Skip to main content
Top
Published in: Metallography, Microstructure, and Analysis 6/2017

05-10-2017 | Technical Article

Pearlite Development in Commercial Hadfield Steel by Means of Isothermal Reactions

Authors: M. Martín, M. Raposo, O. Prat, M. F. Giordana, J. Malarría

Published in: Metallography, Microstructure, and Analysis | Issue 6/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The Fe–12Mn–1C Hadfield steel is an abrasion-resistant alloy of high technological relevance for mining and heavy machinery. This composition is susceptible to pearlite formation which is detrimental for the material’s ductility. Although its spread use, the study of pearlite formation has been preserved to laboratory conditions which cannot be transferred to industrial practices. This manuscript provides updated information about this phenomenon by constructing the time–temperature-transformation diagram of the alloy between 400 and 600 °C. The pearlitic reaction occurs above 450 °C and begins on the grain boundaries. Only 7 min is needed for the transformation to start at 550 °C, and a maximum pearlite fraction of 35% is reached after 150 min at this temperature. Results are compared with the Fe–12Mn–0.8C composition mostly found in literature. The discussion comprises the effects of carbon and manganese content on the pearlitic reaction with the support of thermodynamics calculations.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference M. Martín, M. Raposo, A. Druker, C. Sobrero, J. Malarría, Influence of Pearlite Formation on the Ductility Response of Commercial Hadfield Steel. Metallogr. Microstruct. Anal. 5, 505 (2016)CrossRef M. Martín, M. Raposo, A. Druker, C. Sobrero, J. Malarría, Influence of Pearlite Formation on the Ductility Response of Commercial Hadfield Steel. Metallogr. Microstruct. Anal. 5, 505 (2016)CrossRef
2.
go back to reference Y. Ono, T. Tsuchiyama, and S. Takaki, Mechanism of Embrittlement in Hadfield Steel, in Steels and Materials for Power Plants (Wiley, New York, 2006) FRG, pp. 143–148 Y. Ono, T. Tsuchiyama, and S. Takaki, Mechanism of Embrittlement in Hadfield Steel, in Steels and Materials for Power Plants (Wiley, New York, 2006) FRG, pp. 143–148
3.
go back to reference S.A. Hackney, G.J. Shiflet, The Pearlite-Austenite Growth Interface in an Fe–0.8 C–12 Mn alloy. Acta Met. 35, 1007 (1987)CrossRef S.A. Hackney, G.J. Shiflet, The Pearlite-Austenite Growth Interface in an Fe–0.8 C–12 Mn alloy. Acta Met. 35, 1007 (1987)CrossRef
4.
go back to reference S.A. Hackney, G.J. Shiflet, Pearlite Growth Mechanism. Acta Met. 35, 1019 (1987)CrossRef S.A. Hackney, G.J. Shiflet, Pearlite Growth Mechanism. Acta Met. 35, 1019 (1987)CrossRef
5.
go back to reference S.A. Hackney, Morphological Instabilities and Branching Processes at the Initiation of the Eutectoid Transformation. Scr. Metall. Mater. 25, 1453 (1991)CrossRef S.A. Hackney, Morphological Instabilities and Branching Processes at the Initiation of the Eutectoid Transformation. Scr. Metall. Mater. 25, 1453 (1991)CrossRef
6.
go back to reference S.A. Hackney, G.J. Shiflet, Interfacial Structure at the pearlite: Austenite Growth Interface in an Fe–0.8C–12Mn Steel. Scr. Metall. 19, 757 (1985)CrossRef S.A. Hackney, G.J. Shiflet, Interfacial Structure at the pearlite: Austenite Growth Interface in an Fe–0.8C–12Mn Steel. Scr. Metall. 19, 757 (1985)CrossRef
