZC, Sun XM (2015) Ultrathin branched PtFe and PtRuFe nanodendrites with enhanced electrocatalytic activity. J Mater Chem A 3(3):1182–1187
74.
He WW, Wu XC, Liu JB, Zhang K, Chu WG, Feng LL, Hu XN, Zhou WY, Xie SS (2010) Formation of AgPt alloy nanoislands via chemical etching with tunable optical and catalytic properties. Langmuir 26(6):4443–4448
75.
Zhang K, Hu XN, Liu JB, Yin JJ, Hou S, Wen T, He WW, Ji YL, Guo YT, Wang Q, Wu XC (2011) Formation of PdPt alloy nanodots on gold nanorods: tuning oxidase-like activities via composition. Langmuir 27(6):2796–2803
76.
Li JR, Lv L, Zhang GN, Zhou XD, Shen AG, Hu JM (2016) Core-shell Fructus Broussonetia-like Au@Ag@Pt nanoparticles as highly efficient peroxidase mimetics for supersensitive resonance-enhanced Raman sensing. Anal Methods 8(9):2097–2105
77.
Mu XY, Wang JY, Li YH, Xu FJ, Long W, Ouyang LF, Liu HL, Jing YQ, Wang JY, Dai HT, Liu Q, Sun YM, Liu CL (2019) Redox trimetallic nanozyme with neutral environment preference for brain injury. ACS Nano 13(2):1870–1884
78.
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field in atomically thin carbon films. Science 306:666–669
79.
Ahmed SR, Takemeura K, Li TC, Kitamoto N, Tanaka T, Suzuki T, Park EY (2017) Size-controlled preparation of peroxidase-like graphene-gold nanoparticle hybrids for the visible detection of norovirus-like particles. Biosens Bioelectron 87:558–565
80.
Wang AC, Zhao HM, Chen XC, Tan B, Zhang YB, Quan X (2017) A colorimetric aptasensor for sulfadimethoxine detection based on peroxidase-like activity of graphenene/nickel@palladium hybrids. Anal Biochem 525(15):92–99
81.
Chen XM, Su BY, Cai ZX, Chen X, Oyama M (2014) PtPd nanodendrites supported on graphene nanosheets: a peroxidase-like catalyst for colorimetric detection of H2O2. Sensor Actuat B-Chem 201(4):286–292
82.
Chen CH, Li NX, Lan JW, Ji XH, He ZK (2016) A label-free colorimetric platform for DNA via target-catalyzed hairpin assembly and the peroxidase-like catalytic of graphene/Au-NPs hybrids. Anal Chim Acta 902:154–159
83.
Tao Y, Lin YH, Huang ZZ, Ren JS, Qu XG (2013) Incorporating graphene oxide and gold nanoclusters: a synergistic catalyst with surprisingly high peroxidase-like activity over a broad pH range and its application for cancer cell detection. Adv Mater 25(18):2594–2599
84.
Zhang LN, Deng HH, Lin FL, Xu XW, Weng SH, Liu AL, Lin XH, Xia XH, Chen W (2014) In situ growth of porous platinum nanoparticles on graphene oxide for colorimetric detection of cancer cells. Anal Chem 86(5):2711–2718
85.
Zhang HJ, Liang X, Han L, Li F (2018) “Non-naked” gold with glucose oxidase-like activity: a nanozyme for tandem catalysis. Small 14(44):1803256
86.
Darabdhara G, Sharma B, Das MR, Boukherroub R, Szunerits S (2017) Cu-Ag bimetallic nanoparticles on reduced graphene oxide nanosheets as peroxidase mimic for glucose and ascorbic acid detection. Sensor Actuat B-Chem 238:842–851
87.
Ganatra R, Zhang Q (2014) Few-layer MoS2: a promising layered semiconductor. ACS Nano 8(5):4074–4099
88.
Huang YX, Guo JH, Kang YJ, Ai Y, Li MC (2015) Two dimensional atomically thin MoS2 nanosheets and their sensing applications. Nanoscale 7(46):19358–19376
89.
Zhang X, Lai ZC, Tan CL, Zhang H (2016) Solution-processed two-dimensional MoS2 nanosheets: preparation, hybridization, and applications. Angew Chem Int Ed 55(31):8816–8838
