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2024 | OriginalPaper | Chapter

Organometallic Nanoparticles for Magnetically Induced Catalysis in Solution

Authors : Jaime Mazarío, Víctor Varela-Izquierdo, Bruno Chaudret

Published in: Surface Functionalized Metal Catalysts

Publisher: Springer Nature Switzerland

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Abstract

In the starting exploration of magnetically induced catalysis, organometallic nanoparticles (NPs) have proven themselves to serve as efficient and versatile heating agents, demonstrating remarkable potential for diverse liquid-phase reactions. The present chapter delves into the synthesis and application of various organometallic magnetic NPs (MagNPs), i.e., Fe2.2C, FeCo, FeNi3, and NiCo NPs. These magnetic cores, decorated with metals like Ru, Cu, or Ni, exhibit remarkable performance in hydrogenation and hydrodeoxygenation reactions, with promising results in the valorization of biomass derivatives under low hydrogen pressures. The superior catalytic activity compared to those achieved under similar apparent conditions through conventional heating, as well as some recent advances in stability, add to the well-proven advantages of this technology, such as rapid heating, improved energy efficiency, and adaptability to renewable energy sources. The present chapter also establishes the need for precise temperature control, optimized ligand strategies, and strategic stability enhancement in aqueous media, signaling avenues for future progress in magnetically induced catalysis.

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previous chapter Metal Nanoparticles Functionalized with Hydrosoluble Ligands
next chapter Ligand-Capped Heterogeneous Catalysts from Groups 8 to 10
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Metadata
Title
Organometallic Nanoparticles for Magnetically Induced Catalysis in Solution
Authors
Jaime Mazarío
Víctor Varela-Izquierdo
Bruno Chaudret
Copyright Year
2024
Book
Surface Functionalized Metal Catalysts

Print ISBN: 978-3-031-73840-1

Electronic ISBN: 978-3-031-73841-8

Copyright Year: 2024

DOI
https://doi.org/10.1007/3418_2024_117