7.
go back to reference R.J. Dippenaar, R.W.K. Honeycombe, The Crystallography and Nucleation of Pearlite. Proc. R. Soc. A Math. Phys. Eng. Sci. 333, 455 (1973)CrossRef R.J. Dippenaar, R.W.K. Honeycombe, The Crystallography and Nucleation of Pearlite. Proc. R. Soc. A Math. Phys. Eng. Sci. 333, 455 (1973)CrossRef
8.
go back to reference D.S. Zhou, G.J. Shiflet, Ferrite: Cementite Crystallography in Pearlite. Met. Trans. A 23, 1259 (1992)CrossRef D.S. Zhou, G.J. Shiflet, Ferrite: Cementite Crystallography in Pearlite. Met. Trans. A 23, 1259 (1992)CrossRef
9.
go back to reference C.R. Hutchinson, G.J. Shiflet, The Formation of Partitioned Pearlite at Temperatures Above the Upper Ae1 in an Fe–C–Mn Steel. Scr. Mater. 50, 1 (2004)CrossRef C.R. Hutchinson, G.J. Shiflet, The Formation of Partitioned Pearlite at Temperatures Above the Upper Ae1 in an Fe–C–Mn Steel. Scr. Mater. 50, 1 (2004)CrossRef
10.
go back to reference A.Y.M. Ontman, G.J. Shiflet, Thermodynamic Mapping of Austenite Decomposition’s Approach Toward Equilibrium in Fe–C–Mn at 700 °C. Acta Mater. 89, 98 (2015)CrossRef A.Y.M. Ontman, G.J. Shiflet, Thermodynamic Mapping of Austenite Decomposition’s Approach Toward Equilibrium in Fe–C–Mn at 700 °C. Acta Mater. 89, 98 (2015)CrossRef
11.
go back to reference M.X. Zhang, P.M. Kelly, The Morphology and Formation Mechanism of Pearlite in Steels. Mater. Charact. 60, 545 (2009)CrossRef M.X. Zhang, P.M. Kelly, The Morphology and Formation Mechanism of Pearlite in Steels. Mater. Charact. 60, 545 (2009)CrossRef
12.
go back to reference R.F. Mehl, W.C. Hagel, The Austenite: Pearlite Reaction. Prog. Met. Phys. 6, 74 (1956)CrossRef R.F. Mehl, W.C. Hagel, The Austenite: Pearlite Reaction. Prog. Met. Phys. 6, 74 (1956)CrossRef
13.
go back to reference N. Zhong, X. Wang, Z. Guo, Y. Rong, Orientation Relationships between Ferrite and Cementite by Edge-to-edge Matching Principle. J. Mater. Sci. Technol. 27, 475 (2011)CrossRef N. Zhong, X. Wang, Z. Guo, Y. Rong, Orientation Relationships between Ferrite and Cementite by Edge-to-edge Matching Principle. J. Mater. Sci. Technol. 27, 475 (2011)CrossRef
14.
go back to reference Y. Ono, T. Tsuchiyama, S. Takaki, Microstructural Change during Isothermal Aging in High Manganese Austenitic Steels. Tetsu-to-Hagane 84, 309 (1998)CrossRef Y. Ono, T. Tsuchiyama, S. Takaki, Microstructural Change during Isothermal Aging in High Manganese Austenitic Steels. Tetsu-to-Hagane 84, 309 (1998)CrossRef
15.
go back to reference D.A. Porter, K.E. Easterling, Phase Transformations in Metals and Alloys (Chapman and Hall, London, 1992), p. 333CrossRef D.A. Porter, K.E. Easterling, Phase Transformations in Metals and Alloys (Chapman and Hall, London, 1992), p. 333CrossRef
16.
go back to reference C. Scott, S. Allain, M. Faral, N. Guelton, The Development of a New Fe–Mn–C Austenitic Steel for Automotive Applications. Rev. Métallurgie 103, 293 (2006)CrossRef C. Scott, S. Allain, M. Faral, N. Guelton, The Development of a New Fe–Mn–C Austenitic Steel for Automotive Applications. Rev. Métallurgie 103, 293 (2006)CrossRef
17.