90.
Singha SS, Nandi D, Singha A (2015) Tuning the photoluminescence and ultrasensitive trace detection properties of few-layer MoS2 by decoration with gold nanoparticles. RSC Adv 5(31):24188–24193
91.
Yuwen L, Xu F, Xue B, Luo Z, Zhang Q, Bao B, Su S, Weng L, Huang W, Wang L (2014) General synthesis of noble metal (Au, Ag, Pd, Pt) nanocrystals modified MoS2 nanosheets and the enhanced catalytic activity of Pd-MoS2 for methanol oxidation. Nanoscale 6(11):5762–5769
92.
Deng J, Li H, Xiao J, Tu Y, Deng D, Yang H, Tian H, Li J, Ren P, Bao X (2015) Arousing the electrocatalytic hydrogen evolution activity of inert wo-dimensional MoS2 surface via single-atom metal doping. Energy Environ Sci 8(5):1594–1601
93.
Zhong X, Yang H, Guo S, Li S, Gou G, Niu Z, Dong Z, Lei Y, Jin J, Li R, Ma J (2012) In situ growth of Ni-Fe alloy on graphene-like MoS2 for catalysis of hydrazine oxidation. J Mater Chem 22(28):13925–13927
94.
Su S, Zhang C, Yuwen LH, Liu XF, Wang LH, Fan CH, Wang LH (2016) Uniform Au@Pt core-shell nanodendrites supported on molybdenum disulfide nanosheets for the methanol oxidation reaction. Nanoscale 8(1):602–608
95.
Sun Z, Zhao QS, Zhang GH, Li Y, Zhang GL, Zhang FB, Fan XB (2015) Exfoliated MoS2 supported Au-Pd bimetallic nanoparticles with core-shell structures and superior peroxidase-like activities. RSC Adv 5(14):10352–10357
96.
Cai SF, Han QS, Qi C, Lian Z, Jia XH, Yang R, Wang C (2016) Pt74Ag26 nanoparticle-decorated ultrathin MoS2 nanosheets as novel peroxidase mimics for highly selective colorimetric detection of H2O2 and glucose. Nanoscale 8(6):3685–3693
97.
Cai SF, Han QS, Qi C, Wang XH, Wang T, Jia XH, Yang R, Wang C (2017) MoS2-Pt3Au1 nanocomposites with enhanced peroxidase-like activities for selective colorimetric detection of phenol. Chin J Chem 35(5):605–612
98.
Qi C, Cai SF, Wang XH, Li JY, Lian Z, Sun SS, Yang R, Wang C (2016) Enhanced oxidase/peroxidase-like activities of aptamer conjuagated MoS2/PtCu nanocomposites and their biosensing application. RSC Adv 6(60):54949–54955
99.
Ma M, Xie J, Zhang Y, Chen ZP, Gu N (2013) Fe3O4@Pt nanoparticles with enhanced peroxidase-like catalytic activity. Mater Lett 105(16):36–39
100.
Wang XH, Han QS, Cai SF, Wang T, Qi C, Yang R, Wang C (2017) Analyst 142(13):2500–2506
101.
Liu XL, Wang XH, Qi C, Han QS, Xiao W, Cai SF, Wang C, Yang R (2019) Sensitive colorimetric detection of ascorbic acid using Pt/CeO2 nanocomposites as peroxidase mimics. Appl Surf Sci 479:532–539
102.
Li ZH, Yang XD, Yang YB, Tan YN, He Y, Liu M, Liu XW, Yuan Q (2018) Peroxidase-mimicking nanozyme with enhanced activity and high stability based on metal-support interactions. Chem Eur J 24(2):409–415
103.
Kluenker M, Tahir MN, Ragg R, Korschelt K, Simon P, Gorelik TE, Barton B, Shylin SI, Panthöfer M, Herzberger J, Frey H, Ksenofontov V, Möller A, Kolb U, Grin J, Tremel W (2017) Pd@Fe2O3 superparticles with enhanced peroxidase activity by solution phase epitaxial growth. Chem Mater 29(3):1134–1146
104.
Liu J, Meng LJ, Fei ZF, Dyson PJ, Zhang L (2018) On the origin of the synergy between the Pt nanoparticles and MnO2 nanosheets in Wonton-like 3D nanozyme oxidase mimics. Biosens Bioelectron 121:159–165
105.
Lin T, Wang JJ, Zhang H, Song ST, Zhou YZ, Zhao J, Du XW (2015) Freestanding ultrathin metallic nanosheets: materials, synthesis, and applications. Adv Mater 27(36):5396–5402
106.
Chen Y, Fan ZX, Zhang ZC, Niu WX, Li CL, Yang NL, Chen B, Zhang H (2018) Two-dimensional metal nanomaterials: synthesis, properties, and applications. Chem Rev 118(13):6409–6455
107.
Sial MAZG, Din MAU, Wang X (2018) Multimetalllic nanosheets: synthesis and applications in fuel cells. Chem Soc Rev 47(16):6175–6200
108.
Wei JP, Chen XL, Shi SG, Mo SG, Zheng NF (2015) An investigation of the mimetic enzyme activity of two-dimensional Pd-based nanostructures. Nanoscale 7(45):19018–19026
109.
Cai SF, Lian C, Duan HH, Xiao W, Han QS, Qi C, Wang C, Yang R (2019) Facile strategy to prepare Rh nanosheet-supported PtRh nanoparticles with synergistically enhanced catalysis in oxidation. Chem Mater 31(3):808–818
110.
Cai SF, Liu XL, Han QS, Qi C, Yang R, Wang C (2018) A novel strategy to construct supported Pd nanocomposites with synergistically enhanced catalytic performances. Nano Res 11(6):3272–3281
111.
Huang Y, Zhao MT, Han SK, Lai ZC, Yang J, Tan CL, Ma QL, Lu QP, Chen JZ, Zhang X, Zhang ZC, Li B, Chen B, Zong Y, Zhang H (2017) Growth of Au nanoparticles on 2D metalloporphyrinic metal-organic framework nanosheets used as biomimetic catalysts for cascade reactions. Adv Mater 29(32):1700102
112.
Haider W, Hayat A, Raza Y, Chaudhry AA, Rehman IU, Marty JL (2015) Gold nanopariticle decorated single walled carbon nanotube nanocomposite with synergistic peroxidase like activity for D-alanine detection. RSC Adv 5(32):24853–24858
113.
Kim MC, Lee D, Jeong SH, Lee SY, Kang E (2016) Nanodiamond-gold nanocomposites with the peroxidase-like oxidative catalytic activity. ACS Appl Mater Inter 8(50):34317–34326
114.
Xu YQ, Fei JB, Li GL, Yuan TT, Xu X, Li JB (2019) Nanozyme-catalyzed cascade reactions for mitochondria-mimicking oxidative phosphorylation. Angew Chem Int Ed 58(17):5572–5576
115.
Ivanova MN, Grayfer ED, Plotnikova EE, Kibis LS, Darabdhara G, Boruah PK, Das MR, Fedorov VE (2019) Pt-decorated boron nitride nanosheets as artificial nanozyme for detection of dopamine. ACS Appl Mater Interfaces 11(25):22102–22112
116.
Zhao C, Xiong C, Liu XK, Qiao M, Li ZJ, Yuan TW, Wang J, Qu YT, Wang XQ, Zhou FY, Xu Q, Wang SQ, Chen M, Wang WY, Li YF, Yao T, Wu YE, Li YD (2019) Unraveling the enzyme-like activity of heterogeneous single atom catalyst. Chem Commun 55(16):2285–2288
117.
Huang L, Chen JX, Gan LF, Wang J, Dong SJ (2019) Single-atom nanozymes. Sci Adv 5(5):eaav5490
118.
Xu BL, Wang H, Wang WW, Gao LZ, Li SS, Pan XT, Wang HY, Yang HL, Meng XQ, Wu QW, Zheng LR, Chen SM, Shen XH, Fan KL, Yan XY, Liu HY (2019) A single-atom nanozyme for wound disinfection applications. Angew Chem Int Ed 58(15):4911–4916
119.
Zhang Z, Liu B, Liu J (2016) Molecular imprinting for substrate selectivity and enhanced activity of enzyme mimics. Small 13(7):1602730
120.
Golub E, Albada HB, Liao WC, Biniuri Y, Willner I (2016) Nucleoapzymes: Hemin/G-quadruplex DNAzyme-aptamer binding site conjugates with superior enzyme-like catalytic functions. J Am Chem Soc 138(1):164–172
Metadata
Title
Noble Metal-Based Nanozymes
Authors
Shuangfei Cai
Rong Yang
Copyright Year
2020
Publisher
Springer Singapore
Book
Nanozymology

Print ISBN: 978-981-15-1489-0

Electronic ISBN: 978-981-15-1490-6

Copyright Year: 2020

DOI
https://doi.org/10.1007/978-981-15-1490-6_10

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