go back to reference N. Ridley, The Pearlite Reaction, in Proceedings of International Conference on Phase Transformations in Ferrous alloys, eds. by A.R. Marder, J.I. Goldstein (TMS-AIME, Warrendale, 1984), p. 201–236 N. Ridley, The Pearlite Reaction, in Proceedings of International Conference on Phase Transformations in Ferrous alloys, eds. by A.R. Marder, J.I. Goldstein (TMS-AIME, Warrendale, 1984), p. 201–236
18.
go back to reference M. Hillert, Analysis of the Effect of Alloying Elements on the Pearlite Reaction, in Proceedings of an International Conference on Solid to Solid Phase Transformations, ed. by H.I. Aaronson (TMS-AIME, Warrendale, 1982), p. 789–806 M. Hillert, Analysis of the Effect of Alloying Elements on the Pearlite Reaction, in Proceedings of an International Conference on Solid to Solid Phase Transformations, ed. by H.I. Aaronson (TMS-AIME, Warrendale, 1982), p. 789–806
19.
go back to reference H.K.D.H. Bhadeshia, D.V. Edmonds, The Bainite Transformation in a Silicon Steel. Metall. Trans. A 10, 895 (1979)CrossRef H.K.D.H. Bhadeshia, D.V. Edmonds, The Bainite Transformation in a Silicon Steel. Metall. Trans. A 10, 895 (1979)CrossRef
20.
go back to reference B.C. De Cooman, Structure-Properties Relationship in TRIP Steels Containing Carbide-Free Bainite. Curr. Opin. Solid State Mater. Sci. 8, 285 (2004)CrossRef B.C. De Cooman, Structure-Properties Relationship in TRIP Steels Containing Carbide-Free Bainite. Curr. Opin. Solid State Mater. Sci. 8, 285 (2004)CrossRef
21.
go back to reference H. Dierkes, R. Dronskowski, High-Resolution Powder Neutron Diffraction on Mn3C. Zeitschrift Fur Anorg. Und Allg. Chemie 640, 3148 (2014)CrossRef H. Dierkes, R. Dronskowski, High-Resolution Powder Neutron Diffraction on Mn3C. Zeitschrift Fur Anorg. Und Allg. Chemie 640, 3148 (2014)CrossRef
22.
go back to reference J.D. Verhoeven, Fundamentals of Physical Metallurgy (Wiley, New York, 1975), p. 458 J.D. Verhoeven, Fundamentals of Physical Metallurgy (Wiley, New York, 1975), p. 458
23.
go back to reference C.R. Hutchinson, R.E. Hackenberg, G.J. Shiflet, The Growth of Partitioned Pearlite in Fe–C–Mn Steels. Acta Mater. 52, 3565 (2004)CrossRef C.R. Hutchinson, R.E. Hackenberg, G.J. Shiflet, The Growth of Partitioned Pearlite in Fe–C–Mn Steels. Acta Mater. 52, 3565 (2004)CrossRef
24.
go back to reference N.A. Razik, G.W. Lorimer, N. Ridley, An Investigation of Manganese Partitioning During the Austenite–Pearlite Transformation Using Analytical Electron Microscopy. Acta Met. 22, 1249 (1974)CrossRef N.A. Razik, G.W. Lorimer, N. Ridley, An Investigation of Manganese Partitioning During the Austenite–Pearlite Transformation Using Analytical Electron Microscopy. Acta Met. 22, 1249 (1974)CrossRef
Metadata
Title
Pearlite Development in Commercial Hadfield Steel by Means of Isothermal Reactions
Authors
M. Martín
M. Raposo
O. Prat
M. F. Giordana
J. Malarría
Publication date
05-10-2017
Publisher
Springer US
Published in
Metallography, Microstructure, and Analysis / Issue 6/2017
Print ISSN: 2192-9262
Electronic ISSN: 2192-9270
DOI
https://doi.org/10.1007/s13632-017-0391-4

Other articles of this Issue 6/2017

Metallography, Microstructure, and Analysis 6/2017 Go to the issue

Premium Partners